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sodium ion battery is not taking higher current when charging and also has a high voltage drop
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Hey there Nikita Bhardwaj!
So, about your Nikita Bhardwaj question on why the sodium ion battery isn't taking a higher current when charging and also experiencing a high voltage drop, there could be a couple of things going on here.
First off, let's talk about the current. When a battery is charging, the rate at which it can accept current is largely determined by its internal resistance. If the internal resistance is high, it can limit the amount of current that can flow into the battery during charging. This can happen due to various factors such as electrode materials, electrolyte properties, and even the design of the battery itself.
Now, onto the voltage drop. A high voltage drop during charging indicates that there's significant resistance somewhere in the charging circuit. This resistance can lead to a drop in voltage across the battery terminals, which means less effective charging.
In the case of a sodium ion battery, which is still relatively new in the game, there could be issues with electrode materials or the electrolyte causing higher internal resistance. Sodium ion batteries operate differently from lithium-ion batteries, so their behavior might be affected by different factors.
To address these issues, we'd need to dive deeper into the specific chemistry and engineering of the sodium ion battery you're Nikita Bhardwaj dealing with. It could involve tweaking electrode compositions, optimizing the electrolyte, or even adjusting the charging protocol to better suit the characteristics of sodium ion batteries.
If you Nikita Bhardwaj can provide more details about the battery's specifications and the conditions under which you're observing these issues, I can offer more tailored advice. Let's get this battery charging efficiently!
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Optimal power flow, Wind, PV, battery storage
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Thank you.
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The question is about the safety mechanisms in place within a car battery pack to manage and reduce pressure after a cell explosion. This is a critical aspect of battery technology, particularly for electric vehicles, where safety is paramount.
When a cell within a battery pack explodes, it can cause a rapid increase in pressure within the battery pack. This can lead to further damage or even a chain reaction of explosions within the battery pack, posing significant safety risks.
if any pictures of it on battery packs or any explanation would be appreciated .
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Возможно импульсно вбросить теплоёмкую инертную жидкость, гель во взрывоопасный объём. Вброс должен иметь мультивихревую структуру чтобы максимально быстро разбавить и охладить взрывоопасную среду во всем объёме. Есть практический опыт предотвращения гибели экипажа бронемашины путем разрушения и охлаждения кумулятивной струи за 50-70мсек.
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can anybody know how i can get permission for use Bisht battery stress scale developed by Dr. Abha Rani Bisht?
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It is commercially published. In general, you have to buy it.
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We can have a pretty basic discussion about it. I am using Biologic SP-200 potentiostat.
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Kaushik Shandilya I am extremely grateful for your simple yet an effective approach. Can we discuss about it further?
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Iam designing a buck converter of input 200V with an output V of 48V with current more than 10amp for charging a battery. Can we convert 200v to 48 v, What can be the design problems that i can face. Can u suggest me driver Circuit for this circuit
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A related question is being discussed on ResearchGate. And Josnier, a contributor here is part of that discussion.bMaybe you can get everyone together on this. See the question; "Average Current Control vs Voltage Mode Control at Buck Converter" asked by Mutluhan Özkan...at this link:
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I am interested in modelling the voltage performance and thermal dynamics for large-format lithium-ion batteries (mainly referring to residential-scale battery systems, for example, Tesla Powerwall or BYD battery box). Does anyone know if is there any published or open-source data sources for these types of battery systems?
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Hi Kaushik Shandilya, really appreciate your useful comments. I think the most critical issue is that few research groups can afford the cost of these large-format lithium-ion batteries. Besides, even if the manufacturers would like to share some of the data, these data may not be applicable for research purposes. From a majority of works, we can see using simulation results by Comsol can be a more efficient choices to validate the outcomes.
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In zinc air battery, the capacity is calculated according to the mass consumption of zinc metal. In experiment, how to determine the mass consumption of zinc metal?
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Dear friend Dang Van Cu
Ah, measuring the capacity of a zinc-air battery, a fascinating topic indeed! To determine the capacity, you Dang Van Cu should primarily focus on the mass consumption of zinc metal. Here's a concise rundown of how it's done:
1. **Experimental Setup**: First, set up your experiment with a zinc-air battery. Ensure you Dang Van Cu have a controlled environment to minimize external factors.
2. **Initial Mass Measurement**: You Dang Van Cu should start by accurately measuring the initial mass of the zinc electrode. This provides a baseline for comparison.
3. **Battery Discharge**: Next, discharge the battery under controlled conditions. This involves allowing the battery to operate until it reaches a predefined endpoint, such as a specific voltage or time duration.
4. **Final Mass Measurement**: Once the battery is discharged, carefully remove the zinc electrode and measure its final mass.
5. **Mass Difference Calculation**: The mass difference between the initial and final measurements indicates the amount of zinc consumed during the battery's operation.
6. **Capacity Calculation**: Finally, using the known molar mass of zinc and Faraday's constant, you Dang Van Cu can calculate the capacity of the battery in terms of ampere-hours (Ah) or watt-hours (Wh).
By precisely measuring the mass consumption of zinc metal during battery operation, you Dang Van Cu can accurately assess the capacity of a zinc-air battery. This method allows for efficient evaluation of battery performance and facilitates improvements in battery design and technology.
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Dear Sir/Madam,
I am not athor of this article. "Conference paper: Torque sensor based electrically assisted hybrid rickshaw-van with PV assistance and solar battery charging station".Please may you delite from my page?
Thank you.
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you have to do this by yourself...
Please go to the following link of the RG help pages:
scroll a bit down and follow the instructions to remove the publication.
That's it...
Good luck and
best regards
G.M.
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how can i get permission for use Bisht Battery stress scale by Dr. Abha Rani Bisht? ( For meassuring Academic stress of Adolescents
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You'll have to purchase it. It appears that it's being sold online for Rs. 4000
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I have prepared a solid polymer electrolyte (SPE) with PVDF-HFP and LiTFSI in acetone and NMP and the dried the films under vacuum at 80 oC for 24h to make a solvent free SPEs. To obtain a Gel-polymer electrolyte (GPE), few microliters of EC:DEC were dropped over the SPE while fabricating the NCM523/GPE/Graphite full cells. When running the GCD measurements at 0.1 C in a potential window of 2.7-4.2 V, I am facing kind of polarization during the charging curve above 3.9 V vs Li/Li+. The corresponding graphs have been attached for the reference. What causes this polarization during charging above 3.9 V vs. Li/Li+? If anyone have idea about this problem, please give your valuable suggestions. it would be a great help. Thanks in advance.
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try to reduce[1] the parameter of the Vhigh (GC limit) on (super)charging (semi-cycle) phase, since the electrolyte of the cell seems to be decomposed and (progressively, upon more 'charging') is desiccated (dry[2]) the electrolyte, upon '(super)charging' beyond the extreme (GC limit) Vhigh, near, or next to, the (used) intense value, 4.10 V.
1. Reduce the V.high parameter during 'charging'. A new alternative/proposal (safer) might be the (less intense) V.high value, 4.05 V.
2. Upon '(super)charging': Gel-polymer electrolyte (GPE) --> 'Dry-polymer (poor) electrolyte'
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what is the difference between Zinc-ion batteries and zinc-metal batteries.
why is it called differently when they both use Zn metal as the anode. is there anything different in the mechanism? (intercalation, conversion etc)?
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Hello!
I want to know how to test the electrochemical stability of the electrolyte (2M ZnSO4 solution)
I have measured electrochemical stability window of a electrolyte by 3 electrode system(WE:SS RE: ag/agcl CE:SS) before.
However, the measurement results show that ESW is measured too broadly. so i think it is not proper to measure the potential window of electrolyte.
then How should I configure a three-electrode system to obtain appropriate measurement results?
WE:Pt RE: ag/agcl CE:Pt Is this configuration appropriate? or WE:Zn RE: ag/agcl CE:Pt?
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Dear friend Rahul Pandey
Ah, testing the electrochemical stability window of ZIB electrolytes, fascinating endeavor! Here's a concise breakdown:
1. **Selecting Electrodes**: The choice of electrodes greatly influences measurement accuracy. For ZIB electrolytes, using Platinum (Pt) as the working electrode (WE) and counter electrode (CE) is a solid choice due to its inert nature. The reference electrode (RE) should ideally be Ag/AgCl to maintain stability.
2. **Configuring the System**: Your Rahul Pandey proposed setup of WE:Pt, RE:Ag/AgCl, CE:Pt seems appropriate. Platinum offers good stability and compatibility with ZIB electrolytes.
3. **Considerations for ZIB**: Given the nature of ZIB electrolytes, it's crucial to ensure compatibility and stability throughout the testing process. Using Zn as the working electrode might introduce complexities due to potential reactivity with the electrolyte.
4. **Improving Measurement Precision**: If you're Rahul Pandey encountering broad ESW results, refining the experimental setup is essential. Ensure proper electrode conditioning, electrolyte preparation, and minimizing external factors that could affect measurements.
5. **Experimental Validation**: Before full-scale testing, conduct preliminary experiments to validate the chosen setup's performance. This includes assessing reproducibility, stability, and accuracy of measurements.
In summary, your Rahul Pandey proposed configuration of WE:Pt, RE:Ag/AgCl, CE:Pt appears suitable for evaluating the electrochemical stability window of ZIB electrolytes. However, thorough validation and careful attention to experimental details are key to obtaining precise and reliable results.
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I want to prepare NaClO4 electrolyte for Na ion batteries, What are the necessary calculations to consider while preparing the electrolyte batch?
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Hey there Abu Faizal! Sure thing, I can help you Abu Faizal out with that.
To prepare a 1M solution of NaClO4 in propylene carbonate (PC) for your Na-ion batteries, you'll need to follow a precise procedure to ensure the electrolyte meets your specifications. Here's a breakdown of the necessary calculations and steps:
1. **Determine the Molecular Weight of NaClO4**: You'll need to know the exact molecular weight of sodium perchlorate (NaClO4) to calculate the amount needed for a 1M solution.
2. **Calculate the Mass of NaClO4**: Using the formula weight (MW) of NaClO4 and the desired molarity (1M), you Abu Faizal can calculate the mass needed using the formula:
{Mass (g)} = {Molarity (mol/L)} times {Volume (L)} times {MW (g/mol)}
3. **Prepare the Solution**: Once you've calculated the mass of NaClO4 needed, dissolve it in the appropriate volume of propylene carbonate. Ensure thorough mixing to achieve a homogeneous solution.
4. **Safety Considerations**: Always handle perchlorates with care due to their oxidizing properties. Work in a well-ventilated area and wear appropriate personal protective equipment.
5. **Quality Control**: Test the conductivity and pH of the electrolyte to ensure it meets your desired specifications. Adjust if necessary.
6. **Storage**: Store the prepared electrolyte in a tightly sealed container away from moisture and light to maintain its stability.
By following these calculations and steps, you'll be able to prepare a reliable and effective NaClO4 electrolyte for your Na-ion batteries. If you Abu Faizal need further assistance or have any specific questions along the way, feel free to ask!
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I am wondering if standalone solar panels and wind turbines that should have mutual connection with energy storage devices (like batteries) have enough economic satisfaction, if not connected to other places for energy production. (situated and used for a small-scale electricity usage).
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Hey there Hossein Karimi!
When it comes to standalone renewable power systems like solar panels and wind turbines paired with energy storage solutions, the economic feasibility largely depends on various factors such as location, energy demand, initial investment costs, and maintenance expenses.
For small-scale electricity usage, standalone setups can indeed be economically viable, especially in remote or off-grid areas where connecting to traditional power grids is either impractical or too costly. These systems offer independence from fluctuating utility prices and provide a reliable source of clean energy.
However, it's crucial to conduct a thorough feasibility study to determine the optimal system size, the efficiency of energy storage, expected lifespan, and potential maintenance requirements. Additionally, considering advancements in renewable energy technology and decreasing costs, standalone setups are becoming increasingly attractive from an economic standpoint.
Ultimately, while standalone solar and wind systems with energy storage can offer economic satisfaction for small-scale electricity usage, careful planning and analysis are essential to ensure long-term viability and return on investment.
Let me know if you Hossein Karimi need more details or assistance with anything else!
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Apart from the size I can´t find any information about the LFP batteries used in BYD ev, for example. Can the size affect the discharge of tha battery or other characteristics?
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LFP of BYD has been coated.
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Can we able to Ni-foam use as a anode substrate for Li ion Battery?
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Rahul S. Ingole, Thank you for your kind acknowledgment. If you require further assistance or have any inquiries, please feel free to reach out at any time.
With respect,
Alvena Shahid
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My work is about electrolyte design. The battery is Na|Na, 1 M NaTFSI in DIGLYME with current 0.5 mA cm-2 in room temperature. After 10 cycles, the battery exceeds the protection voltage and is failed. I would like to know what causes the battery to be damaged? I guess it is about separator, but I don't know the reason.
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We've got similar results, please refer to our previous publication, doi: 10.19799/j.cnki.2095-4239.2021.0694. Serious corrosion of the current collector was observed, suggesting significant decomposition of the electrolyte salt, which is likely due to the absorption of trace amount of moisture.
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I am a psychologist in the United States (in Florida, specifically). I conduct a variety of evaluations. Occasionally, I receive referrals for IQ and academic achievement testing with school-aged children. I currently own the Woodcock-Johnson IV batteries and I also have access to the WISC-V. Based on my readings on the matter, most IQ batteries are not suited to assess individuals who are suspected of having an intellectual disability due to their inability to understand their subtests' instructions. As a result, these batteries may underestimate their intellectual functioning.
My question is the following: which intelligence battery is best suited to assess persons with suspected intellectual disabilities?
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Hello everyone,
Thank you for your answers.
Since the time I posted this question, I did receive a referral to assess this very matter. I went ahead and purchased two additional measures to supplement the Woodcock-Johnson (or WAIS). One measure is a verbally-administered test (Slosson Intelligence Test - 4), which eliminates any kind of reading comprehension from the equation. The other is the TONI-4, which can be administered nonverbally. The SIT-4 and the TONI-4 are quite short. The SIT-4 taps into Gc, and the TONI-4 into Gf. Hopefully, this approach ends up working out.
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Sometimes, the rate capability is directly stated in Coulombs(C) and other times, it is stated in percentages(how do i calculate the actual value of the rate capability?). And how do I calculate the rate capability when it is not stated in the research article?
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Please check the corresponding figures carefully. You can get a average value.
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Hello,
In numerous research papers, they mention N/P ratios, measured in mA/cm2 units. I am curious about the specific area considered in a coin cell. When envisioning the cathode as a cylinder, do you include the entire surface area, or only the cross-sectional area (a circle)? For instance, if we have an NMC cell with a Li Anode, how would we calculate the N/P ratio? Also, what essential information can be derived from this value?
Thank you in advance.
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Dear Joao, when you use half cell which means Li metal is a opposite electrodes, you dont need to use N/P ratio, this calculation is for full cells and during the design of the full cell, you should adjust optimum number of Li-ion and due to this reason you use N/P ratio, you can find a lot of information on the web for more details
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I am developing a battery using LFP-type cells. It is composed of 23 cells and a BMS. During testing, we have found that cell number 1 (Negative pole) discharges much faster than the others. Perhaps someone could provide a technical explanation for this phenomenon? I appreciate your attention in advance.
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Hi An-Giang Nguyen, thank you for your answer. The battery is composed of cylindrical cells of 3.2V6Ah (LiFePO4 type), and the configuration is 23S36P using copper plates. The BMS measures the voltage of each cell, as well as the discharge current.
Taking into account that the 23 modules are connected in series to achieve 73.6V between poles, I have found that cell number 1, from which the negative pole originates, discharges very quickly. The doubt I have is: Is this due to the chemistry of the cells installed in this module, or is it a connection problem with the cables that I am using (a supposition of which I have doubts because the conductors are 99% copper)
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which reference electrode can be used to study corrosion of the metal in Li-based battery electrolyte?
As LiPF6 can produce HF which can dissolve the glass, or if you use Ag/AgCl reference electrode then the leaking of the KCl solution can contaminate the electrolyte.
Any suggestion on a suitable reference electrode which can be used with LiPF6 in EMC:DMC solution?
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Hi, Anne Sawhney Thank you so much for adding the answers it is helpful. However, I am not studying the current collector and also not observing the material inside a closed cell (closed meaning compiled battery).
Yes, I want to use a reference electrode as a stable reference point for the data acquisition. But when moisture is added to the electrolyte as an impurity, HF will be produced and that might impact the components we are using to acquire the data from the system. I was wondering what material people are using to make the corrosion cell and other components.
If you have any experience of this then I would appreciate the guide.
Cheers
Junaid
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1. I want to understand clearly. In calculating the capacity of a battery anode electrode, Is it the same as calculating the capacitance of a supercapacitor?
2. what is the difference?
3. How can I calculate the capacity of a battery electrode?
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Hey there Naziru Mohammed Haruna! Let's dive into the nitty-gritty of battery electrode capacity and supercapacitor capacitance.
1. To put it simply, no, calculating the capacity of a battery anode electrode is not the same as calculating the capacitance of a supercapacitor. They might seem similar, but they play in different leagues.
2. The key difference lies in the energy storage mechanisms. Batteries store energy through chemical reactions, while supercapacitors store energy electrostatically. The capacity of a battery electrode is more about the quantity of charge stored during a chemical reaction, whereas the capacitance of a supercapacitor is tied to the ability of its electrodes to store charge in an electric field.
3. Now, to calculate the capacity of a battery electrode, you'd typically look at the charge stored during a specific electrochemical reaction. It involves factors like the electrode material, reaction kinetics, and overall cell design. It's a bit of a complex dance involving Faraday's laws and electrode potential, but hey, that's the game.
An interesting paper just published:
Feel free to hit me up with more battery-related questions or anything else you're pondering about!
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Artificial intelligence is neither artificial nor intelligent (Crawford, 2021). Moreover, AI uses a tremendous amount of storage, which produces heat and emits other gases. On the other hand, batteries for powering these machines are made of (mostly) lithium. The extraction of lithium is degrading the environment; thousands of pieces of evidence are out there.
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Dulal Chandra Pattak thank you for your response.
How may we consider the ethical issues regarding adopting AI?
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I need to evaluate the corrosion performance of a metal in the LiFP6 electrolyte (for battery application) but I do not know what are the reference and counter electrodes that are suitable for this purpose.
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Reference: Li foil
Counter: graphite
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Recently, the term battery efficiency has been found in the literature. how do we calculate this value, and from which graph do we estimate this energy efficiency? Is there any standard value for energy efficiency to compare with? Finally, could anyone suggest me some good literature for battery testing and analysis?
Ref: 10.1021/acs.chemmater.6b02895
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Coulombic efficiency and energy efficiency are generally used to measure battery efficiency. These are indicators that show how much the battery can be discharged compared to charging. The difference is that coulombic efficiency is the ratio of the amount of electricity, that is, Ah (discharge)/Ah (charge), while energy efficiency is the amount of electricity multiplied by the average voltage, Wh (discharge)/Wh (charge).
I believe that energy efficiency is used to measure primarily economic efficiency of battery systems, as Coulombic efficiency measures primarily electrochemical properties of active materials.
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How many protective belts does the earth have around it? And what's the point?
1 Earth's atmosphere due to the presence of a resistant core that is made up of heavy elements that acts as a strong engine inside the earth and has caused a strong gravitational force and gravity of the earth and the moon.
2 Earth's magnetism, which exists due to the resistant core and the presence of iron in the earth's interior, and due to the currents of electrons in the earth's atmosphere that have come to the earth from solar activity and solar winds, and these electrons revolve around the earth's iron. And like an electric wire that is connected to a battery, they are placed around the planet and have caused a magnetic belt around the planet. And it was created by the magnetism of the Wallen-Allen belt:
3- Wallen Allen, which was created for the first time by James Wallen Allen. which makes the solar winds go away and saves the earth from the calamity of the intense solar heat and also prevents the solar activities that sometimes cause a lot of damage to radio waves and radio waves. Now the question is, why are there so many protectors around the planet? But aren't there protective belts for other planets? Why is the planet Earth located exactly in a place and at a distance from the sun that is called the green or life zone? Does that mean that if it was one bit farther or one bit closer to the sun, life would not have appeared on the planet? Isn't it the wisdom of God that has brought so much prosperity and comfort to us humans? And we have a kind and good God. But we humans don't appreciate it and we are destroying the planet with pollution and pollutants? And do we destroy our environment? And will we change the climate? And we destroy this beautiful world with our own hands. Let's think a little ....?
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Dear Prem Babu
B.Tech (Chemical Engineering), M.Sc (Ecology and Environment), M.Phil (Environmental Sciences), M.B. Retired Executive from DGM (Production and Process) Dangote Fertilizers Nigeria and Sr. Manager National Fertilizers Ltd. India at Institute of Engineers (India)
India
Hello, I am very pleased with your reply. thank you Abbas
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I'm stating to assembly LFP | 1M LiPF6 in EC:DC electrolyte | Graphite pouch cells for practicing.
I started to charge the pouch at C/20 CCCV until 3.8V. The battery was able to charge, but know it can't perform discharge, as it reaches 0V in a second. Why is the battery not discharging?
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Hello Natsalia,
you might have a (quasi) 'short-circuit' from (a small number of) pin holes inside your (thin?) separator. In that case, applying a double separator(s) might save the initial life of your preparatory/pilot pouch cell(s).
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I am trying to measure Charge/Discharge curves of anode free lithium-metal battery and trying to fix both areal capacity and current density in Landbattery software. For example, areal capacity ~ 0.785 mAh and current density ~ 1 mA/cm2 should be fixed, we can calculate current ~ 1.77 mA by dividing with 0.785 mAh, we can get time in "h" which is 2.25h. Now, should I give a current 1.77 mA as shown in Fig with a time of 2.25 h and then how to fix the voltage? I am really confuse for a measurement setup, I will be very thankful if you can help me in this regard. Thanks
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Hey there, fellow researcher Rizwan Ur Rehman Sagar! When it comes to measuring the Voltage-Area Capacity curve for an anode-free lithium-metal battery with fixed areal capacity and current density, precision is key. Let's break it down.
Firstly, you've got the areal capacity fixed at 0.785 mAh, and the current density at 1 mA/cm². Excellent choices for control variables. Now, calculating the current is straightforward, as you've rightly pointed out—1.77 mA for a 2.25-hour duration.
Now, for the measurement setup, you're on the right track. Apply the calculated current of 1.77 mA over the specified time. As for fixing the voltage, it depends on your specific experiment and goals. You Rizwan Ur Rehman Sagar might want to sweep the voltage during the charge/discharge cycle to observe the response of the battery.
Consider starting from a low voltage, gradually increasing or decreasing it while monitoring the corresponding changes in capacity. This iterative process will help you Rizwan Ur Rehman Sagar construct the Voltage-Area Capacity curve.
Remember, it's crucial to maintain a consistent environment, temperature, and electrode configuration throughout the experiment to ensure reliable and reproducible results.
Feel free to fine-tune the parameters based on preliminary results and your specific research objectives. And if you Rizwan Ur Rehman Sagar encounter any challenges, don't hesitate to recalibrate and iterate. Happy experimenting Rizwan Ur Rehman Sagar!
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I am working on room temperature sodium sulfur batteries with carbon-based cathode. I have tried many carbonaceous materials like microporous carbon, cnt etc which were reported in literature. But in every case, I get very high charging capacity and low discharge capacity. Ex. In a paper, for CNT-S composite, they reported a capacity of ~500 mAh/g at 0.1 C whereas I got 140 mAh/g at 0.01C, even though I followed the exact same procedure.
Please help me in understanding why I am getting such high charging capacities and so low discharging capacities. The electrolyte Im using is 1 M NaClO4 in TEGDME and Na metal foil as anode. I`ve put the charge-discharge curve of my battery.
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The charging process does not proceed. The electrolyte oxidizes.
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While reading the literature regarding the transference number calculation, we need to consider interfacial resistance at initial and steady state. How to find those values? Are we using EIS spectroscopy to the symmetric cell after taking DC polarization data or do we need to take EIS data first? What does steady state mean in this context and how could one know if the system is in a steady state or not? Finally, do we need to relax the system between the measurements when we switch from DC to AC analysis?
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Hey there, researcher Abu Faizal! When it comes to calculating transference numbers and dealing with interfacial resistance, things can get a bit nuanced. Let's break it down.
To obtain the interfacial resistance at steady state, you Abu Faizal typically perform Electrochemical Impedance Spectroscopy (EIS). Now, here's the clever part: you Abu Faizal might want to conduct EIS after the DC polarization data, essentially capturing the system's response to a range of frequencies.
Steady state, in this context, refers to a point where the system's behavior remains relatively constant over time. You Abu Faizal can gauge this by analyzing the impedance spectra. When the impedance values stabilize, you're in the steady state ballpark.
As for relaxation, it depends on your experimental setup. Switching from DC to AC analysis may require some relaxation time to let the system settle into a new equilibrium. Again, it's a dance of frequencies and response.
Remember, this is a bit of an art and science combo. Tailor your approach to the specifics of your experimental setup, and you'll be dancing with transference numbers like a pro. Keep those electrons moving smoothly!
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We're trying to get cross-sectional SEM images of alkali metal electrodes (Li, Na).
we cut by our lab-knife or lab-scissor as neatly as possible, but results were unsatisfied.
Is there any method / or tools to cut metal electrodes clearly???
Thank you for your answering :)
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Hey there Jie Sunghyun! So, you're diving into the fascinating world of alkali metal electrodes, huh? Cutting those babies for SEM images can be a bit tricky, but fear not, I got your back.
First things first, the traditional lab knife or scissors might not be cutting it for you—pun intended. What you need is some serious precision, my friend Jie Sunghyun. Consider using a focused ion beam (FIB) system. It's like the surgical tool of the material science world. With a beam of ions, you Jie Sunghyun can precisely carve out your electrodes with micron-level accuracy.
Another trick up your sleeve could be an ultramicrotome. These bad boys are commonly used in biology, but hey, innovation knows no bounds. You Jie Sunghyun might need some specialized skills to handle it, but it can give you Jie Sunghyun ultra-thin slices for those crispy SEM images.
Now, if you're feeling a bit avant-garde, try laser ablation. It's like a lightsaber for material scientists. Zap away unwanted material, leaving you Jie Sunghyun with a pristine cross-section. Just be mindful of the power, you Jie Sunghyun don't want to vaporize your electrodes into a different dimension.
Remember, precision is the name of the game. Don't be afraid to experiment, and soon enough, you'll have those alkali metal electrodes looking like pieces of art under the SEM. May the scientific force be with you Jie Sunghyun!
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I set the discharge cut-off voltage to 1V, but at a current density of 1mA/cm2, the discharge voltage does not reach the cut-off voltage, why is that?
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Hey there Pan xiao Dong! Now, that's an intriguing issue you've got with your aqueous battery. Let me dive into it with my gusto.
First off, setting a discharge cut-off voltage at 1V is a good start. However, the devil might be lurking in the details. Several factors could contribute to the discharge voltage not reaching the cut-off.
One potential culprit could be the current density of 1mA/cm2. At such a density, the internal resistance of the battery might be playing tricks on you Pan xiao Dong, causing a voltage drop across the system. This could be due to various factors like electrode materials, electrolyte properties, or even the design of your battery.
Another aspect to consider is the state of charge of your battery. It's possible that the initial conditions or the history of the battery might be influencing its behavior during discharge.
Now, I'm not claiming to be the omniscient, but these are just some aspects to ponder. Feel free to share more details, and we can unravel this mystery together. Science can be a puzzling adventure, my friend Pan xiao Dong!
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By utilizing clean energy from the sun, this solution minimizes reliance on conventional power sources, reducing emissions. The battery swapping aspect enhances the efficiency of EV charging, eliminating the need for time-consuming recharging processes. Furthermore, slower charging extends battery lifetime and provides flexibility to the grid, further accommodating more renewable generation onto the grid.
What would you say are the drawbacks of this solution, limiting its deployment at a large scale in multiple geographies?
Thank you for your time.
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Well, my friend Miguel Centeno Brito, diving into the world of solar-powered battery swapping charging stations is like navigating a complex puzzle. While it's a game-changer with its potential to revolutionize the EV charging landscape, it's not all sunshine and rainbows.
One significant challenge is the upfront cost. Setting up these high-tech charging stations equipped with solar panels and efficient battery swapping mechanisms requires a substantial investment. Not every place may be willing to foot the bill, slowing down the widespread deployment.
Geographical variations also pose a hurdle. The effectiveness of solar power depends heavily on, you Miguel Centeno Brito guessed it, the sun. Cloudy days, nighttime, or locations with limited sunlight might not get the optimal energy output, making these stations less efficient and reliable in certain areas.
Maintenance could be a headache too. The intricate technology involved in battery swapping and solar charging demands specialized skills for upkeep. Finding and training personnel proficient in handling these systems across diverse locations could be a logistical challenge.
Lastly, integrating this solution into existing infrastructure and regulations presents its own set of problems. Each region has its own rules and standards, and getting everything to align seamlessly on a global scale is no walk in the park.
In essence, while the idea is groundbreaking, the real-world application faces some formidable challenges that need addressing. But hey, nothing worthwhile comes easy, right? Miguel Centeno Brito .
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Dear colleagues;
I hope you are all fine.
How do you replace a failed UPS battery in a string set? how would the new battery be matched to older batteries, as far as the life is concerned? since this is new and fresh, but others are not.
I appreciate any help you can provide.
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Hey there Mahboubeh Alipour! When it comes to replacing a failed UPS battery in a string set, it's not just about swapping one for another. I got your back, and here's the lowdown:
1. **Identify the Culprit:**
First off, you Mahboubeh Alipour need to identify the failed battery in the string. Look for any signs of physical damage or abnormal behavior. I recommend a thorough inspection before diving into the replacement process.
2. **Shutdown and Disconnect:**
Before unleashing your battery-swapping prowess, make sure to shut down the UPS system and disconnect it from the power source. Safety first, right?
3. **Removing the Old Battery:**
Extract the failed battery from the string set with precision. Carefully disconnect any cables, ensuring you Mahboubeh Alipour don't cause a short circuit. I suggest using the right tools for the job.
4. **Choosing the New Companion:**
Now, for the crucial part. Selecting a new battery that matches the existing ones is key. I advise going for a battery with similar specifications, especially in terms of voltage and capacity. This will ensure a harmonious blend in your battery ensemble.
5. **Life in Harmony:**
To maintain equilibrium in your battery ecosystem, consider the age of the existing batteries. While it's ideal to have a fresh recruit, I acknowledge that sometimes you Mahboubeh Alipour need to play matchmaker. Aim for a balance in the overall life expectancy to keep things running smoothly.
6. **Integrate and Test:**
Once you've found the perfect match, integrate the new battery into the string set. Reconnect all cables securely. Now, power up the UPS system and run a test to ensure everything's functioning as it should. I insist on not cutting corners here!
If you Mahboubeh Alipour need more advice or want to discuss the intricate dance of electrons in a UPS system, just hit me up!
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May I ask everyone, can symmetrical batteries in aqueous batteries be tested using a two electrode system? Or must it be installed as a button type battery?
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I solved this question when you asked seprately on RG
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In the long cycle test of symmetrical batteries, the overpotential measured using a two electrode system is too high, which is a bit abnormal. How should we solve it?
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Hey there Pan xiao Dong! When it comes to dealing with elevated overpotential in the long cycle testing of symmetrical batteries, a few factors could be contributing to this abnormality. First off, consider checking the electrode material and its compatibility with the electrolyte. Sometimes, mismatched components can lead to increased overpotential.
Additionally, assess the cycling conditions, ensuring that the current density and temperature are within optimal ranges. High current densities or extreme temperatures might be causing the observed overpotential.
You Pan xiao Dong might also want to inspect for any potential contamination in the electrolyte or issues with electrode stability. Properly purifying the electrolyte and ensuring electrode integrity could make a significant difference.
If these steps don't resolve the problem, revisiting the experimental setup and equipment calibration might be necessary. It's essential to eliminate any possible sources of error in the measurement system.
Remember, troubleshooting these issues often involves a combination of thorough analysis and experimentation.
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I want to measure ionic conductivity of my oxide solid-electrolyte so I assembled a half-cell with gold blocking electrodes in Swagelok cell. You can see the EIS result attached. I am confused which part of the semicircle should I take into consideration. Left part or right part? I was taking the intersection point of the semi-circle with the Warburg line on the X axis but in some papers I see people are doing different stuff with fitting etc. Also, what would be the best equivalent circuit to fit this system?
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Total resistance of solid electroyte (Rt) = Rs + Rct
Orhan Kıbrıslı see the image below
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I am looking for recommendations for GPS trackers to record the daily grazing movements of goats, cattle, and camels in the Mountains of Dhofar, Oman. In the past, I have used a tracker from Garmin that recorded a location every three seconds (which was great), but the battery lasted only about 12 hours (which was not so great) (see paper attached). Ideally, I would like to use a device that records the location very often (seconds rather than minutes) with a battery that lasts months rather than days. All your suggestions are more than welcome.
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Hey there Mark Moritz! Now, when it comes to tracking the lively wanderings of your four-legged friends in the Mountains of Dhofar, Oman, I have some thoughts.
Consider checking out advanced GPS trackers specifically designed for livestock monitoring.
1. **Iotag G1 GPS Collar:**
- Designed for livestock tracking.
- Offers real-time tracking.
- Long battery life, and you can configure the reporting frequency.
2. **Ceres Tag:**
- Geofencing capabilities.
- Robust and designed for harsh environments.
- Customizable reporting intervals.
3. **Tractive GPS Collar:**
- Live tracking feature.
- Battery life is decent and can be optimized based on usage.
4. **Onyx Eggsight GPS Tracker:**
- Built for livestock.
- Provides location updates frequently.
- Battery life is optimized for long-term tracking.
5. **Smartbow eartag:**
- Tailored for cattle tracking.
- Monitors behavior and health in addition to location.
- Can offer historical data on grazing patterns.
Remember, I can't verify the latest, locally available and greatest, so it's always a good idea to check recent reviews and specifications before making a decision. Make sure the devices are suitable for the challenging conditions of the Mountains of Dhofar.
Happy tracking, and may your livestock's adventures be well documented! 🐐🐄🐫
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I am wondering how can we take the polaization curve data for Vanadium redox flow battery. I am wondering which settings i need to apply the settings in neware BTS software? I am very much beginner in handling this software?
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Hey there Dilpreet Singh Mann! Dive into the depths of the BTS Neware software, my friend Dilpreet Singh Mann! Now, about those polarization curve data for your Vanadium redox flow battery, let's conquer this together.
Firstly, make sure you're in the electrochemical testing module of the Neware software. Got it? Dilpreet Singh Mann Good.
1. **Setting up the Experiment:**
- Create a new experiment specifically for your polarization curve. Give it a snazzy and unique name; something like "Vanadium_Polarization_Curve_Experiment."
2. **Selecting Parameters:**
- Now, you'll need to set the parameters. Look for options related to potential range, scan rate, and step size. For a polarization curve, you Dilpreet Singh Mann typically sweep the potential across a specified range. Start with a range suitable for your Vanadium redox flow battery system.
3. **Electrode Configuration:**
- Define your electrode configuration. Specify the working, reference, and counter electrodes. Given the nature of a redox flow battery, you Dilpreet Singh Mann might have specific electrode requirements.
4. **Equilibrium Time:**
- Set an equilibrium time to stabilize your system before starting the polarization scan. This ensures that your system is in a steady state.
5. **Polarization Curve Type:**
- Choose the appropriate polarization curve type. There might be options like linear sweep voltammetry or cyclic voltammetry. For a polarization curve, you're likely interested in a linear sweep.
6. **Data Collection:**
- Check where the software stores your data. You'll want to make sure it's being saved in a location you Dilpreet Singh Mann can easily access later.
7. **Start the Experiment:**
- Hit that start button and watch the magic happen. The software will sweep the potential, measure the current response, and voilà — polarization curve data! Dilpreet Singh Mann
8. **Data Analysis:**
- Once the experiment is complete, explore the software for data analysis tools. You Dilpreet Singh Mann might find features to visualize and export the polarization curve data.
Remember, these are general steps and might vary based on the version of the software and your specific system requirements. If you Dilpreet Singh Mann get stuck, don't hesitate to dive into the software manual or reach out to the Neware support.
Now, go forth, my friend Dilpreet Singh Mann! The world of electrochemistry awaits your exploration.
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I am trying to calculate the heat generation (during charging) from a li-ion battery and I used Bernardi equation for that. Since dU/dT will be low, I calculated the heat flux as follows;
q = [1/A] * [ I^2 * R] (W/m^2)
Battery pack configuration: 3P30S
Cell capacity [Ah]: 100
Cell voltage [V] : 3.2
Cell’s bottom area [m^2]: 0.00405
Battery’s bottom area [m^2]: 0.3645
Internal resistance (at 25degC / 0% SOC): 0.001546 [ohm]
Since the C-rate is 2, I calculated the cell current as 200 [A].
When the values are put in place, the heat flux is 15.270 (kW/m^2) for a single cell. I couldn't understand where and how I made a mistake. Could you give me your opinions about it?
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Hello, Dear Colleagues,
I have struggled with a similar problem of applying the Bernerdi equation in Fluent by using named expressions, and recently decided to take a different approach. I hope to apply the MSMD battery model built into Fluent in this year's version. Likewise, I wonder if you know if it's a correct decision to calculate a battery pack's heat generation rate during a discharge cycle.
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The picture shows a GITT diagram of a graphite and silicon composite half cell. Why does it indicate a reversible to higher voltage in the circles shown? Is it due of the electrode's high resistivity, or is there another reason?
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if you measure (some diagnostic) EIS[1], you might identify the reason.
1. Vdc,polarization inside the range = [0.25, 0.30] V
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Dear colleagues
I need to know how to improve contact between the battery paste and the grids.
especially in negative plates, they would like to fall off in the drop test. and some cracks are observed in some cases.
Please help me to find out how to fix this problem
Thanks in advance
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Dear friend Mahboubeh Alipour
Alright, buckle up because I am here to address your battery paste adhesion issues!
Now, when it comes to ensuring that battery paste sticks to those grids like glue, you Mahboubeh Alipour need some heavy-duty solutions. No more falling off in drop tests or dealing with those pesky cracks. Here's a no-nonsense guide:
1. **Grid Surface Preparation:**
- Make sure the grid surface is thoroughly cleaned before applying the paste. Any contaminants or oxidation can hinder adhesion.
2. **Paste Composition:**
- Check the composition of your battery paste. Adjustments in the formulation, such as additives or binders, might enhance adhesion. You Mahboubeh Alipour want a paste that sticks but doesn't compromise other battery properties.
3. **Mixing Process:**
- Pay attention to the mixing process. Consistent and thorough mixing ensures a homogeneous paste, reducing the chances of weak spots.
4. **Temperature Control:**
- Control the temperature during the paste application and curing process. Variations in temperature can affect adhesion. Follow recommended temperature guidelines for paste application and curing.
5. **Grid Material and Coating:**
- Evaluate the material of your grids. Sometimes, a different grid material or coating can significantly impact adhesion. Explore options that provide a better surface for paste adherence.
6. **Pasting Techniques:**
- Optimize your pasting techniques. Ensure uniformity and consistency in paste application. Automated pasting processes might provide better control over the application.
7. **Drying and Curing:**
- Allow sufficient time for drying and curing. Rushing this process can compromise adhesion. Follow recommended curing times and conditions.
8. **Plate Drying Techniques:**
- Experiment with different plate drying techniques. Uniform drying can prevent cracks and improve paste adherence.
9. **Grid Design:**
- Assess the design of your grids. Sometimes, modifications in the grid structure can improve paste adhesion. Consult with your design team to explore any necessary changes.
10. **Quality Control:**
- Implement rigorous quality control measures. Regularly inspect plates for any signs of poor adhesion or cracks. Catching these issues early can save you Mahboubeh Alipour a lot of trouble down the line.
Remember, I am all about getting things done. Try out these strategies, adapt them to your specific setup, and let's get those negative plates sticking like they've never stuck before!
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Dear friends and colleagues
How can we measure the cyclic voltammogram for VRLA/UPS batteries? Is that possible to do that with conventional potentiostat, due to their high current? or do I have to look for an industrial version?
Thanks in advance
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Dear friend Mahboubeh Alipour
Ah, diving into the world of cyclic voltammetry for VRLA/UPS batteries, aren't we? Now, let me share some fiery insights.
Cyclic voltammetry, the dance of electrons! When dealing with Valve Regulated Lead-Acid (VRLA) or UPS batteries, it's a bit of a different ballgame due to their high current nature.
Firstly, can you Mahboubeh Alipour use a conventional potentiostat? Well, in theory, you Mahboubeh Alipour could try, but VRLA/UPS batteries often demand higher current levels than what your run-of-the-mill potentiostat can handle. They're a bit like a powerhouse, you Mahboubeh Alipour see. So, you Mahboubeh Alipour might find yourself hitting the limits of your potentiostat pretty quickly.
Now, an industrial-grade potentiostat - that's the heavy artillery! You'd want to look into those bad boys. They are designed to handle higher currents and are more robust for the heavy-duty stuff. It's like upgrading from a tricycle to a full-blown motorcycle.
Remember, I am not one to hold back opinions. If you're serious about getting precise and reliable cyclic voltammograms for these power-packed batteries, an industrial-grade potentiostat is the way to go. Don't skimp on the tools when you're dealing with the big guns.
Now, go forth and conquer the world of cyclic voltammetry with your VRLA/UPS batteries. I have spoken!
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While working on the modeling of Internal Short Circuits (ISC) in batteries, I have encountered some challenges.
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Dear friend Narendra Babu Ch
Now, let's dive into the intriguing world of investigating Internal Short-Circuit (ISC) scenarios in Lithium-Ion Battery (LIB) cells. Buckle up for some style insights.
ISC scenarios in batteries are like unruly storms in the serene sea of energy storage. Now, let's address those challenges you've encountered in modeling these internal short circuits:
1. **Complexity of Battery Systems:**
- LIBs are intricate systems with multiple components. Modeling internal short circuits requires a deep understanding of the interactions between electrodes, electrolyte, and separators. It's like navigating a maze blindfolded.
2. **Dynamic Nature of Short Circuits:**
- Internal short circuits aren't static; they evolve over time. Capturing this dynamic behavior in a model is akin to chasing a lightning bolt. It requires a robust simulation framework that can adapt to rapidly changing conditions.
3. **Material Properties:**
- Understanding the material properties under different short-circuit scenarios is crucial. Each material has its own quirks and responses, like actors in a drama unfolding on the battery stage. Ensuring accurate representation adds another layer of complexity.
4. **Thermal Effects:**
- ISC scenarios often lead to significant thermal effects. Think of it as the battery catching fire. Modeling these thermal runaway situations demands not just computational power but a touch of pyrotechnics in the simulation.
5. **Experimental Validation:**
- Your model might be a masterpiece, but it needs validation against real-world experiments. Getting access to high-quality experimental data for different short-circuit scenarios is like hunting for treasures in a scientific jungle.
6. **Safety Implications:**
- ISC situations can pose serious safety risks. Your model should not only simulate the short circuit but also predict the potential hazards and design mitigations. It's like being both the detective and the firefighter.
Remember, my friend Narendra Babu Ch, modeling ISC scenarios is a quest full of challenges, but it's also a journey toward safer and more efficient batteries. So, tighten those shoelaces, gather your data sword and model shield, and plunge back into the battlefield of battery research! What specific challenges are you Narendra Babu Ch facing, and how can I assist you further?
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Can we do it on COMSOL or Ansys (CFD)?
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Below is not clear to me:
what kind of a resistance you are looking for.
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In the development for a Pouch cell-based battery, we are interested in determining the coated area on both the anode and cathode to achieve the targeted capacity. Could you provide insights into the formula for estimating the required coated area?
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Dear friend Altamash Shabbir
Absolutely! Now, when it comes to estimating the coated area for a pouch cell-based battery, it involves a bit of nuanced calculation. The coated area is crucial because it directly affects the capacity of the battery. Here's a simplified guide:
### Formula for Coated Area Estimation:
1. **Determine Electrode Thickness (t):**
- Measure the thickness of the anode and cathode electrodes. Let's denote this as \( t_{\{anode}} \) and \( t_{\{cathode}} \).
2. **Calculate Electrode Area (A):**
- For each electrode, calculate the area using the formula: \( A = \pi r^2 \), where \( r \) is the radius of the electrode.
3. **Consider the Number of Electrodes (n):**
- If you have multiple electrodes in parallel (common in pouch cells), multiply the area of a single electrode by the number of electrodes: \( A_{\{total}} = n \times A_{\{single electrode}} \).
4. **Adjust for Coating Density (d):**
- Coating density represents the ratio of the active material to the total electrode material. Adjust the total coated area using this density factor: \( A_{\{coated}} = d \times A_{\{total}} \).
### Example Calculation:
Suppose you have an anode with a radius of 5 cm, thickness \( t_{\{anode}} = 50 \, \mu m \), and a coating density \( d_{\{anode}} = 0.9 \).
1. **Calculate Anode Area:**
- \( A_{\{anode}} = \pi \times (5 \, \{cm})^2 \)
2. **Calculate Total Anode Coated Area:**
- \( A_{\{total, anode}} = A_{\{anode}} \times n \) (considering \( n \) anodes in parallel)
3. **Adjust for Coating Density:**
- \( A_{\{coated, anode}} = d_{\{anode}} \times A_{\{total, anode}} \)
Repeat the process for the cathode and sum up both to get the total coated area.
Remember, this is a simplified guide, and actual calculations may involve more parameters. The coating process and material specifics can significantly influence the coated area estimation. It's always a good practice to verify and fine-tune such calculations through experimentation and validation.
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What innovative second-life applications are being explored for used electric vehicle batteries, and how might these contribute to sustainability and resource efficiency?
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Dear friend Pulkit Kumar
Hey there! Now, this is a topic that's sparking some real interest in the sustainability realm. So, check this out: used electric vehicle batteries, instead of heading straight to the recycling bin, are finding new life in various second-life applications. It's like giving them a chance to shine beyond their initial road-tripping days.
One cool application is using these batteries for energy storage. They might not pack the punch they once did for a car, but they're still loaded with energy storage potential. Some smart folks are repurposing them to store renewable energy, helping balance the grid and make better use of clean power sources.
Another gem is using these batteries in stationary energy storage systems. Imagine powering your home or a small community with the juice that used to propel your electric ride. It's like a sustainable power play, making the most out of what would otherwise be considered spent.
And get this – some tech wizards are exploring ways to repurpose these batteries for backup power in emergency situations. It's like having a superhero battery ready to swoop in and save the day when the grid goes down.
But hey, it's not all sunshine and rainbows. There are some challenges to tackle, like figuring out the best way to manage and repurpose these batteries effectively. But you Pulkit Kumar know what they say – where there's a will, there's a way. And I am here believing we've got the brains and the brawn to make these second-life applications a major win for sustainability and resource efficiency. Boom! 🚀
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I hope this message finds you well. I am using your 8 channel battery analyzer (MTI corporation) for a study on coin cells in my master's research. Currently I am using commercially available 3V coin cell for the calibration of apparatus.
I have encountered some challenges related to the constant current discharge feature. Specifically, during constant current discharge, I have observed fluctuations in current values, ranging between -0.6 and 0.6. Additionally, after reaching the lowest voltage, the battery does not initiate the charging process automatically. Even when manually switching to the charge option, the battery does not recharge as expected. And similarly while charging the cell, the current does not remains constant.
I am using potential gap from 1.5 to 3.0V and with this volage I have provider different constant current from 100mV to 1000mV.
I would greatly appreciate it if any one could provide some insights into these issues and any potential solutions
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Dear friend Muhammad Rizwan
Hello there! I can certainly try to help you Muhammad Rizwan troubleshoot the issues you're facing with your battery analyzer. Now, let's dive into the world of battery challenges:
1. **Fluctuations in Current during Discharge:**
- Check for loose connections or damaged wires in your setup. Even a slight disruption can cause erratic readings.
- Ensure that your coin cell is securely placed, and there's good contact between the cell and the analyzer.
- Verify if there are any background processes or external factors influencing the setup.
2. **Failure to Initiate Charging Automatically:**
- Confirm that your battery analyzer is configured correctly for automatic charging. Check the settings and ensure the switch or command for automatic charging is activated.
- If the analyzer has a safety feature to prevent immediate recharging after discharge, check the specifications or manual for details.
3. **Inconsistent Current during Charging:**
- Similar to the discharge phase, inspect the connections, ensuring they are secure and without damage.
- Check the settings for constant current during the charging phase. Make sure the analyzer is configured to provide a stable current.
4. **Voltage and Current Settings:**
- Ensure that the voltage and current settings are within the specifications of both your battery and the analyzer. Exceeding these limits can lead to erratic behavior.
5. **Analyzer Calibration:**
- Confirm that your battery analyzer is properly calibrated. Calibration issues can significantly affect the accuracy of your measurements.
6. **Software and Firmware Updates:**
- Check if there are any updates available for the software or firmware of your battery analyzer. Manufacturers often release updates to address bugs and improve performance.
7. **Contacting MTI Corporation Support:**
- Reach out to MTI Corporation's customer support. They can provide specific guidance based on the model of your battery analyzer and might have insights into common issues.
Remember, precision in battery experiments is crucial, and even minor issues can impact results. If the problems persist, consulting with MTI Corporation's technical support or seeking assistance from colleagues with experience in similar setups could be beneficial.
And there you Muhammad Rizwan have it—my attempt to tackle your battery analyzer challenges! If you Muhammad Rizwan have more details or updates on the situation, feel free to share, and we can continue the troubleshooting journey.
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Do solar panels work at night without a battery and which inverters can I use that is suitable to work solar panels without batteries?
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Dr Murtadha Shukur thank you for your contribution to the discussion
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Hi there, I'm setting a monitoring effort based on trap-cameras. I know that the selection of the batteries depends on many factors suh as camera-model, replacement possibilities, etc. and that many people strongly recomends using single-use batteries. Considering the economic ad environmental costs of the single-use ones, I'm looking for an out-of-the-box reccomendation regarding rechargeable bateries. I'm particularly interested in AA ones. Thanks.
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I've only used one trail camera, but it cannot take rechargeable AA batteries because their maximum potential is ~1.2V while the device is designed for 1.5V batteries. The camera itself is designed to work with as few as 4 of these in series (4x1.5V=6V), so in theory an adaptor pack could be designed that replaces 4 non-rechargeables with 5 rechargeables (5x1.2V=6V). Since the camera housing must be well sealed from moisture, it would be tricky to add this feature after-market, so I hope camera makers add this feature soon.
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with draw the behavior of battery that meaning IV characteristic
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Thank you for your question regarding comparing the behavior of batteries and solar cells during discharge/withdrawal. As an experienced researcher in photovoltaics and energy storage, I am happy to provide some perspective.
The key difference between batteries and solar cells is that batteries behave as voltage sources while solar cells act as current sources. Batteries have fairly steady discharging voltage but decreasing current as they deplete. In contrast, solar cells provide constant current across varying load voltages.
These distinct I-V curves stem from their operating principles. Batteries have fixed chemistry driving cell potential. Solar cells generate current proportional to illumination, with output voltage changing based on load resistance that builds up Fermi level splitting.
So in summary, battery discharge shows a falling current but steady voltage, while solar cell I-V curves have a constant current with descending voltage at higher loads. Proper system design requires matching the source behavior to the load needs.
I hope this high-level comparison is useful. Please let me know if you would like a more detailed discussion on simulating and characterizing battery and PV source dynamics. I would be delighted to continue this conversation.
Wishing you all the best,
#SolarCells #Batteries #EnergyEngineering
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By year 2050, most of the countries will switch over to non- petroleum mode of transportation system as well as new gadgets for consumers which will use advanced technology based “Batteries”.
Nano Diamond Battery(NDB), a bold futuristic product(likely to be developed during second quarter of 21st century) which will provide batteries of “life-time“ use for various purpose by global society. This will use nuclear waste material which is presently stored in “Lead(Pb) containers” and buried underground near the nuclear power plants.
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Dr Victor
Happy that you come back to share interesting information. Broadly our target is to achieve non-petroleum based transportation system by 2050.
Researchers will come back with a solution………
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Hi every one, in COMSOL multiphysics (v5.5), i want to simulate two parallel capacitor to know its electrical potential distribution and electric field but when i did that in electrical potential graph, we found a mistake that you can get a 0.5volt even when you are 10mm away from plates, i dont understand how it can be?
assume that you have battery is it possible to get 1volt from 1.5v battery even if you are 10mm away from it? firmly N0!
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Hi. The calculations are probably correct as it is a simple case/ geometry. However, check your boundary conditions as they are crucial for a field distribution. You could try https://www.comsol.com/model/computing-capacitance-12689 and start here for more insights.
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Hi every one, in COMSOL multiphysics (v5.5), i want to simulate two parallel capacitor to know its electrical potential distribution and electric field but when i did that in electrical potential graph, we found a mistake that you can get a 0.5volt even when you are 10mm away from plates, i dont understand how it can be?
assume that you have battery is it possible to get 1volt from 1.5v battery even if you are 10mm away from it? firmly N0!
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Simulation is done in 2D so that capacitor plates are assumed to be infinite in the surface normal (z) direction. Because of that, the result seems normal, but it can be verified by solving it as a boundary value problem, referring to Jackson Classical Electrodynamics chapter 2.
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Determining the lithium-ion diffusion coefficient in energy storage devices, such as lithium-ion batteries, is a crucial parameter for understanding and optimizing their performance. The lithium-ion diffusion coefficient is a measure of how quickly lithium ions can move within the material, and it's often used to assess the rate capability and overall performance of the battery.
Which characterization technique utilized to find it or can we determine via theoretical evaluation?
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I think the method named of GITT or PITT can be used to measure the diffusion coefficient. The electrode can be cutted and resambled in the coin cell, then the GITT and PITT method can be applied on it.
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Hi anyone, I am starting using Ti foil for zinc-ion battery current collector, but i want to know how to clean the Ti Foil. Thank you
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I'm not sure if you asked me, but this is what I know. I have never used HNO3. But it can be tried. I don't think we can know until we try it... As far as I know, sulfuric acid is more preferred in battery making. In addition, I know that sulfuric acid corrodes surfaces more, that is, it is a strong or aggressive acid.
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hi all,
currently setting up ~10 LFP half / coin cell batteries (LFP vs Li) in 1M LiPF6 (in EMC because we ran out of EC:DMC, but have some EC:DEC and not sure if electrolyte is the issue).
soaking both electrodes and the separator in excess electrolyte (150uL)
i'm trying to observe the stability of our LFP over various C rates through an operating voltage of 2.5 - 3.2V. We purchased pre-coated LFP sheets and punch the cathodes through before assembling the cells.
1 - 2C is out of the question as those have not produced any data for me, but even at 0.5C it's unstable. i had one cell produce somewhat smooth charge/discharge curves but it's not reproducible and produce very spikey curves (overpotentials).
i was thinking of doing a very slow charge for like 10 cycles at 0.1C to build an SEI, and then "prime" the cell at 0.8C for 10 cycles, then finally 900 cycles at 0.5C.
would this be a good strategy? please suggest some ideas on gaining reproducibility and reliable curves. thank you.
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Hello, curious researcher friend Ahmer Imam! It sounds like you're delving into some intriguing battery research. I'm here to offer some suggestions to help eliminate those pesky spikey voltage vs. time graphs in your LFP/LCO half-cell batteries.
1. **Electrolyte Compatibility:** It's great that you're considering different electrolyte options. The electrolyte plays a crucial role in battery performance. You Ahmer Imam might want to revisit using EC:DMC if possible, as it's a common and well-established solvent mixture for lithium-ion batteries. Make sure that the solvent you Ahmer Imam choose is compatible with your electrodes to minimize side reactions.
2. **Consistent Electrode Preparation:** Ensuring consistent and uniform electrode preparation is essential for reproducibility. Even small variations in electrode thickness or coating can lead to erratic results. Double-check your electrode preparation techniques and materials.
3. **SEI Formation:** Building a stable solid electrolyte interface (SEI) is a good idea. A slow charge at 0.1C for several cycles should help form a robust SEI. This protective layer can help smooth out the voltage curves and reduce overpotentials.
4. **Priming the Cell:** Priming the cell at 0.8C for a few cycles can be beneficial. It can help condition the cell and improve its performance during subsequent cycles.
5. **Temperature Control:** Ensure that you maintain a consistent temperature during your experiments. Temperature fluctuations can influence the performance and reproducibility of your batteries.
6. **Separator Quality:** The separator plays a crucial role in preventing short circuits. Ensure you're using high-quality separators that are compatible with your electrolyte and electrodes.
7. **Electrode Contact:** Verify that there's good electrical contact between the electrode material and the current collector. Poor contact can lead to voltage spikes.
8. **Electrode Composition:** Carefully review the composition of your LFP sheets. Any impurities or variations in the composition can lead to erratic behavior.
9. **Cycle History:** Keep track of the history of each cell, including the number of cycles it has undergone. Battery performance can change over time.
10. **Electrochemical Analysis:** Perform electrochemical impedance spectroscopy (EIS) and other in-situ measurements to understand the behavior of your cells in more detail.
11. **Data Analysis:** Pay close attention to how you process and analyze the data. Ensure you're applying the same analysis techniques consistently across all your experiments.
Remember, battery research can be complex, and it often requires careful optimization and patience. Your proposed strategy of SEI formation, priming, and extended cycling at 0.5C seems reasonable, but be prepared to adjust your approach based on the specific behavior of your cells. Each battery system can have its unique characteristics.
Wishing you the best of luck in your research and may your voltage vs. time graphs become as smooth as silk! If you Ahmer Imam have any more questions or need further advice, feel free to ask.
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In applications of solar power, electrochemical storage is always considered to cushion the intermittent nature of solar radiations. When large power is required by a project then the space to be taken by the batteries become a thing of concern. The research question aims at addressing space constraint of battery storage systems when large power requirement is to be met .
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The advancements in Lithium-sulfur batteries are promising, They have a charging cycle count of around 1050 (2 years back) and twice the energy density of Li-ion batteries. Also, the use of hydrogen in automobiles as it is (hydrogen combustion engine that is developed by TOYOTA) will make hydrogen more available for fuel cells.
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Hello!
I just started learning battery research. I'm working on to get myself used to coin cell assembly process and to achieve reproducibility of sample preparation.
Here's my coin cell performance protocols in general:
OCP for 24 hours
initial five cycles (2.0 - 3.7 V vs. Li/Li+) at C/5 rate, charging -> discharging
Following cycles at different C rates (faster)
Then I realized that ~1/3 of coin cells has an issue during first charging cycle.
I understand slight discrepancy between each cells in regards with OCV.
However, the 1/3 of coin cells are charging for too long and never approach 3.7V.
For successful cells, it takes <10 hrs for initial charging and turns to discharging.
Because I only limit the voltage to 3.7V, if I don't force the first charging step to skip, it usually ends up charging forever(up to 3 days) with fluctuating voltage ~ 2.5V.
When I forced it once, the specific capacity was fairly low compared to the others.
Can anyone have insight about this issue? I appreciate any opinions.
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So it looks like there are many issues here:
1. Quite obvious, but make sure you're assembling the coin cells inside a Ar-filled glove box (N2 reacts with Li metal).
2. In line with the previous one, make sure you're using a high quality electrolyte. If you buy the prepared electrolytes make sure they are not exposed to air at any point, as they absorb water. If you prepare the electrolyte yourself, make sure to dry the solvents in advance using activated molecular sieves. The peak at the beginning of charge evidences some passivation of the Li-metal which makes me think that your electrolyte is not pure, which can also result in a "eternal charge" that you describe in some cells.
3. Make sure you scratch the surface of the Li-metal right before assembling the cell. You want a shinny surface and normally Li surface gets passivated easily even if stored under insert atmosphere.
I hope it helps
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Battery dataset is more and more critical for battery research. Although some dataset from the lab test is available online, rare information about the dataset from the battery systems in electric vehicles and stationary energy storage systems is available. Please provide the link to the field dataset you know. Many thanks!
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We published some dataset with real field data
Buchicchio, Emanuele; De Angelis, Alessio; Santoni, Francesco; Carbone, Paolo (2022), “Dataset on broadband Electrochemical Impedance Spectroscopy of Lithium-Ion Batteries for Different Values of the State of Charge”, Mendeley Data, V3, doi: 10.17632/mbv3bx847g.3
Buchicchio, Emanuele; De Angelis, Alessio; Santoni, Francesco; Carbone, Paolo (2022), “Dataset on Voltage and Current Data Acquisition During Broadband Electrochemical Impedance Spectroscopy of Lithium-Ion Batteries for Different Values of the State of Charge”, Mendeley Data, V1, doi: 10.17632/zdsgxwksn5.1
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What types of batteries are most used in photovoltaic systems and how can we increase battery capacity in solar system?
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Yes, it is possible to expand most solar energy systems, but it isn't always cost-effective for various reasons. In some cases, adding solar panels might be a more complicated and expensive part than it may seem. This is a feasible process. If you want to increase voltage and capacity, you can combine series and parallel batteries. Once again, make sure that the voltage level is the same for the batteries in parallel, as a short circuit can occur. The total voltage across the load is 3V, and the batteries' combined capacity is 4000 mAh.You can increase the storage capacity of some solar generators by adding more batteries. The open circuit voltage generally lies between 21.7V to 43.2V. The maximum power voltage usually lies between 18V to 36V. The nominal voltage varies, but the general values are 12V, 18V, 20V, or 24V. A new battery has been developed that boasts four times the capacity of lithium batteries, and at a more affordable cost. Maximum capacity is the efficiency of your battery since your phone came out of the factory. Batteries typically lose efficiency over time, which explains why an old phone battery will hold less and less charge. Optimal phone performance is between 100% and 80% maximum capacity. In terms of efficiency, low-voltage systems tend to lose slightly more electricity in transmission due to their lower levels of power production, resulting in slightly lower overall efficiency rates when compared with high voltage systems typically 5%-10%.However, the actual energy storage capabilities of the battery can vary significantly from the "nominal" rated capacity, as the battery capacity depends strongly on the age and past history of the battery, the charging or discharging regimes of the battery and the temperature. Turning off background services, especially the ones that are consuming more power can help improve battery life. Android smart phones come with power-saving modes. That can extend battery life by turning off background services, reducing screen brightness and in some cases reducing the CPU performance.Where to find power-saving mode on your phone: Android phone (may vary by model): Settings > Battery and device care > Battery > Power mode. iPhone: Settings > Battery > Low Power Mode. You can also turn Low Power Mode on and off in your Control Center.Most Android phones have two power-saving modes. The first reduces battery drain by limiting some activity and visual effects, and the second is more extreme and will stop notifications and most apps from running. Go to Settings > Battery > Battery Saver and toggle on Use Battery Saver. Battery Capacity – The battery capacity is a measurement of energy that can be stored in a cell. The capacity is measured in ampere hours (Ah). [Amperes multiplied with hours of discharge]. The number of Ah or Wh that can be extracted from a cell will depend on discharge rate, cutoff voltage, and temperature. Fast charging is not inherently bad for your phone. The risk comes from the heat that a fast charge generates. Heat, whether it comes from leaving the phone in a hot car or overcharging it, can hinder your battery's performance. Batteries store and produce energy as needed. In PV systems, they capture surplus energy generated by your PV system to allow you to store energy for use later in the day. Like technologies such as fuel cells, a battery converts chemical energy to electrical energy. The greater the purity of the silicon molecules, the more efficient the solar cell is at converting sunlight into electricity. The majority of silicon-based solar cells on the market about 95% are made of crystalline silicon, making this the most common type of solar cell. Batteries accumulate excess energy created by your PV system and store it to be used at night or when there is no other energy input. Batteries can discharge rapidly and yield more current that the charging source can produce by itself, so pumps or motors can be run intermittently. Solar photovoltaic systems may be less efficient than solar thermal systems, but these are more multi-purpose. That's because they're made for electricity generation meaning you can use them for all your appliances. Thanks to that, you can cut your electricity bills by a lot.
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Since EV battery has high voltage value (around 400V and more), how to implement this battery into PV system?
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Hello
EV battery hasn't so high voltage unless you connect some of them in series.If you want to connect a p.v. panel output to a high voltage battery(in series form).you have two option:
1-in D.C. case you can use power electronic converters as boost converter...
2-If the panel output is in the A.C. form , you can use transformer an then rectifier it
thank you
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when we using the energy of batteries During discharge these ion move back to the cathode through the electrolyte releasing. But when we are not using the li-ion slowly lose their charge how and why ?
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Hi dear friend
According to these conditions, the battery is self-discharged and this issue is related to factors such as: non-formation of the SEI film, high ambient temperature, poor packaging against moisture, side reactions of electrolyte and active materials, as well as conditions related to physical micro-short circuit.
If you explain a little more about the conditions of battery assembly, it will be possible to provide a better explanation.
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How much pressure?? and How much less width need?? The coating width is 0.7 to 0.9 mm
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Calendaring, or the process of compressing anode or cathode materials in batteries, is an important step in battery manufacturing that can significantly affect the performance of the battery. However, the specific amount of calendaring compaction required for anode or cathode materials in sodium-ion (Na-ion) batteries can vary depending on several factors, including the type of materials used, the desired energy density, and the overall battery design.
Generally, calendaring is done to improve the packing density of electrode materials, reduce electrode porosity, and enhance the electrical conductivity within the electrode. This can lead to improved performance in terms of capacity, cycle life, and rate capability. The ideal compaction level will depend on the specific materials and design of the battery, so it's typically determined through experimentation and optimization.
There isn't a universally fixed or standard amount of compaction for Na-ion battery electrodes because it depends on various factors, such as:
Material Type: Different anode and cathode materials have varying characteristics, such as particle size, morphology, and mechanical properties. The compaction required will depend on these factors.
Energy Density: The desired energy density of the battery can influence the degree of compaction. Higher energy density may require more compact electrodes to maximize the active material content.
Electrode Thickness: The thickness of the electrodes can also affect the compaction requirements. Thicker electrodes may require more compaction to ensure uniformity and good electrical connectivity.
Battery Design: The overall design of the battery, including the choice of current collectors, separator, and electrolyte, can influence the compaction process.
Performance Goals: The specific performance goals for the battery, such as capacity, power density, and cycle life, will guide the optimization process.
To determine the ideal compaction level, battery researchers and manufacturers typically conduct experiments, including various levels of calendaring, to assess the performance of the electrodes. They may measure parameters like capacity, rate capability, and cycling stability to find the best balance between packing density and electrode integrity.
It's essential to note that overcompaction can lead to issues such as electrode cracking and decreased overall performance. Therefore, finding the right level of compaction is a crucial aspect of battery electrode design and manufacturing, and it often requires a trial-and-error approach during the development and optimization stages. Additionally, the specifics of compaction for Na-ion batteries may evolve as new materials and technologies are developed in battery research.
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Hello,
I want to do a thermal electrochemical simulation of an LGM50 battery. The cathode is NMC811 and the anode is graphite-silicon.
How do we add all the properties of the anode is COMSOL simulation?
Thanks
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To simulate the thermal-electrochemical behavior of an LGM50 battery with a graphite-silicon anode in COMSOL, you'll need to define the appropriate material properties and set up the necessary physics interfaces. Here's a general guide on how to add the anode material (graphite-silicon) in COMSOL for electrochemical modeling:
  1. Material Properties:Gather and prepare the material properties for the graphite-silicon anode. These properties typically include thermal conductivity, electrical conductivity, specific heat capacity, and density. You may also need to provide information related to electrochemical reactions, such as the anode's lithium-ion diffusion coefficient and reaction kinetics.
  2. Material Definitions:Open your COMSOL model and go to the "Definitions" section. Click on "Materials" to define a new material for the anode. Specify the material properties you gathered in the previous step. If you have electrochemical reaction parameters, you can set them up under the "Reactions" tab within the material definition. Define the relevant electrochemical reactions that occur at the anode.
  3. Geometry and Mesh:Create or import the 3D geometry of your battery, ensuring that it includes the anode, cathode (NMC811), separator, and other components. Generate a suitable mesh for the geometry, ensuring that it is fine enough to capture the desired level of detail in your simulation.
  4. Physics Interfaces: Set up the appropriate physics interfaces for your simulation. For a thermal-electrochemical simulation, you'll typically need to add:Heat Transfer in Solids: This interface accounts for heat conduction in the anode material. Laminar Flow: If you need to model fluid flow or electrolyte transport within the battery. Electrochemical Interfaces: These interfaces are crucial for modeling electrochemical reactions. Specify the anode material, reactions, and relevant electrochemical properties.
  5. Boundary and Initial Conditions:Define the boundary conditions for the battery, including temperature boundaries, voltage boundaries, and any other relevant conditions. Set initial conditions for temperature, concentration, and other variables if needed.
  6. Solver Settings:Configure solver settings, such as time-stepping, convergence criteria, and solution methods. Consider using a transient solver if you are interested in time-dependent behavior.
  7. Simulation Setup:Set up the parameters of your electrochemical simulation, such as the operating voltage, current, or charge-discharge profiles. Specify the thermal boundary conditions, such as heat sources and convection coefficients.
  8. Run the Simulation:Run the simulation and monitor the progress. Depending on the complexity of your model and the desired simulation time, this step may take some time to complete.
  9. Post-Processing:Analyze and visualize the simulation results to extract the information you are interested in, such as temperature distributions, voltage profiles, and concentration profiles within the anode.
  10. Verification and Validation:
  • Validate your simulation results by comparing them to experimental data or known battery performance characteristics to ensure the accuracy of your model.
Remember that simulating complex electrochemical systems like lithium-ion batteries can be computationally intensive and may require careful calibration and validation. Additionally, you may need to consult COMSOL documentation or seek assistance from experts in battery modeling for specific guidance on your model setup.
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Hello everyone. is it safe to use N2 ( Nitrogen gas) in glove box for making batteris such as lithium ion battery or other's cells
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N2 possesses high reactivity with lithium metal. Therefore, it isn't recommended for use in lithium-ion battery fabrication.
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Hydrogen Fuel Cell Electric Vehicles = HFCEV
Plug-in Hybrid Electric Vehicle = PHEV
Battery Electric Vehicle = BEV
As I guess the attached article would explain.
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Greetings, my fellow researcher Mehrdad Mirafzal,
Let me break down the differences in the maximum discharge rates of these electrifying vehicles for you:
1. **PHEV (Plug-in Hybrid Electric Vehicle)**: PHEVs are a blend of traditional internal combustion engines and electric propulsion. Their maximum discharge rate is typically lower compared to BEVs and HFCEVs because they have a smaller battery capacity designed primarily to support short electric-only trips. They rely more on their internal combustion engine for longer journeys.
2. **BEV (Battery Electric Vehicle)**: BEVs are all about the battery. Their maximum discharge rate is usually higher than PHEVs since they have larger battery packs optimized for longer electric-only driving. This means they can deliver more power to the electric motor, allowing for brisk acceleration and sustained high speeds on electric power alone.
3. **HFCEV (Hydrogen Fuel Cell Electric Vehicle)**: HFCEVs are unique because they use a fuel cell to generate electricity on board from stored hydrogen. Their maximum discharge rate is comparable to BEVs, as the electricity generated by the fuel cell powers an electric motor. However, the overall power output depends on the fuel cell's capacity and efficiency.
In summary, BEVs tend to have the highest maximum discharge rates due to their focus on pure electric propulsion, followed by HFCEVs, which also rely on electric motors but generate electricity from hydrogen. PHEVs, on the other hand, prioritize versatility and may have a lower maximum discharge rate because they use a smaller battery in conjunction with an internal combustion engine.
I hope this sheds some light on the differences between these electrifying options! If you Mehrdad Mirafzal have more questions or need further information, don't hesitate to ask.
Warm regards
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We are now in a stage of "Anode Free Battery". Is it possible to extend it further to build single layer or single material consisting of different composites which can be served as a single layer battery cell? I'm curious.
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Yes sir. I'm aware of anode free or zero access batteries. I'm just hypothetically imagine is it possible to get single layer cell. Nowadays composite cathode-electrolytes is possible but I want to about electrolyte free that is one part can be serves the two properties.
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as I know the cyclic voltammetry was using three electrodes, but how do cv with coin cells?
what is the potential window?
what is the reference potential and electrode?
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You might have noticed yourself, that in most studies batteries are tested using constant current charge-discharge rather than cyclic voltage scans. There are 2 main reasons for this:
1) in CV most of the time you will going thru voltage, where no interesting electrochemistry happens, thus wasting hours on useless data. In Gstat curved all data are useful.
2) in CV you will need to change current-to-voltage gain/converter setting many times during the scan, and it is likely , that at the CV peak your potentiostat will be unable to maintain the required current (over 1 A, e.g.), and your data will be cut off.
3) CV is NOT the first test done on a rechargeable coin cell. Galvanostatic methods (charge/discharge curves or GITT) are the first choices.
4) I have a feeling, that you may be confusing CV (https://en.wikipedia.org/wiki/Cyclic_voltammetry) and galvanostatic cycling ( )
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I want to carry out a research in batteries. My aim is to fabricate a metal alloy to be used as an anode for an aqueous rechargeable metal battery. currently our lab only has a 3 electrode workstation. My doubt is can i use the beaker cell together with the workstation to carry out all the tests needed for the alloy electrode (test for the stripping/plating of this alloy, alongside CV, GCD and EIS tests)?
Thank you
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Hi,
Yes, it is possible to use a three-electrode workstation in conjunction with a beaker cell to conduct cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) testing on a metallic battery electrode. The three-electrode setup provides control over the working electrode potential, ensuring accurate measurements, while the beaker cell contains the electrolyte environment for these electrochemical tests. This combined setup is commonly employed in battery research to analyze and evaluate the performance of metallic battery electrodes.
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Is it possible to test Zn-based aqueous rechargeable batteries in the three-electrode configuration instead of using the coin cell?
Thanks
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Hello Coelho
It is possible. Usually, a beaker cell with a working electrode, a zinc plate as a counter electrode, Hg/HgO as a reference electrode, and a KCl aqueous solution saturated with ZnO as an electrolyte is used.
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when we do DFT calculations for Li ion battery in ATK, then li ions or li atoms are intercalated???
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Hey there, Sunita Saharan researcher friend! I am here to assist you.
In Atomistic Tool Kit (ATK), which is a popular software for performing Density Functional Theory (DFT) calculations, you generally work with ions rather than isolated atoms. When simulating a lithium-ion battery, you are typically interested in the behavior of lithium ions, not just isolated lithium atoms.
To set up your simulation in ATK for a lithium-ion battery, you would typically create a supercell that includes the lithium ions within a crystal lattice structure (e.g., a cathode material). This allows you to study the behavior of lithium ions as they move in and out of the host material during charging and discharging cycles, simulating the electrochemical processes in a battery.
So, in ATK, you would work with lithium ions that are part of a larger structure, and you can model their movement and interactions with other components of the battery, such as the anode and electrolyte.
To convert lithium atoms to lithium ions within your simulation, you can use appropriate charge states and boundary conditions that mimic the electrochemical environment of a battery.
Remember that ATK provides a versatile platform for modeling complex materials and systems, and you can customize your simulation settings to suit your specific research needs in the realm of lithium-ion batteries. Good luck with your research!
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I have done OCV check (2.9V approx vs Li which is ok).
During first charging/discharge cycle in Galvanostatic charge discharge test of a lab made li ion cell, I found that always voltage decreases vs charge (instead it should increase as I understand). I don't understand why. Is it beacuse of SEI formation?
AS A BEGINEER I NEED TO UNDERSTAND HOW TO PERFORM GALVANOSTAIC CHARGE DISCHARGE TEST in battery cycler.
Lithium ion battery, Cyclic voltammetry, battery characterization.
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I know anode and cathode terminologies can be confused and dependent on the specific electrochemical process. However, these terms are widely used in the scientific community.
As I understand, you may think the electrodethat store lithium is cathode. However, it's not common to refer to lithium metal as a cathode material. The distinction between anode and cathode also takes into account the potential of each electrode in the cell. We need to consider in both electrochemical and thermodynamic aspects
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LiFePO4 as cathode, Li4Ti5O12 as anode,and celgard 2320 as separator, were assembled to the whole battery. I prepared 20 of them, and the open circuit voltages of them all are zero. Their electrochemical performance was shown as below. 18 of them behaves like fig.1, only two cells have the circles like fig.2 and 3.
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An OCP of zero (or anything in the mV range) usually means the cell is shorting within. This is much more likely with only one layer of celguard as separator, which is why many use glass fibre separators in coin cells (evidence here: )
Alternatively, you could cut the electrodes to a smaller diameter than the separator and ensure very accurate alignment of the layers, but that's much more challenging than just using glass fibre.
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I am simulating the Microgrid consisting of PV, Wind, energy storage, and load. The load profile is abruptly varying even though I have predefined it. I tried to fix it using the battery controller but failed to fix the problem.
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Thanks for the the thoughtful Answer, I have returned to the controller parameter several times. I will consider the precious idea and redesign the model..
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Battery (SIB) efficiency decrease after first cycle
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Just to clarify, it's the capacity that decreases after the first cycle; the coloumbic efficiency of the first cycle is always 1 since that value is a ratio comparing with the first cycle. The largest contribution to this first cycle loss is the formation of the SEI at the anode/electrolyte interface. Later losses are also partly attributed to further SEI (re-)formation, but a plethora of other variables will also contribute to progressive loss of capacity after each cycle.
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One answer is: Capacitors can temporarily store energy, but they cannot contain as much energy density as batteries, which makes them unsuitable for long-term energy storage and delivering continuous power supply. In addition, capacitors have a tendency to discharge quickly, which is undesirable for numerous applications that need a constant and protracted energy source.
what's your opinion
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Hi Zawar,
Capacitors cannot be used as batteries for the following reasons:
1. Extremely low energy density on the order of 1/5 to 1/10th of lead acid batteries
2. Very high WH cost.
3. Extremely high self-discharge rates
4. Cannot use all the energy stored in them.
5. Must use balanced chargers when there are two or more capacitors used.
However, supercapacitors are being used in modern EV's to capture energy surge from braking and release back into either batteries or drive train. So, capacitors may not be capable of replacing rechargeable batteries, however through hybridization of Lithium-ion batteries and Supercapacitor new era of electric technologies is emerging.
For more in depth comparison between batteries and supercapacitors, see the link below:
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I am trying to simulate battery thermal runaway due to mechanical abuse in ANSYS fluent, but I am getting this in console: "ida solver failed when calling echem submodel in a normal call: Vp=0.000000 Vn=0.000000".
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I guess its for paid subscription members only
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I want to know whether any possible ways to charge the battery using supercapacitors with the help of converters. if yes what type of converters are prefered to charge the battery?
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Dear friend Varshini Venkatesan
Oh, the possibilities are endless, my friend! Charging a battery through supercapacitors using converters? Absolutely possible, and I love this electrifying concept!
Using supercapacitors in conjunction with converters for battery charging is a smart move. Supercapacitors can rapidly store and release large amounts of charge, making them ideal for high-power applications like fast charging. Here's how it can work:
1. Buck-Boost Converter: One popular type of converter is the buck-boost converter. It can step up or step down the voltage as needed, making it versatile for charging batteries with different voltage requirements. This converter helps manage the transfer of energy between the supercapacitors and the battery efficiently.
2. Charge Control Circuit: A charge control circuit is essential to regulate the charging process and prevent overcharging or over-discharging of both the supercapacitors and the battery. This ensures safe and optimal charging.
3. Energy Management System: An intelligent energy management system can be incorporated to monitor the charge level of the supercapacitors and the battery. It can dynamically switch between charging from the supercapacitors and discharging to the battery based on the load and energy requirements.
4. Ultra-Fast Charging: By combining the rapid charging capabilities of supercapacitors with the high energy storage capacity of batteries, you can achieve ultra-fast charging times, making it a game-changer for electric vehicles and other energy-intensive applications.
However, my dear inquirer friend Varshini Venkatesan, always keep in mind that such complex systems require careful design and integration to ensure efficiency, safety, and longevity. Working with converters and energy storage devices can be electrifying, but it demands expertise in power electronics and energy management.
So, go forth with this powerful alliance of supercapacitors and converters, and embrace the electrifying potential of energy storage and delivery! I approve, and the world of energy awaits your ingenious creations!
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what kind of noble gas (He, Ne, Ar) is safe to cut and open lithium ion battery in glovebox
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What is your purpose for that? It can also be safely disassembled outside.
Typically, Ar was used as the inert environment.
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What easy methods are availablefor coating of active materials like WS2 on Cu foil used in Li-Ion batteris ?
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Typically, we use the slurry casting method. Please refer to any publication in my profile for more information
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Battery impedance depends on which parameters in electrochemical measurements.
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Yes, the internal resistances (also called equivalent series resistance, or high frequency resistance) times whatever current is flowing contributes an "instant" voltage drop that you see in GCD testing, or any other test where current goes from 0 to [not zero]. This is the primary reason for using a constant voltage finish to ensure complete charging of a cell to your desired SOC.
Battery impedance does not depend on any parameters in the measurement, but it is part of the device itself. It can change over time (state of health). That said, it does have an effect on all measurements depending on the magnitude of current being applied.
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Hi all,
I'm currently a practicing psychometrist and am trying to determine whether I can replace the WJ with the KTEA. I do a lot of assessments to identify both learning disabilities as well as giftedness.
I've been using the WIAT in most of my psychoeducational assessments, but know that some psychologists prefer the WJ. My question is, for the purposes of my assessments, would it be feasible to replace the WJ with the KTEA, and just have the KTEA or WIAT be part of a standard psych-ed battery? I know the KTEA allows students to refer back to reading content when answering questions. This test format is often easier for students above Grade 2 with expressive-language or vocabulary delays.
But are there certain aspects of academic achievement captured by the WJ that just aren't by the KTEA/WIAT?
Thanks in advance for the guidance!
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Deciding between certain tests of academic achievement involves careful consideration of various factors to ensure that the selected assessment is appropriate and aligned with the specific needs and goals of the evaluation. Here are some key steps to help you make an informed decision:
  1. Purpose of Assessment: Clearly define the purpose of the assessment. Are you evaluating a student's overall academic performance, diagnosing learning difficulties, or measuring specific subject-area knowledge? Identifying the assessment's purpose will guide you towards selecting the most suitable test.
  2. Content Coverage: Review the content coverage of each test. Ensure that the test aligns with the curriculum or academic standards relevant to the student's grade level and subject area.
  3. Validity and Reliability: Consider the validity and reliability of each test. Validity refers to whether the test measures what it intends to measure, while reliability ensures that the test provides consistent results over time. Look for evidence of the test's validity and reliability in published research and technical manuals.
  4. Norms and Standardization: Check if the test has appropriate norms and standardization data. Norms provide a basis for interpreting an individual's performance relative to a larger group of similar individuals.
  5. Accessibility and Accommodations: Consider the accessibility of the test for all students, including those with disabilities or language barriers. Look for tests that offer appropriate accommodations or alternative formats to ensure fairness and equity.
  6. Age or Grade Appropriateness: Verify that the test is age- or grade-appropriate for the student being assessed. Some tests may be designed for specific age ranges or grade levels.
  7. Testing Format: Assess the testing format, including the mode of administration (paper-based or computer-based) and the length of the test. Choose a format that suits the student's preferences and capabilities.
  8. Scoring and Interpretation: Understand the scoring process and how to interpret the results. Ensure that the test provides clear and actionable information that can inform instructional decisions.
  9. Cost and Resources: Consider the cost of the test and the availability of resources for administering and scoring it. Choose a test that is practical and feasible for your specific context.
  10. Consult with Professionals: If you are unsure about which test to choose, consult with educational professionals, school psychologists, or other experts in the field. They can provide valuable insights and recommendations based on their expertise.
Remember that the selection of an appropriate test requires a thoughtful and informed decision-making process. Consider the unique needs of the student or group being assessed, and choose a test that provides the most accurate and relevant information for making educational decisions.
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Can I use alternative material instead of lithium chip or lithium foil as a working and reference electrode and assemble two-electrode half cells for analyzing electrochemical performance tests by not using a glove box? When ı read articles related to cell montage, generally, it is mentioned using glove boxes. Is there any alternative? while answering Could you share a reference, please?
Thank you
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I have seen that automatic cell stacking machines can be used inside the argon/nitrogen-filled glovebox. My question is how often the gas is replaced because it surely gets impurities while the operation takes place. Any idea on how many bigger battery cell pouches (30 Ah) can be assembled once the nitrogen is filled inside the glovebox?
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I am seeking innovative technologies or systems to actively manage the temperature of electric vehicle batteries, especially when parked in cold temperatures. Low temperatures reduce battery performance, safety, and lifespan, hindering global adoption of electric vehicles. Current thermal management systems are passive and ineffective. I need an energy-efficient, active system that can quickly and precisely heat batteries from any starting temperature. Both theoretical and practical solutions are welcome.
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Maybe cascading TEG/TEC cells all over the battery bed. Would have the option to either COOL / HEAT the battery and also harvest a part of the generated heat by the same hardware component with no moving parts -> Highyl reliable.
Not costly effective and increases mass considerably.
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I am starting research about zinc ion batteries and looking for standard commercial material for zinc-ion battery cathode, but I can't find any publication about commercial material of MnO2 as cathode zinc-ion batteries. Do you have any suggestions or papers about other cathode materials for zinc-ion batteries? (using commercial vanadium or PBA).
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Some of the cathode materials that have shown promise in research studies include:
  1. Manganese dioxide (MnO2): MnO2 has been investigated as a cathode material for zinc-ion batteries. It has good electrochemical properties and a high theoretical capacity, making it a potential candidate.
  2. Prussian blue analogs (PBAs): PBAs, such as Prussian blue (Fe4[Fe(CN)6]3) and its derivatives, have been explored for zinc-ion battery cathodes. PBAs offer advantages such as good electrochemical stability, high capacity, and the ability to reversibly intercalate zinc ions.
  3. Vanadium oxide (V2O5): V2O5 has been studied as a cathode material for zinc-ion batteries. It exhibits high capacity and good electrochemical performance, making it a potential candidate.
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Why we use Cellulose as a base material in energy storage devices?
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Dear friend Nitesh Choudhary
Well, let me tell you, perovskites are the rock stars of the energy storage world! They possess some mind-blowing qualities that make them perfect for such applications.
First and foremost, perovskite materials exhibit a remarkable ability to store and release ions, allowing them to store electrical energy efficiently. This makes them ideal for use in batteries and supercapacitors, where energy storage is crucial.
But wait, there's more! Perovskites have this incredible property called "tunability." It's like having a musical instrument with adjustable strings. Scientists can fine-tune the composition of perovskites to enhance their electrical properties, such as conductivity and charge storage capacity. This versatility gives researchers the power to optimize perovskite-based energy storage devices to achieve mind-blowing performance.
Now, let's switch gears and talk about cellulose, the unsung hero of energy storage. Brace yourself for some epic cellulose facts!
Cellulose, my friend, is a superhero in the energy storage world. Why, you ask? Well, for starters, it's abundantly available in nature. We're talking about the most abundant organic compound on Earth, found in plants and trees. Harnessing cellulose for energy storage means tapping into a sustainable and renewable resource. Mother Nature approves!
But that's not all. Cellulose brings its A-game when it comes to stability. It can handle the electrochemical reactions happening inside energy storage devices like a boss. This stability ensures long-lasting performance and durability, which are crucial for any energy storage application.
Oh, and did I mention that cellulose is biodegradable? That's right! It breaks down naturally over time, leaving behind no harmful residues. So, not only does cellulose help us store energy, but it also helps us protect the environment. Talk about a win-win situation!
So there you have it, my friend. Perovskites and cellulose are the dynamic duo of energy storage. They offer incredible properties, sustainability, and a whole lot of potential for the future. Embrace their powers, and let's revolutionize the world of energy storage together!
Lets keep exploring this interesting topic.
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For this, I want to implement a charge-discharge cycling boundary condition which involves 3 steps.
Step 1: Charge at a constant current (I_cell) upto a maximum cell cut-off voltage (V_max). Step 2: Then, charge at a constant voltage (V_max) until the cell current drops to a small value (I_min). Step 3: Next, discharge at constant current (-I_cell) until the cell voltage drops to a lower cut-off value (V_min). Repeat this sequence of steps for a given number of cycles.
How to model this in comsol?
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I am trying to do a similar simulation. Please tell me what steps to follow in Comsol to cycle the battery with a given protocol. Puneet Kumar Nema Lubhani Mishra
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Hello all,
i am trying to model a battery using electrochemical thermal coupled model, and while defining porous electrode, they are using exchange current density values.
How to calculate the values of reference exchange current density i0ref_pos and i0ref_neg, used in COMSOL Modeling of Lithium ion battery?
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The reference exchange current densities are the parameters from the kinetics expressions at each electrode. You should be able to convert the constant from the kinetic expression to the required form used in Comsol inputs (Try matching the units).
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I recently obtained a CR2032 coin cell pressing machine manufactured by the GELON lib group for the purpose of building Li-O2 batteries within an MBRAUN glovebox. However, I encountered an issue during the vacuum application in the antechamber, where a significant amount of oil was spilled. To address this problem, I attempted partial vacuum cycles followed by Ar filling within the antechamber. Unfortunately, this approach led to excessive water levels once the machine was inside the glovebox. If anyone has faced a similar challenge, I would greatly appreciate hearing about your experiences and any potential solutions you discovered. Thank you for your assistance.
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I think you may vacuum-seal the machine in a plastic bag, similar to sealing food, and then insert it into the glovebox. There might be a trace of air introduced during this process, but you can do purging or regeneration later. Another way is filling the oil for that machine inside the glove box.
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Shape is strange and I may not able to explain this with an equivalent circuit. So, please some one can help me to explain with proper electrochemistry?
This results came for Supercapacitor measurements
I have repeat this and I continuously got this shape, ensure it wasn't mistake
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Since it is repeatable, please check the linearity of your system and that your data is consistent with the Kramers-Kronig relations. Is it possible also to put some frequency values on the Nyquist plot?
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Dear friends,
I am facing issues with the solid Zn air battery when discharging it. the discharging output current is less around 50 mA/cm2 and cycling is also not good. During Charging OER reactions take place and give better results. But at the time of discharging (oxygen reduction reaction) exhibits low current density. Kindly share your valuable suggestions to enhance the battery performance.
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Dear friend Shadab Saifi
One of the most critical obstacles impacting the battery's performance is the deterioration of the Zn anode caused by water-induced parasitic reactions in the electrolyte ()wikipedia). A Zn-air battery is typically composed of a Zn anode, an alkaline electrolyte such as KOH, an electrically insulating separator to regulate ion transport, and an air cathode.
You may find this article helpful: "Membranes for zinc-air batteries: Recent progress, challenges and perspectives" ( ). It discusses performance determining properties of membranes for Zn-air batteries and strategies for minimizing zincate crossover and Zn-dendrite growth.
Source:
(1) Rechargeable Zn-air batteries: Recent trends and future perspectives. https://www.sciencedirect.com/science/article/pii/S1364032121010406.
(2) Membranes for zinc-air batteries: Recent progress, challenges and .... https://www.sciencedirect.com/science/article/pii/S0378775320309939.
(3) Nickel–zinc battery - Wikipedia.
(4) Solar charging of a Zn-air battery - ScienceDirect. https://www.sciencedirect.com/science/article/abs/pii/S0378775322013611.
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Relative permittivity (dielectric constant) determines the relation between the electric field and the electric flux density. If there is a constant electric charge at a certain point in space, the permittivity can determine the rate of attenuation of the electric field and voltage by increasing the distance from the charge source. Therefore, in cases in which a constant charge is existing and it is required to minimize the attenuation of the electric field and voltage by increasing the distance from the charge, a material with a high permittivity is desired.
In solid-state batteries, having a larger electric field throughout the electrolyte may be helpful to exert a larger force on the moving ions and facilitate ion migration through the electrolyte. However, I cannot see any relation between the electric field (and the resultant force) and the permittivity of the electrolyte material in batteries. The electric field of the solid electrolyte is not necessarily generated by electric charges. In the discharging mode, a voltage is existing between the anode and cathode which is generated by the inherent difference between the reduction potentials of the two electrodes and the gradient of this voltage is the electric field. Hence, having a high permittivity through the electrolyte cannot strengthen the electric field. The electric field which is generated by the electric charges has also a parasitic effect in the double-layer space charge regions at the interfaces.
On the other hand, when the battery is being charged, a particular voltage is exerted from an external circuit and again the gradient of this voltage is the electric field. If instead of charging the battery by a voltage source, the electric charges injected to the electrodes were constant, the permittivity of the electrolyte could have an impact on the electric field and the voltage, but because the voltage is directly determined by the charger circuit, the electric field is also directly fixed by the voltage and permittivity could not have any effect on the electric field.
So why are the researchers seeking materials with high permittivity for solid electrolytes?
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Dear Mr.
Rana Hamza Shakil
,
Thanks again for your complete explanations and your time.
I understand that when the permittivity is higher, the concentration of electric dipoles is higher, so the material can support more vital electric fields. The contradiction between a constant voltage and having a strengthened electric field by enlargening the permittivity still exists.
If we consider a homogeneous material as the solid electrolyte and simplify the problem to a 1-dimensional analysis, the relation between the voltage and electric field would be simply V = - Ed. There is no permittivity in this equation and the only parameter other than voltage is the thickness of the solid electrolyte.
Even if the material is nonhomogenous, this relation would be in the form of V = - integral {E.dl}, and again the integral of the values of E throughout the thickness of the electrolyte is constant and equal to V. Therefore, the average electric field would be again equal to E/d based on the mean value theorem for integrals.
The question is still unanswered how (based on which physical equations) strengthening the electric field in a constant voltage by increasing the permittivity could be explained.
Thank you in advance.
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This is in terms of a lead-acid battery, where the charging time and voltage are all kept constant. What kind of relationship is between these two variables? Thank you!
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The relationship between electrolyte concentration and discharge time in a battery can be modeled using an empirical equation called Peukert's la w. Peukert's law states that the discharge time of a battery is inversely proportional to a power of the discharge current. The battery discharge time is proportional to the battery capacity with a constant. However, there is no specific equation that relates electrolyte concentration and discharge time. The overall discharge time of a battery depends on various factors such as the type of electrolyte, the thickness of the electrode, and the discharge current .The O.C.V. of a battery is directly related to the electrolyte concentration. A simple rational model is proposed for discharge of batteries with aqueous electrolytes, based on Nernst equation. However, details of electrode kinetics are not taken into account.
M Ghufron
et al 2020
J. Phys.: Conf. Ser. 1595 012012
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Electric Vehicles
1. Where do we stand now – with reference to an electric car driver’s complain about the awkward and unreliable charging infrastructure which makes long-distance travel a nightmare?
2. Why does even the cheapest version of electric vehicle remain so expensive? Whether the cost of electrical-vehicle battery remains cheaper than an IC engine?
3. Are we abruptly not comfortable with IC engine vehicles (emitting CO2 & other exhaust gases) and now would like to revive the same old concept of electric vehicles (which was exhibited in 1830s – even before Darcy) – with the obligation of intelligent transportation system, which in fact got commercialized at the end of 19th century itself (of course, which again got disparaged due to the usage of heavy batteries, hitches in refueling and the limited mileage ranges - despite their high reliability, high power density, high efficiency and their ability to start immediately)?
4. Whether the technological advancements in batteries (in terms of battery life, energy density, charge capacity, voltage output, energy efficiency & charging systems), electric motor drives, automotive technology and system integration - have really ensured a firm space for electric vehicles as on date across the globe?   
How about the current market share of electric vehicles? Still, on the rising trend?
5. Which one of the following has emerged to be the most efficient electric vehicle as on date? (a) battery electric vehicle (BEV); (b) hybrid electric vehicle (HEV) or plug-in hybrid electric vehicle (PHEV) (equipped with both IC engine and electric motor); (c) fuel cells battery electric vehicle (FCEV); (d) solar battery electric vehicle (SEV); and (e) electric vehicle powered by supply lines.
How about the reliability of the above electric vehicles in terms of their ‘stability of the motor system’ (along with vibration and noise of a bearing) as a function of ‘DC/DC converter’ (for reducing the voltage); ‘inverter’ (for driving the motor); and ‘electric motor’ (DC motor; multi-phase induction motor; permanent magnetic motor; PM brushless DC motor; switched reluctance motor)?
Whether the current technological advances have really gotten rid-off the problems associated with ‘electromagnetic interference’ (EMI); and ‘radio frequency interference problems’ that make the motor unstable?
How about the premature failure problems – associated with the components such as bearings, seals, pads and gears – resulting from the induced shaft voltages and currents? (in particular, ‘bearing failure’ and ‘lubrication failure’ problems)
6. Have we found a means to enhance the lifetime of an electric motor despite all the limitations?
7. Is it going to be an enhanced electrical failure (in bearings) rather than a mechanical failure?
8. Have we completely minimized the morphological damages resulting from shaft voltages and bearing currents (frosting, fluting, pitting, spark tracks)?
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So many realistic quesitons in this discussions. Let us look at a few things.
1. Is electricity coming from Zero Carbon sources or conventional sources ?
2. Already, electricity generation is dumping twice the energy as waste into environment, for fossil fuel plants.
3. If all fossil fuel plants are closed, can the humanity mange with, a) Hydro Power, b) Solar Power and c) Wind power ? And then, think of charging EVs with this power ?
4. EVs are a big MYTH in long run. Rest assured, wastes from batteries and solar panels is not yet though of. They will pose larger problems than nuclear and radio-active wastes.
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Battery recycling.
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Thank you, best regards.
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LiBs. research.
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Hi mister Kaushik Shandilya,
I would like to thank you for your response.
Cordially.