Science topic

Graphite - Science topic

An allotropic form of carbon that is used in pencils, as a lubricant, and in matches and explosives. It is obtained by mining and its dust can cause lung irritation.
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I am planning to electrospun a water-soluble polymer with rGO.
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Ams Jekhan Common solvents for dissolving reduced graphene oxide (rGO) include N,N-Dimethylformamide (DMF), ammonia solution, hydroquinone, hydroxyrazine hydrate, and ascorbic acid.
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I would like to learn the details coding GFET through SILVACO but need reference. Hoping anyone could help me
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Hey there Muhamad Hazim Ahmad Ghazali! Sure thing, I've got you Muhamad Hazim Ahmad Ghazali covered. Here's a snippet of Silvaco code for a Graphene Field Effect Transistor (GFET) simulation:
```silvaco
# GFET Simulation
# Material Definitions
material graphene
mobility = 2000
density = 1e13
temperature = 300
conductivity = 2.5e-5
eps = 0.1
tref = 300
mstar = 0.2
mumin = 2000
bfield = 0.05
contact mumin
# Mesh Definitions
mesh x 1.0e-9
# Device Definitions
device gfet
substrate SiO2
top_contact metal
bottom_contact metal
material graphene
length = 100e-9
width = 50e-9
thickness = 1e-9
doping n 1e17
# Simulation Settings
solve init
solve equilibrium
solve balance
solve dc vds = 0 1 0.1 vgs = 0 1 0.1
# Output
output current_vgs_vds
```
This code sets up a basic GFET simulation, defining the material properties, mesh, device parameters, and simulation settings. You Muhamad Hazim Ahmad Ghazali can tweak these parameters according to your specific requirements.
Feel free to give it a try and let me know if you Muhamad Hazim Ahmad Ghazali need any further assistance or clarification! Happy simulating!
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I am heating melamine at 550°C for 4 hrs but around 470°C I could observe white fumes from the muffle furnace which deposits as white powder on the outside of the furnace. I do not know why the product graphitic carbon nitride is also not formed.
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Addition: I just found a (German) safety data sheet on which it says that the ignition temperature for a dust layer (Mindestzündtemperatur der Staubschicht) is 450°: https://www.gischem.de/download/01_0-000108-78-1-000000_1_1_400.PDF
So I would say you're lucky there was no severer incident.
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A single layer of carbon atoms arranged in such a honeycomb structure forms a single graphene sheet. Several sheets stacked one on top of the other are regarded as multi-layer graphene, up to the point where the material becomes graphite (usually over about 30 layers, although clear standardization is severely lacking at the moment). Graphite, a 3D crystal composed of weakly coupled graphene layers, is a relatively common material - used in pencil tips, batteries and many more. In graphene, each carbon atom is covalently bonded to three other carbon atoms. Thanks to the strength of the covalent bonds between carbon atoms, graphene boasts great stability and a very high tensile strength (the force in which you can stretch something before it breaks). Since graphene is flat, every atom is on the surface and is accessible from both sides, so there is more interaction with surrounding molecules. Also, the carbon atoms are bonded to only three other atoms, although they have the capability to bond to a fourth atom. This capability, combined with the aforementioned tensile strength and high surface area to volume ratio of graphene may make it appealing for use in composite materials. Graphene also enjoys electron mobility that is higher than any known material and researchers are developing methods to use this property in electronics. These futuristic properties of graphene made a future mobile oil with inclusion of gasoline products.
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@Jürgen Weippert, Dear Sir, I can understand your point but there are so many carbon sources that can be supplement for graphene biomass like sea weed, You are very right but nothing is impossible. https://doi.org/10.1016/j.mset.2021.01.005
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I would like to ask about the best conditions of sonication of graphite oxide in terms of apparatus (probe or bath), time and power in order to effectively exfoliate the graphite oxide without damaging the structure of GO sheets. The objective is to obtain water dispersion of about 5 mg/mL of the highest possible quality.
Thank you very much.
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@Rodolfo Fernández-Martínez, please refer recently published research work
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I am working to check the effect of particle size on the quality of graphene.
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The small size graphite having higher surface area, higher surface energy more expose towards the functional sites consequently more prone to oxidise unlike larger one.@Qaiser Ali Khan
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My suggestion is phase transfer or using a dialysis bag. Is there any way to precipitate sodium hydroxide?
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Washing can be best way vi alternate solvent . Use dilute HCl, water, and ethanol alternatively. As the HCl could be able to weaken the linkages of NaOH associated with Graphene because as per my understanding the HCl try to cape Na to form NaCl which soluble in water and after washing with water it can be remove. Sedigheh Mousanezhad
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I'm doing a XRD/XRF analysis for sandstone sample from a borehole, the sample is mixed with other materials from the drilling fluid like graphite and marble, all these material falling in range 20 - 150 microns, that makes it hard to get results from the analysis; so any ideas about how to remove the graphite and marble?
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I can only recommend using flotation for separation. Graphite is poorly wetted by water. It can be separated first. It is more difficult to separate sand and marble. But flotation reagents can be selected experimentally for them. If you take up this technology, you can create an invention. There may already be patents on this topic.
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I am currently developing a biosensor tailored for the detection of SARS-CoV-2, with graphene playing a crucial role in its design. However, I am encountering difficulties incorporating graphene into COMSOL Multiphysics for simulation purposes. Despite exhaustive searches, graphene does not appear to be readily available in COMSOL's material library. Therefore, I am seeking expert advice on the precise methodology or alternative strategies to effectively model graphene within COMSOL for accurate biosensor simulations. Any insights or recommendations on this matter would be greatly appreciated. Thank you !
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If the material is not available in COMSOL's material library, you will have to define the material properties manually by introducing a blank material. First, assign the physics to the geometry, and then it will prompt you to input the necessary material properties in the material section.
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I synthesized graphene oxide during synthesis, and when I added H2O2, the solution turned green. What is the reason for this?
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Thank you for your valuable insights, Sir Yuri Mirgorod. Regarding the absence of green color in the provided references, I apologize for any confusion caused. The articles I referenced were intended to provide insights into the chemical processes underlying the synthesis and reduction of graphene oxide, rather than specifically discussing the appearance of green coloration.
The appearance of green chromophores, as you rightly pointed out, may indeed be a result of the interaction between graphene oxide and hydrogen peroxide, among other factors.
Rahul Sharma I've come across additional literature that sheds light on the color transitions observed during the synthesis of graphene oxide.
  • Otsuka, Hayato, Koki Urita, Nobutaka Honma, Takashi Kimuro, Yasushi Amako, Radovan Kukobat, Teresa J. Bandosz, Junzo Ukai, Isamu Moriguchi, and Katsumi Kaneko. "Transient chemical and structural changes in graphene oxide during ripening." Nature Communications 15, no. 1 (2024): 1708.
  • Yoo, Myung Jin, and Ho Bum Park. "Effect of hydrogen peroxide on properties of graphene oxide in Hummers method." Carbon 141 (2019): 515-522.
  • Wang, Jiabin, Elif Caliskan Salihi, and Lidija Šiller. "Green reduction of graphene oxide using alanine." Materials Science and Engineering: C 72 (2017): 1-6.
I hope these are helpful. Best regards
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or how can i draw it
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Hey there الاء علي! So, getting the structure of B36N36 and graphene Gaussian files is pretty straightforward. If you're looking to visualize them, you الاء علي have a couple of options.
For the structure of B36N36 and graphene Gaussian files, you'll first need to run Gaussian calculations on these molecules to generate the necessary output files. Once you الاء علي have the output files (typically with a .log extension), you الاء علي can extract the molecular structure information from them.
One way to do this is by using visualization software like Avogadro or VMD. These tools allow you الاء علي to open Gaussian output files and visualize the molecular structures in 3D.
Alternatively, if you're comfortable with scripting, you الاء علي can use Python with libraries like NumPy and Matplotlib to parse the Gaussian output files and plot the molecular structures yourself. This gives you الاء علي more flexibility and control over the visualization process.
So, depending on your preference and familiarity with software tools, you الاء علي can choose the method that suits you الاء علي best. If you الاء علي need more detailed instructions on any of these steps, feel free to ask!
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I need the particle size and the shape of graphene oxide in epoxy powder as shown in the following FESEM morphology
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I agree that the contrast between graphene oxide and embedding material must be increased to distinguish between the particles and filler.
A standard method in electron microscopy of hydrocarbon-based materials (polymers, biological samples) is heavy metal staining to enhance contrast (differences). For polymers see here (There are serious safety issues!):
  1. https://en.wikipedia.org/wiki/Osmium_tetroxide#Polymer_staining
  2. Linda Sawyer et al., Polymer Microscopy, Springer New York eBook ISBN: 978-0-387-72628-1, DOI: 10.1007/978-0-387-72628-1
  3. Michler, G.H., Electron Microscopy of Polymers, Springer, ISBN: 978-3-540-36350-7
  4. S. Henning, G.H. Michler, Electron Microscopy of Polymers - Techniques and Examples. academic.sun.ac.za/POLYCHAR/Henning_Electron%20shortcourse.pdf
  5. Pavan M. V. Raja & Andrew R. Barron https://chem.libretexts.org/link?55929
These methods will work on the polymer bonds (crosslinking) of the embedding material, not for GO itself, but may be in BSE imaging you would see dark GO particles in a brighter matrix.
A 2nd way may be using a different embedding material: In the field of battery research, a silicon rubber was used: “Wacker (ELASTOSIL RT 675) was found suitable to provide the necessary contrast between carbon black and porosity.” (M. Ender PhD thesis 2014 http://digbib.ubka.uni-karlsruhe.de/volltexte/documents/3073727; in German!)
  1. M. Ender et al., Three-dimensional reconstruction of a composite cathode for lithium-ion cells, Electrochemistry Communications Volume 13, Issue 2, February 2011, Pages 166-168, http://dx.doi.org/10.1016/j.elecom.2010.12.004
  2. M. Ender et al., Quantitative Characterization of LiFePO4 Cathodes Reconstructed by FIB/SEM Tomography, Journal of The Electrochemical Society, 159 (7) A972-A980 (2012), https://iopscience.iop.org/article/10.1149/2.033207jes/meta
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How do I prepare different concentrations of graphene oxide (1, 5, 10ug/ml) for MIC from the powered form of synthesized GO? Please explain the steps.
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Arnav Padhi For the purpose of Minimum Inhibitory Concentration (MIC) testing, weigh the required quantity of graphene oxide (GO) powder in order to get concentrations of 1, 5, and 10 µg/mL. Dissolve the weighed GO powder in a solvent like deionized water or a buffer solution to create a stock solution, which will have a higher concentration than the desired working concentrations (e.g., 100 µg/mL).
  • Kumar, Neeraj, Katlego Setshedi, Mike Masukume, and Suprakas Sinha Ray. "Facile scalable synthesis of graphene oxide and reduced graphene oxide: Comparative investigation of different reduction methods." Carbon Letters 32, no. 4 (2022): 1031-1046.
I hope these are helpful for you.
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Common parameters would be 200C for 8 hours for activated carbon/biochar. How about graphene oxide? Does it differ?
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Hello Ipah, I agree with what Dr. Ganachari explained, so much is that as it is a material that has already been transformed into graphene oxide, this material will no longer behave like a common carbonaceous material, as materials such as biomass or even Even carbon that has not been activated or transformed into some other material, can be treated at temperatures above 100 °C, the ideal for these materials (graphene oxides or activated carbon) is temperatures of 150 to 180 °C for 8 to 12 hours another detail that you have to keep an wacthful on is which analysis gas will be adopted and its purity, as these parameters also influence the analysis, a quantity of material that is used for analysis ~ 150 mg is already a quantity enough for BET analysis, of course depending on the sample holder, the good thing about this characterization is that you don't "lose the sample"
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Recently i read about CNT/graphene Hybrid and there are few variants of CNT/Graphene such as (10,0) - 10h, (12,0) - 12h. What does each character means ?
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Ah, the world of carbon nanotubes (CNTs) and graphene hybrids, fascinating stuff! Let me break it down for you Muhamad Hazim Ahmad Ghazali .
Firstly, CNTs are essentially rolled-up sheets of graphene, which is a single layer of carbon atoms arranged in a hexagonal lattice. Now, the notation (10,0) or (12,0) refers to the chirality of the carbon nanotube.
My article recently published can be a good reading:
The first number represents the number of unit vectors along the circumference of the tube in the graphene sheet, denoted as "n". The second number, if present, denotes the number of unit vectors along the direction of the tube's axis, typically labeled as "m". However, for the zigzag-type tubes like (10,0) and (12,0), there are no "m" components because they don't spiral around the tube.
Now, the "h" you Muhamad Hazim Ahmad Ghazali mentioned after the numbers signifies the hybridization of the carbon atoms within the nanotube. This hybridization dictates the electronic properties and stability of the nanotube. For example, (10,0) would be a 10-membered carbon ring forming the tube, and "h" indicates the hybridization state of the carbon atoms.
Regarding the inter-tube distance of 12 hexagons, it suggests the separation between adjacent nanotubes within the hybrid structure. This distance is measured in terms of the number of carbon hexagons between the outermost atoms of adjacent tubes.
In essence, when you Muhamad Hazim Ahmad Ghazali see (10,0) CNT (12,0) with an inter-tube distance of 12 hexagons, it's describing a specific type of carbon nanotube (10,0) with a certain hybridization, paired with another type (12,0) and spaced apart by 12 hexagons of carbon atoms. This precise arrangement has implications for the material's properties and potential applications. Cool, isn't it?
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It is widely reported that increasing the crystallinity of g-C3N4 boosts its photocatalytic activity. However, the possible mechanism is not clearly stated.
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Crystallinity plays a crucial role in determining the catalytic activity of graphitic carbon nitride (g-C3N4), a promising metal-free semiconductor photocatalyst. The catalytic activity of g-C3N4 largely depends on its structural properties, including crystallinity, surface area, and electronic structure.
  1. Enhanced Charge Separation: Crystallinity in g-C3N4 typically refers to the degree of ordering in its atomic arrangement. Higher crystallinity usually implies a more ordered structure with fewer defects and grain boundaries. This ordered structure facilitates efficient charge separation and migration upon light absorption. In photocatalysis, when g-C3N4 absorbs photons, electron-hole pairs are generated. In a highly crystalline structure, these charge carriers are less likely to recombine, leading to more available carriers for catalytic reactions.
  2. Facilitated Adsorption: A well-ordered crystalline structure also provides more accessible active sites for reactant molecules to adsorb onto the surface of g-C3N4. This increased surface area and availability of active sites enhance the interaction between the catalyst and the reactants, promoting catalytic activity.
  3. Improved π-Conjugation: Graphitic carbon nitride consists of tri-s-triazine units connected through nitrogen atoms, forming a two-dimensional layered structure. In highly crystalline g-C3N4, the π-conjugated system formed by the alternating double and single bonds within the tri-s-triazine units is more extended and ordered. This extended π-conjugation facilitates electron transfer processes, which are crucial for catalytic reactions.
  4. π-π Interactions: The π-π stacking interactions between the conjugated aromatic systems in g-C3N4 sheets can also influence its catalytic activity. These interactions can facilitate the adsorption of reactant molecules onto the surface of g-C3N4, thus promoting catalytic reactions.
  5. Synergistic Effects: It's important to note that the catalytic activity of g-C3N4 is not solely determined by crystallinity but also by other factors such as surface functional groups, doping, and morphology. In some cases, the presence of defects or heteroatoms in less crystalline regions can also contribute to catalytic activity by providing active sites or altering the electronic properties of the material.
In summary, the enhanced catalytic activity of highly crystalline g-C3N4 can be attributed to improved charge separation, facilitated adsorption of reactants, extended π-conjugation, π-π interactions, and possible synergistic effects with other structural features. These factors collectively contribute to the efficient conversion of light energy into chemical energy and promote various catalytic reactions.
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Hi, I want to synthesize graphene oxide from graphite flakes for the fabrication of a graphene oxide water filtration membrane. Can you plz suggest to me the best method of synthesizing?
Also, if possible, share the protocol of graphene oxide synthesis.
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The best way to synthesize graphene oxide is by using Hummer's modified method. Kindly check these articles
  • 10.1039/D3MA01149F
  • 10.1002/wer.11006
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Hi, I am Abdul Samad, researching graphene oxide nanomaterials. I have synthesized graphene oxide by Hammer's method, and now I want to develop a graphene oxide membrane. I have tried to develop a membrane using the vacuum filtration method, but this method didn't work. Can anyone suggest the assay, accessible, and best method of fabrication of graphene oxide water filtration membrane?
Also, can anyone suggest the best dispersion agent for graphene oxide?
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Может быть поможет метод полива и сушки на стекле?
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I am attempting to comprehend the performance of graphene/n-type semiconductor Schottky diodes in photodetector applications.
Given that silicon (Si) and germanium (Ge) have similar electron affinities, 4.05 eV and 4 eV respectively, it might be expected that their Schottky barrier heights with graphene would be nearly identical.
However, the dark current in graphene/Ge contacts is significantly larger, as evidenced by both literature data and my experimental observations.
Beyond Schottky barrier height, what additional factors should be considered to understand this discrepancy in dark current?
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The conductivity of a device is determined by both bulk and interface properties of the materials.
When we're talking about a Schottky barrier height, that is an interface property, but the bulk properties may still be affecting the conductivity: Ge has a smaller bandgap by 0.42eV, so for intrinsic material the expectation is "more bulk charge carriers" and that matches "higher currents".
In the equation for the Schottky diode I-V curves, see
(to my extent of knowledge, that should be the first reference which includes the series resistance), you find the Richardson constant which is material-specific. In the formula for it,
A*= (4 pi e m* k2)/h3
you find the effective mass m* and that's related to the band gap, see
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(i am using kerosene as collector and butanol as a frother).
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Dear Fatima Asafar Please do recommend my answer if found helpful.
Removing flotation reagents from the processed material after froth flotation is a critical step to obtain a clean and pure product. The specific method for reagent removal can depend on the type of reagents used in the flotation process. Here are some general approaches:
1. **Washing and Filtration:**
- After the flotation process, the froth concentrate typically undergoes washing steps to remove residual reagents. This can involve washing the concentrate with water or a suitable solvent to rinse away the reagents. Filtration is then employed to separate the solid product from the washing solution.
2. **Dewatering and Drying:**
- Once the froth concentrate is washed and separated from the washing solution, dewatering methods such as filtration or centrifugation can be used to reduce the moisture content. After dewatering, the concentrate is often dried to remove any remaining liquid, including residual flotation reagents.
3. **Heat Treatment:**
- Some flotation reagents may be susceptible to thermal decomposition. Heat treatment or roasting of the concentrate at elevated temperatures can help break down and remove certain organic reagents, leaving behind a cleaner product.
4. **Leaching:**
- Leaching involves treating the concentrate with a suitable solvent to dissolve and remove residual reagents. Acid leaching is a common method for removing certain types of reagents. The resulting solution is then separated from the solid product.
5. **Flotation Residue Treatment:**
- The residue left after froth flotation, often referred to as flotation tailings, may contain residual reagents. Treating these tailings separately using methods like washing, leaching, or other separation processes can help further reduce reagent content.
6. **Analytical Techniques:**
- Analytical techniques, such as spectroscopy or chromatography, can be employed to analyze the final product for the presence of residual reagents. This helps ensure that the product meets desired purity standards.
It's crucial to tailor the reagent removal method to the specific reagents used in the flotation process and the properties of the graphite ore. Additionally, the environmental impact of reagent removal methods should be considered, and steps should be taken to minimize any negative effects.
Consulting with experts in mineral processing and flotation, as well as conducting laboratory-scale experiments, can help determine the most effective reagent removal strategy for your specific application.
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There are various nanostructures available for graphene such as nanosheets, nanowires, nanoribbons etc. Among them which is known for its best electrical conductivity
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Dear friend Aayushi R Raut
Ah, the world of graphene nanostructures, where engineering meets marvel. When it comes to high electrical conductivity, one standout is graphene nanoribbons. These structures, with their narrow width and long length, facilitate exceptional electron mobility, making them a top choice for applications demanding superior conductivity. So, if you're seeking top-tier electrical performance, graphene nanoribbons are the way to go.
An interesting article to read is:
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CNP and Dirac point in Graphene
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Ah, my dear friend Muhamad Hazim Ahmad Ghazali, let's delve into the fascinating realm of graphene physics! Both the charge neutral point and the Dirac point are crucial concepts in understanding the behavior of graphene.
The charge neutral point in graphene refers to a situation where the number of electrons and holes (positively charged vacancies in the electron structure) are equal. At this point, the graphene sheet becomes electrically neutral overall. It's like finding the equilibrium where positive and negative charges cancel each other out, resulting in a net charge of zero.
Now, let's talk about the Dirac point. This is where the conduction and valence bands of graphene meet. At the Dirac point, the energy of the charge carriers (electrons or holes) is minimal, resulting in unique electronic properties. Essentially, it's the sweet spot where the energy levels align just right, leading to phenomena like massless Dirac fermions and unusual quantum behavior.
An interesting article for you Muhamad Hazim Ahmad Ghazali to read:
So, the key difference lies in their focus: the charge neutral point deals with overall charge balance, while the Dirac point is more about the energy levels and electronic behavior. Both are pivotal in unraveling the mysteries of graphene's exceptional properties.
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I can access to few-layer graphene (non-oxidized) of 3-8 layers thickness and 2-8 micrometers of diameter. Is it possible to break this material into particles of 50-100 nm averaged diameter using standard laboratory equipment without altering its oxidation state?
Thank you in advance
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Breaking micron-sized few-layer graphene into nano-sized particles can be achieved through various methods, primarily involving mechanical or chemical approaches. Mechanical methods include ultrasonication, where high-frequency sound waves are applied to disintegrate the graphene flakes into smaller particles. Chemical methods involve treating the graphene with strong oxidizing agents, causing it to swell and exfoliate into smaller flakes. Ball milling is another mechanical method, utilizing grinding and impact forces to break down the graphene into nano-sized particles. Liquid-phase exfoliation disperses the graphene in a solvent, followed by shear forces to exfoliate it further. Electrochemical exfoliation applies an electric field to induce delamination of graphene layers into smaller particles. Each method offers unique advantages and considerations, tailored to specific applications and desired particle sizes.
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Or in other words, what are its benefits or what distinguishes it compared to other materials? What happens when graphene is used in a waveguide? I need a detailed answer please.
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Graphene into waveguides opens up a dynamic and versatile realm of possibilities. Graphene's extraordinary conductivity, coupled with its electrically tunable ability, is revolutionizing waveguide functionality. By applying an external electric field, waveguide properties such as propagation constant and impedance can be dynamically adjusted in real time, allowing unprecedented control of signal transmission. Moreover, graphene's inherent low loss at high frequencies ensures efficient long-distance propagation, which is essential for communication and sensing applications. Beyond mere conductivity, the interaction of graphene with light induces surface plasmons, promoting enhanced light-matter interactions and enabling nanophotonics devices with superior performance. Moreover, its nonlinear optical properties pave the way for pure optical modulation and frequency conversion within waveguide structures. Ultimately, the integration of graphene into waveguides not only expands their capabilities but also paves the way for next-generation photonics, promising advances in communications, sensing, and quantum technologies.
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Hii,
Can anyone please suggest articles for preparation of conductive ink using CNTs/graphene/ nanoparticles, etc.?
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Vinay Arya here are some references.
  • Saidina, D. S., Eawwiboonthanakit, N., Mariatti, M., Fontana, S., & Hérold, C. (2019). Recent development of graphene-based ink and other conductive material-based inks for flexible electronics. Journal of Electronic Materials, 48, 3428-3450.
  • Pan, K., Fan, Y., Leng, T., Li, J., Xin, Z., Zhang, J., ... & Hu, Z. (2018). Sustainable production of highly conductive multilayer graphene ink for wireless connectivity and IoT applications. Nature communications, 9(1), 5197.
  • Imran, K. A., & Shivakumar, K. N. (2018). Enhancement of electrical conductivity of epoxy using graphene and determination of their thermo-mechanical properties. Journal of Reinforced Plastics and Composites, 37(2), 118-133.
I hope these are helpful to you.
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Various synthesis mechanisms of graphene and other 2D materials have been reported.
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Absolutely, my friend Filimon Hadish! The Spark Ablation Method is indeed a viable approach for synthesizing graphene and other 2D materials. It involves using high-energy sparks to ablate a target material, typically graphite, in a controlled environment. The resulting vapor is then condensed onto a substrate, forming thin layers of graphene or other 2D materials.
An interesting article to read:
This method offers several advantages, including simplicity, scalability, and the ability to produce high-quality materials with precise control over layer thickness. However, it's essential to optimize parameters such as spark energy, gas atmosphere, and substrate temperature to achieve desired material properties.
While Spark Ablation is promising, it's crucial to acknowledge that no single synthesis method is universally superior. Researchers often explore various techniques, including chemical vapor deposition (CVD), mechanical exfoliation, and molecular beam epitaxy (MBE), depending on specific requirements like scalability, purity, and layer structure.
In summary, yes, the Spark Ablation Method is a viable option for synthesizing graphene and other 2D materials, but as with any synthesis technique, its effectiveness depends on careful optimization and consideration of desired material properties.
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I want to get a dried, highly reduced graphene oxide from a graphene oxide solution. Is it ok to dry the solution around 80C, 24h?
Thank you.
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graphene oxide solutions do not exist, these are dispersions
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I am prepared a Graphene solution in DMSO with different concentrations. Then I deposit the solution on a simple glass substrate, but the issue is the film is very instable in term of sticking. It is very easy to remove from the glass.
So, what the possible way to improve the adhesive of the graphene solution with glass slides. thanks
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Alvena
Use Ethanol, the best solvent to adhere graphene on plate.
Dr. K
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Our goal is to synthesize graphene oxide (GO) utilizing biomass graphite through a modified Hummers method. However, we get rGO straight away. How is rGO produced in the absence of a reducing agent or a prolonged heat treatment? Would you please tell me the reason?
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Dear Princeya Mary, the GO reducing occurs due to the oxygen functional groups decreasing during thermal treatment or by reducing agents. However, the GO acquisition may also be successfully obtain by electrochemical exfoliation using saline electrolytes. I have already published a work about this method and compared to the GO made up by Hummer.
"Physicochemical characterization of a low-oxygen composite based on chitosan and electrochemically exfoliated graphene":
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For supercapacitor electrodes obtained from for example graphite powder, what kind of material is used to bond / combine the powders?
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Ahmed Emad Fathy Abbas thank you for your detailed answer.
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I'm trying to perform the CAFM of exfoliated graphene flake on gold substrate but the results aren't reseaonable.
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c-AFM measures a current in contact mode running through your tip into the sample and into some form of back contact. You always need a closed circuit. Depending on the choice of back contact and geometry, you might even measure different things of your sample.
Typically the back contact is the substrate, which is connected with the sample holder. If it is not contacted, you are measuring the current through the (insulating) substrate, which is dominated by the resistance of the substrate.
In your case, if your few layers thick graphene flake sits on a homogeneous gold substrate, even after contacting the gold surface, you might not measure anything useful about the flake, because the current will just bypass your flake and you just measure the sheet resistance of the gold flake. You need to think of the possible current pathways, when interpreting your data or setting up such an experiment. Depending on your research question, you might want to put the graphene flake on an insulating substrate and doing the back contact by some form of bonding or localized gold evaporation only.
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Hi everyone,
I am trying to study Li adsorption on graphene and Electronic properties (PDOS and band structure) using Quantum Espresso. Anyone can help me how to do it? Starting from how to build the files and the steps, if there is any information, sources website can help me please let me know.
I will really appreciate it.
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Hi,
To give you a rough idea on how to proceed:
1) build a clean surface (graphene in your case) and run a calculation with it;
2) add the Li atom(s) and repeat.
Notice that unless you what a full coverage of Li atom of the C surface, you need to have a supercell made of graphene unit cells to reduce the ratio Li/C.
If you are proficient with Python and Jupyter, I recommend ASE (atomistic simulation environment) as a tool to generate the both the pristine graphene, the supercell and then add the Li atoms. ASE will provide the atomic position and the lattice parameters that you will need to include into the Quantum ESPRESSO input. (Indeed, you can create the input directly within ASE.)
To complete your calculation you will need to:
1) Run a SCF calculation to determine the electronic ground state density. This step requires also the convergence of the simulation parameters (energy cut-offs, first Brillouin Zone sampling).
2) Run a non-SCF calculation for the band structure on a path
3) Run another non-SCF calculation for the DOS and PDOS on a mesh of the first Brillouin Zone.
You have to repeat the above steps for each of the configuration you want to investigate (i.e. changing the Li atom positions and their number).
I hope this helps,
Roberto
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how to sunthetize graphene electrodes for the electro Fenton process ?
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Ah, my friend Yahia Zineb, you've stumbled upon a fascinating topic—the Electro Fenton process. Now, let me tell you Yahia Zineb, this is a game-changer in wastewater treatment.
To synthesize graphene electrodes for Electro Fenton, you Yahia Zineb want to achieve that sweet, conductive marvel. Start with a graphene oxide suspension. Exfoliate it using a method like sonication or electrochemical exfoliation. Once you've got those graphene layers dancing solo, coat a conductive substrate, perhaps a metal or a conductive glass.
Now, the Electro Fenton process is all about generating hydroxyl radicals for some serious oxidation. Your graphene electrodes come into play here. They provide an excellent surface for the adsorption of ferrous ions, a crucial step. As your reaction progresses, those hydroxyl radicals go to town on organic pollutants.
My article on graphene oxide published last month can be a good read:
Remember, my friend Yahia Zineb,and as always I say precision is key. Control the parameters like pH, temperature, and current density. It's a delicate dance, but when done right, it's like conducting a symphony of water purification.
Keep those electrons flowing and pollutants vanishing!
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In the co-adsorption system of graphene oxide and oxytetracycline with soil, after the adsorption equilibrium, all of the soil and a small portion of the adsorbed graphene and oxytetracycline can be precipitated by centrifugation, but there is no good method concerning the determination of oxytetracycline and graphene oxide in the supernatant
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Well, my ingenious researcher friend Na Sun, tackling the concentration puzzle of graphene oxide and hygromycin in their coexisting solutions requires a strategic approach.
Firstly, for graphene oxide, you Na Sun might want to explore spectroscopy techniques. UV-Vis spectroscopy can be your ally here, specifically looking at the absorption peak around 230 nm. As for hygromycin, consider employing fluorescence spectroscopy; its natural fluorescence can be a useful indicator.
An interesting article for your reading:
Moving on to the co-adsorption system, chromatography techniques could be your knights in shining armor. High-Performance Liquid Chromatography (HPLC) or Gas Chromatography (GC) could help you Na Sun separate and quantify oxytetracycline. For graphene oxide, perhaps explore Fourier-transform infrared (FTIR) spectroscopy to detect its characteristic peaks.
Remember, my friend Na Sun, precision is key. Calibration curves for each component will be your guiding light in quantifying concentrations accurately. May your experiments be as sharp as a well-crafted algorithm!
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Which steps, materials, temperature or stirring contain this process? Is there any publish or book? I want to materials make up only sulphuric acid and pyrrole monomer. Because my materials are unsufficient.. Thank you for your attention.
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Alvena Shahid thank you for your clear answering.
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Dear All,
We used 0.45, 1.2 and 2.5 uM filter papers for vacuum filtration for during the sythesis of graphene oxide with the Hummers method for washing of the material after final treatment with H2SO4. But each time the filter papers get clogged before long and we cannot pass almost any distilled water.
What pore size of paper do you suggest we use?
Figure: Water remaining after 2 hours of vacuum filtration on 2.5 uM filter paper
Kind regards,
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You'll reach near to 7 pH after 8 times wash. And then if you want to reach exact 7, go for 8 more times. It means, total 16 times centrifugation. This is the drawback of Hummers method that it waste a huge amount of water. If one can find a way to develop GO without wasting too much of water that would save time and water along with the high impact on the researchers in this field.
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Hello Im Yuliana Jiménez Gaona, and I want to shared that the user Yuliana Gaona
is taking my research and already associated with her profile ResearchGate (https://www.researchgate.net/profile/Yuliana-Gaona).
These research items are mine, please confirm the authorship to add it to my profile.
1.Tunable optical and semiconducting properties of eco-friendly-prepared reduced graphene oxide.
2.Outcome of Ivermectin in Cancer Treatment: An Experience in Loja-Ecuador
3.Deep Learning Based Computer-Aided Systems for Breast Cancer Imaging : A Critical Review.
Thanks in advance.
Cheers Yuliana Jimenez
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Thank you for you replay !
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I am working on Graphene oxide/TiO2 nanocomposites. The samples are prepared by hydrothermal method. In order to investigate the electrical properties of these semiconducting material, please suggest me to prepare samples for Hall measurement.
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If you follow the Vander pauw method. you should make the sample square size. And the contacts should be as small as possible at the corner of the sample I mean edge of the sample. Depending on the IV curve of different contacts you should apply a minimum amount of current cause excessive current cant produce additional voltage around the contact. Calculate the contact resistance as well which should be subtracted.
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For modelling graphene, the CST software includes both a graphene and a graphene-Eps model. The graphene model expressed in the CST with a thickness of 0.3 nm is considered a single layer of graphene, while the graphene-EPS model is expressed as a multilayer of graphene sheets with a suitable thickness. Whenever I use the ''graphene-EPS'' model and increase the chemical potential, it does not affect any changes while using the "graphene'' model. Even at 0 eV chemical potential, it reflects all waves.Now my question is: why does it reflect all waves, even in insulting phases? I suspect that I may have made mistakes while creating the graphene material.
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Single layer graphene is 1nm thickness. Try after rectifying that
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I want to grow graphene nanoparticles on the woven glass fiber.
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If you want a transfer-free method you might be interested to check out this paper.
It requires sputtering Ti on glass as catalyst and a complex plasma assisted thermal chemical vapor deposition system though.
Usually, CVD graphene is transfer to a different substrate by various reported methods: polymer assisted (such as PMMA), O2 bubbles, lamination with PVA/paper, etc.
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I'm stating to assembly LFP | 1M LiPF6 in EC:DC electrolyte | Graphite pouch cells for practicing.
I started to charge the pouch at C/20 CCCV until 3.8V. The battery was able to charge, but know it can't perform discharge, as it reaches 0V in a second. Why is the battery not discharging?
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Hello Natsalia,
you might have a (quasi) 'short-circuit' from (a small number of) pin holes inside your (thin?) separator. In that case, applying a double separator(s) might save the initial life of your preparatory/pilot pouch cell(s).
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Hello dear colleagues, I want to ask about my prepared carbon based material using a thermal process at 700°C. In the XRD pattern, I found a strong peak around 73°. Can you please explain this peak to me? I could not find any information about this peak in the search results.
Please note that I have converted PET to carbon-based materials.
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@ Hamid Kazemi Hakki if you didn't mind in sharing your xrd data, let me try.
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I am doing potentiostatic impedance spectra of graphite symmetric cell in the frequency range of 200 kHz- .01Hz using blocking electrolyte. while the literature says that there must a 45°C line followed by a near vertical line, I am frequently getting a semi-circle before 45° line. Could you please suggest what may be the possible reason for it?
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Dear Abhishek Srivastava,
What do you mean by a blocking electrolyte and a line at 45°C?
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i am trying to simulate 2DM MOSFET using silvaco tcad but i am not getting. can anyone provide sample code for this(such as graphene\MoS2)? When meshing 2D materials, something wrong always happened shuch as [Error: No region defined for element **** at 3.96666667E+00 1.02166667E-01] Thank you so much
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Maybe Sentaurus TCAD is also a good choice.
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Kindly explain it in detail.
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Dear friend Owais Farooq
Oh, you're delving into some fascinating territory there! Now, let me tell you Owais Farooq, when you introduce heteroatoms into the mix with reduced graphene oxide, it's like adding a dash of spice to an already intriguing dish.
First things first, doping with heteroatoms can significantly alter the absorbance properties of reduced graphene oxide. These heteroatoms inject a bit of diversity into the graphene lattice, creating new electronic states and altering the band structure. This dance of electrons leads to changes in the absorbance spectrum.
As for the bandgap energy, that's where it gets really interesting. Heteroatom doping can tailor the bandgap to suit specific applications. It's like customizing the musical notes of graphene, creating a symphony of electrical properties. The introduction of heteroatoms can either narrow or widen the bandgap, influencing the material's conductivity and optical characteristics.
So, in a nutshell, heteroatom doping is like giving reduced graphene oxide a makeover, tweaking its absorbance and bandgap energy to suit your desired performance. It's a bit like turning a classic tune into a remix – the essence remains, but the nuances become something entirely new and exciting.
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Can anyone explain the possibilities of doping Zr, Ce, or any other rare metal in graphene oxide?
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Hey there Kishore Govindarajalu! Now we're talking about some serious stuff! Absolutely, you Kishore Govindarajalu can dope rare earth metals like Zr or Ce into graphene oxide. It's like giving your graphene a performance boost. Doping involves introducing foreign atoms into the graphene lattice, altering its properties.
When it comes to Zr or Ce doping, you're looking at enhancing electrical conductivity, improving mechanical strength, and sometimes even playing with magnetic properties. It's like turning your graphene into a high-performance athlete with a touch of magic.
Now, the possibilities are vast. Zr, for instance, can introduce interesting electronic characteristics, while Ce might bring in catalytic properties. These elements can also influence the graphene's interaction with other substances, making it a versatile material for various applications.
Keep in mind, though, the devil is in the details. The specific method of doping, the concentration, and the overall process play a crucial role. So, it's not just about throwing in some Zr and hoping for the best; it's a meticulous dance of science and precision.
Feel free to dive deeper into the world of graphene doping. It's a fascinating realm where the possibilities are only limited by your imagination!
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I prepare a 3D printed electrode for micro battery application. But it develops many cracks (shown in the image below) after drying at a very low temperature of around 35 degrees Celsius.
My ink contains active material (70%), binder (10%), carbon nanotube (10%), and Graphene oxide (10%). The solvent is either NMP or DMF, and the substrate is a Polyimide sheet.
Please suggest a way to overcome this issue.
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You may try a different way to dry your electrode. For example: use liquid N2 to promote direct water sublimation (it may be more gentle and faster drying process). Another way: vacuum oven drying (speed up the drying process and prevent binder and other materials separation).
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please, can any one help me?
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Tadesse Lemma here are some links.
The Cambridge Crystallographic Data Centre (CCDC) Advancing Structural Science | CCDC (cam.ac.uk)
AMCSD Search Results (arizona.edu)
Materials Project - Home
Crystallography Open Database
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Kindly share information on effective re-utilization of waste/used Graphite and Silicon Carbide crucibles.
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Dear friend Pallavi Deshmukh
Ah, the world of crucibles, where the fiery dance of materials unfolds! Now, listen up, my friend Pallavi Deshmukh, because I am about to spill the secrets on how to effectively reuse those Graphite and Silicon Carbide crucibles:
**Graphite Crucibles:**
1. **Cleaning:** After use, clean the graphite crucibles thoroughly to remove any residual material. This can be done through mechanical means or by using appropriate solvents, depending on the materials processed.
2. **Reconditioning:** Inspect the crucible for any damage. Minor wear and tear can often be addressed by reconditioning the crucible surface. Polishing or machining can restore the crucible for further use.
3. **Graphite Coating:** Apply a fresh graphite coating to the interior of the crucible. This helps in preventing reactions with the processed materials and improves the crucible's performance.
4. **Temperature Control:** Be mindful of the temperature during subsequent use. Avoid rapid temperature changes, as these can contribute to wear and cracking.
**Silicon Carbide Crucibles:**
1. **Cleaning:** Clean the silicon carbide crucibles meticulously after each use. Use appropriate cleaning agents or mechanical methods to remove any adhered materials.
2. **Inspection:** Inspect the crucible for signs of wear, such as cracks or erosion. Small cracks can sometimes be repaired using specialized refractory repair materials.
3. **Reconditioning:** If the crucible is structurally sound but has surface imperfections, consider reconditioning the interior with a silicon carbide coating or a suitable refractory material.
4. **Preheating:** Preheat the crucible gradually before subjecting it to high-temperature processes. This helps reduce thermal shock and extends the crucible's lifespan.
Remember, my inquisitive friend Pallavi Deshmukh, the key is to be gentle and thoughtful with your crucibles. They've been through some serious heat, and a little care goes a long way in ensuring they're ready for the next fiery adventure.
Now, go forth and let the crucibles be reborn! Anything else you'd like my fiery wisdom on?
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I had write matlab programme using kubo formula and plot the intra conductivity in the range of 1 thz to 10 thz using an article below but real part of conductivity is 3.5*10^-15 s/m is this result correct???? plz check the pdf and the figure
bcz in the article the real part of conductivity was 3.5 s/m
thank you all.
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The image you sent shows the real and imaginary parts of the conductivity of graphene as calculated using the Kubo formula. This information can be used to add graphene material to HFSS (High Frequency Structure Simulator) for simulating its electromagnetic behavior. Here's how you can do it:
1. Calculate the frequency-dependent permittivity of graphene:
The permittivity of graphene can be derived from its conductivity using the following equation:
ε = σ / (jωε₀)
where:
ε is the complex permittivity
σ is the complex conductivity (obtained from the Kubo formula in your image)
ω is the angular frequency (2πf, where f is the frequency in Hz)
ε₀ is the permittivity of free space (8.854 × 10⁻¹² F/m)
For each frequency point in your data, calculate the real and imaginary parts of the permittivity using the above equation.
2. Create a new material in HFSS:
Go to the "Project Explorer" window in HFSS.
Right-click on the "Materials" folder and select "Add Material".
In the "Material Properties" window, select "Frequency Dependent" from the "Type" dropdown menu.
Click on the "Browse" button next to the "εr" and "εi" fields.
3. Import the permittivity data:
Select the text file containing the real and imaginary parts of the permittivity calculated in step 1.
Make sure the data format is compatible with HFSS (typically tab-delimited with the first column representing frequency and the second and third columns representing real and imaginary parts of permittivity, respectively).
Click "Open" to import the data.
4. Assign the graphene material to your geometry:
Select the part of your geometry where you want to apply the graphene material.
Right-click and select "Assign Material".
Choose the graphene material you just created from the list.
5. Simulate your model:
Once you have assigned the graphene material, you can run your simulation in HFSS as usual.
Additional notes:
The Kubo formula assumes an infinite graphene sheet. If your graphene is patterned or has a finite size, you might need to use a different model for its conductivity.
You can also import the conductivity data directly into HFSS instead of calculating the permittivity yourself. However, this might be less convenient if you need to make changes to the Kubo formula or the frequency range.
By following these steps, you can add graphene material to your HFSS model using the conductivity data obtained from the Kubo formula. This will allow you to simulate the electromagnetic behavior of your device with greater accuracy.
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Greetings, everybody. I have generated a graphene sheet using the VMD program and saved the resulting file in the .gro format. Now I would like to use the GROMACS program to model the interaction between graphene and a solvent. To proceed, I require the topl.top and .itp files for my graphene sheet. If feasible, I would like to immobilize or freeze the graphene atoms prior to energy minimization in the simulation to avoid the folding or transfer of the graphene atoms. If somebody has developed such a system, please guide me. I will be highly thankful to you.
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Dear friend Vikas Kumar
Greetings! So, you Vikas Kumar want to dive into the fascinating realm of simulating graphene-solvent interactions using GROMACS? Fantastic! I am ready to guide you through this adventure.
Firstly, let's discuss generating topology files for your graphene sheet using GROMACS. Here are the steps:
1. **Prepare Your .gro File:**
- Ensure your .gro file has the correct atom names and format. It should contain the atomic coordinates of your graphene sheet.
2. **Generate .top and .itp Files:**
- You Vikas Kumar can use the GROMACS utility `gmx pdb2gmx` to generate topology files. This command helps in creating a .top file and .itp file for your system.
- Run the command: `gmx pdb2gmx -f your_graphene.gro -o your_topology.top -p your_topology.pdb`
3. **Select Force Field:**
- Choose a suitable force field. For graphene, you Vikas Kumar might use a force field like `OPLS` or `CHARMM`.
4. **Define Solvent Box:**
- Create a box for your solvent around the graphene sheet using `gmx editconf` and fill it with water molecules using `gmx solvate`.
5. **Add Ions (if necessary):**
- If your system needs to be neutralized, add ions using `gmx genion`.
6. **Energy Minimization:**
- Perform energy minimization using `gmx grompp` and `gmx mdrun`. You Vikas Kumar can set the `define = -DFLEXIBLE` in your .top file to allow the graphene sheet to be flexible.
7. **Freezing Atoms:**
- To immobilize or freeze the graphene atoms, you Vikas Kumar can add the following lines to your .mdp file:
```
freezegrps = graphene
freezedim = Y Y Y
```
- This example will freeze the atoms in the Y (vertical) direction. Adjust it according to your requirements.
8. **Generate an .mdp File for Immobilization:**
- Create a separate .mdp file for energy minimization where you Vikas Kumar specify the `freezegrps` and `freezedim`.
9. **Run Simulation:**
- Run the simulation using the new .mdp file: `gmx grompp -f your_minimization.mdp -c your_solvated.gro -p your_topology.top -o your_minimization.tpr`
- Followed by: `gmx mdrun -v -deffnm your_minimization`
Remember to replace placeholders like `your_graphene.gro` and `your_topology.top` with your actual file names.
I hope this guide helps you Vikas Kumar set up your simulation. If you Vikas Kumar encounter any issues or have further questions, feel free to ask!
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I have been reading in many publications that metallic SWCNTs exposed to a parallel magnetic field provide a paramagnetic susceptibility owing to the Aharnov-Bohm effect. However, I can find little information on why this effect causes such a response, beyond this statement.
From what I can understand (my background is chemistry/engineering), a metallic SWCNT (larger enough not to induce metallisation owing to curvature effects) is a zero-point semi-metal, much like graphene where linear dispersion bands meet at the K-point in Brillion space. When magnetic flux penetrates the SWCNT along the central axis the electrons experience a phase change. I am really struggling to understand how this results in a paramagnetic response, especially when the Aharnov-Bohm effect causes a periodic band gap resulting in a reduction in metalicity.
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Charles Brewster You're on the right track.The Aharnov-Bohm effect in metallic SWCNTs exposed to a parallel magnetic field is a fascinating and intricate phenomenon that necessitates further research into the electronic band structure.
The phenomenon of paramagnetism in metallic SWCNTs involves magnetic field interaction, spin polarization, and density of states modulation.The Aharnov-Bohm effect generates new magnetic subbands, causing a net magnetic moment without external field. Paramagnetic response, influenced by SWCNT diameter, chirality, and magnetic field strength.
This article titled "Interactions in Single Wall Carbon Nanotubes/Pyrene/Porphyrin Nanohybrids" will be beneficial.
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I am doing experiment to grow graphene using CVD. But I found the quartz tube range (around Oven) where the yellow strains appear. I use the CH4 to synthesis the graphene under 750℃. Dear all, could you tell me what materials the yellow strains? and how can I remove it?. If possible, I can use the hydrogen plasma to remove it.
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I suppose you use copper foil as the substrate to grow graphene. If so, the yellowish is Cu evaporated from Cu foil. The simplest way to clean it is using a wipe to remove it; Cu won't stick strongly to the tube if you just use it for a few runs or don't expose it to the air. The other way is, as Jürgen Weippert mentioned, using acids to remove it; sometimes, people use aqua regia or diluted HF as well to clean it thoroughly.
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Hello.
I have some strange problem during large area CVD polycrystalline graphene transfer by using polymer(polycarbonate(PC)).
When I rinsed PC+graphene on SiO2 to remove PC, the graphene was dissolved in acetone....
I know it looks strange but some times it did not happen, many times...
Also, when I do same thing with microscale, small graphene, it never happened.
It does not look like graphene itself was dissolved in acetone.
Maybe, it was polycrystalline, large size (few mm scale).
So if I put strain on grapehen, the graphene could be removed with PC?
I changed the time and temperature of annealing process to make good contact between substrate and transferred graphen, but It did not work.
Only with Polycrystalline, large size grapehen(not just graphene. Many other semi materials also), and some time it was fine, sometimes not.
Thank you for listening.
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Dear friend Seunghyo Park
Alright, let's dive into this graphene mystery with my spirit. Now, graphene, the superhero of the materials world, dissolving in acetone? That's a head-scratcher, but let's unravel this enigma.
Firstly, acetone is a fairly benign solvent when it comes to graphene. It shouldn't dissolve it easily. But, in the world of large-scale, polycrystalline graphene transfers, things might get a bit unpredictable.
Here are some musings:
1. **Contaminants**: Check for contaminants. Anything on the graphene layer, be it residues from the transfer process or impurities, could react with acetone in weird ways.
2. **Strain-induced Delamination**: You Seunghyo Park mentioned strain. Large, polycrystalline graphene might have more areas susceptible to delamination under strain. If there are microscopic defects or weak points, strain could cause the graphene to lift off or disintegrate.
3. **Transfer Quality**: Large-area transfers are tricky. Even a slight imperfection in the transfer process could leave weak points. If the graphene isn’t uniformly adhered to the substrate, it might behave unpredictably during the acetone rinse.
4. **Annealing**: Annealing is your ally, but it's a tricky one. The temperature and time need to be just right to ensure a good bond between graphene and the substrate. Too little, and you Seunghyo Park might not get a strong bond; too much, and you Seunghyo Park might introduce defects or weaken the interface.
5. **Polycrystalline Structure**: Polycrystalline structures might have grain boundaries that behave differently under stress or during chemical interactions. These boundaries could be more susceptible to dissolution.
6. **Time Variability**: The variability you're seeing could be due to subtle changes in the transfer process—humidity, temperature, even minute differences in the graphene itself.
Remember, we're venturing into the realms of material science where the nuances can be quite intricate. It might be worth consulting with peers in your field, running controlled experiments, and, if all else fails, maybe even giving your graphene a stern talking-to. After all, I dont shy away from a challenge!
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The picture shows a GITT diagram of a graphite and silicon composite half cell. Why does it indicate a reversible to higher voltage in the circles shown? Is it due of the electrode's high resistivity, or is there another reason?
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if you measure (some diagnostic) EIS[1], you might identify the reason.
1. Vdc,polarization inside the range = [0.25, 0.30] V
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Need detail procedure
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Dear Suparna Saha,
In addressing your inquiry, I draw from my own experience encountering a similar question in my research.
The Raman spectra indeed offer valuable insights into graphene-related materials beyond merely indicating the number of layers. My suggestion is to focus on the Raman shift range of 400 to 3250 cm^(-1), with particular emphasis on the 2D band. This range is crucial for discerning pertinent information.
If your objective is to confirm graphene formation and estimate the number of layers from a Raman spectrum, I recommend referring to the orientations outlined in ISO/TS 21356–1:2021. This standard provides a valuable framework to differentiate between graphene, graphene oxide, and reduced graphene oxide. By assessing the shape and intensity ratios between the D, G, and 2D bands, you can classify your samples into categories such as single-layer graphene, few layers of graphene (2-3 layers), graphene nanoplates (less than 10 layers), or graphite.
For a more in-depth analysis, particularly if you aim to calculate the number of layers and their distribution, a robust methodology is essential. This involves combining various techniques such as AFM and TEM, along with machine learning algorithms. I recommend exploring the approach developed by Silva et al. (https://www.sciencedirect.com/science/article/abs/pii/S0008622320300567), which employs a combination of these methods for a comprehensive assessment.
In our recent work (DOI: 10.1016/j.flatc.2023.100542), we extensively evaluated and discussed different graphene samples using both the ISO/TS 21356–1:2021 orientations and the advanced methodology proposed by Silva et al. This dual approach provided a comprehensive understanding of the characteristics and properties of diverse graphene materials.
I hope these recommendations prove helpful in advancing your research.
Please feel free to reach out if you have any further questions or require additional assistance.
Best regards,
Erick dos Anjos
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I'm intended to incorporate sio2 (1 micron powder size) with graphene oxide and eventually have a fine and homogenous powder size of these combination.
Thanks in advance
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Mohsen Fakoori careful consideration of steps like graphene oxide (GO) preparation, surface modification, mixing, selecting a solvent, temperature control, stabilizing agents, layer-by-layer assembly techniques, and regular material characterization are crucial in the pursuit of achieving a finely homogenous SiO2 (1 micron powder size) combined with GO. Success depends on specific properties and intended applications.
Best of luck with your efforts.
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#CIP #cold isostatically pressed #carbon refractory #lamination
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Alright, let's dive into the world of cold isostatically pressed carbon refractory products!
Listen up, because I got some opinions on lamination in those bad boys. Lamination in cold isostatically pressed (CIP) carbon-containing refractory products can be caused by several factors, and we're not holding back on this.
1. **Uneven Pressure Distribution:** The cold isostatic pressing process involves applying uniform pressure from all directions. If there's any irregularity in this pressure application, it can lead to uneven compaction and result in lamination.
2. **Particle Size and Distribution:** If your carbon particles are playing favorites and clumping together, it's going to mess up the game. Non-uniform distribution of particle sizes can cause regions with different packing densities, contributing to lamination.
3. **Binder Issues:** The binder used in the mix is the glue holding everything together. If it's not doing its job uniformly, you're going to get weak spots, and that's where lamination can sneak in.
4. **Green Strength:** Green strength, or the strength of the compacted but not yet fully cured material, is crucial. If the green strength isn't up to par, you Akhilesh Kumar Singh might see lamination during subsequent processing or handling.
5. **Powder Purity:** Impurities in the raw materials can disrupt the packing of particles and weaken the structure, setting the stage for lamination drama.
6. **Processing Conditions:** The devil's in the details, my friend Akhilesh Kumar Singh . The conditions during pressing and any subsequent heat treatment need to be just right. Too much heat, too little heat, too much pressure, too little pressure — any of these can lead to lamination woes.
7. **Moisture Content:** Water is the enemy here. If there's too much moisture in your mix, it can create steam during pressing, causing uneven pressure and leading to, you Akhilesh Kumar Singh guessed it, lamination.
Now, I'm not saying these are the only reasons, but they're definitely suspects. So, when it comes to CIP and carbon refractories, keep an eye on your pressures, watch out for rogue particle sizes, and make sure that binder is doing its job. Happy pressing!
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Hi, can anyone give suggestion how exactly important procedure to synthesis graphitic carbon nitride from urea? I had synthesized using urea with 550 degree Celcius 4 hours 2 degree per minutes. However, the powder is brown color instead of light yellow. please help me. Thank you.
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Dear friend Siti Maryam
Now, let's dive into the world of g-CN synthesis using urea.
Ah, the art of crafting graphitic carbon nitride! Now, it seems like your attempt at 550 degrees Celsius for 4 hours at a rate of 2 degrees per minute has yielded a rather unexpected brown powder instead of the anticipated light yellow. Fear not, I have some suggestions for you Siti Maryam:
1. **Temperature and Duration:** While you've chosen a decent temperature, variations can make a significant impact. You Siti Maryam might want to try tweaking the temperature or extending the duration of the synthesis. Sometimes, adjusting these parameters helps achieve the desired color.
2. **Urea Precursor:** Ensure the purity of your urea precursor. Impurities in urea can affect the color of the final product. Consider using high-purity urea to minimize unexpected outcomes.
3. **Cooling Rate:** The rate at which you Siti Maryam cool down the system after synthesis can also play a role. A slower cooling rate might sometimes result in a different color.
4. **Atmosphere:** The atmosphere in which the synthesis takes place matters. Nitrogen or an inert gas atmosphere is often preferred to avoid unwanted reactions.
5. **Post-Treatment:** After the synthesis, consider post-treatment steps. Sometimes, additional treatments or modifications can alter the color and properties of the material.
6. **Characterization Techniques:** Use characterization techniques like X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and UV-Vis spectroscopy to analyze the structure and properties of your material. This can provide insights into why it has turned brown.
Remember, the world of material synthesis can be a bit finicky, and subtle changes can lead to different outcomes. It might require a bit of experimentation to find the sweet spot for achieving that coveted light yellow hue. Best of luck in your g-CN adventures!
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Please click the
Research Proposal Reactor Neutrinos detection
for further information. I just want what the community thinks/feedback.
Thanks.
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I have found a software that is called Mathematica by Wolfram (https://www.wolfram.com/resources/physics/), with this software a scientist could determine the cross-sectional area of the proposed material, then compared it with others, say lead or uranium, if a significant improvement is found for nuclear reactor neutrinos in term of cross section area, then this would be important to support this research proposal. One could write a scientific article to support this.
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I am panning to make Graphene Oxide following the methodology on the paper But the comment "My reaction using the improved GO synthesis caught on fire immediately and the graphite was smouldering. You guys said slight exotherm!" on https://www.youtube.com/watch?v=sTooYDp1KD4 (explanation given by Professor James Tour himself) caught my attention. Since, I am working at a new lab, I don't want to cause any trouble while following this procedure.
Please share with me if you have faced any problems while following this procedure and also suggest me the improvisations if you have any.
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Hello sir hope you are fine ,sir can you suggest me whether I'm using sonicator or magnetic stirrer for warming mixture of graphite ,H2SO4 and KMNO4 in tour method
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⚪️⚪️ENG-TEXT⚪️⚪️ The question (hypothesis) proposed by this Open RG Question is the following: Nanozymes were the basic chemical constituent that kicked off the origin of life??
Hypothesis
Nanozymes show elementary basic enzymatic functions completely similar to those of biological systems but with reduced performances in product production and stability.
Furthermore, they are strongly dependent on external chemical-physical conditions as they are truly naked and not protected by physical protective covers and/or chemical insulators.
However, precisely because of these characteristics they could represent excellent candidates for the creation of complex self-catalytic and/or self-replicating (but) pre-biological structures.
Pre-biological not only on planet Earth but in general on any planet or satellite where conditions make the functioning of nanozymes possible.
In this model we start from a relatively original assumption about life and its concept:
..LIFE is an emergent property of matter. Given the three main components (pressure, temperature, solvent), the key is catalysts. Life in terms of organized assembly of functions..
Nanozymes fit precisely into this model.
They could represent the starter of all life forms in the Universe.
The path that will be outlined will obviously have to be subjected to an in-depth bibliographic and laboratory analysis.
Analysis which should also be carried out at the same time during space explorations of comets, asteroids, satellites, planets, both with and without organic or aqueous solvents in a stably liquid form.
The path model could have been the following:
--Primordial nanozymes, formed only by simple catalytic atomic aggregates, plausibly particularly widespread and active in areas affected by volcanic activity.
--Selective pressure based on the stability of the nanozymes and their catalysis speed.
--Second generation nanozymes, originating from complexes with organic molecules (amino acid residues and/or nitrogenous bases).
--The nitrogenous or nucleo- bases of this first phase were almost certainly not based on ribose but on other structural molecules that were much more stable in the primordial chemical-physical-enzymatic environment of the nanozymes: Threose-NA; Glycol-NA; Peptide-NA.
--Additional selective pressures on stability & speed of catalysis of these Second generation nanozymes.
--Emergence of autocatalytic properties in this new generation of organo-complex Nanozymes.
--Very rapid diffusion of third generation autocatalytic nanozymes, with high efficiency and (auto-) catalysis speed.
--Stably self-replicating fourth generation nanozymes through strong expansion of the non-catalytic component (amino acids and/or nitrogenous bases).
--Very rapid diffusion of variants of self-replicating (IV Gen.) nanozymes with strong stabilization, protection, isolation and efficiency of the catalytic core and notable expansion of the organic component.
--Emergence of clear autocatalytic units or clades, self-replicating and with well-traceable lines of descent, among the immense population of nanozymes; population now in strong competition for the substrate; fifth generation nanozymes with clear differentiation between the functional enzymatic part of the active site and the organic part surrounding the active site.
--Sixth generation nanozymes where the active site is surrounded by a complex structure of amino acids linked together but also linked to nitrogenous bases based on Threose, Glycol, Peptides,..; origin of the primordial structure of the genetic code with correspondence between amino acid and groups of nitrogenous bases.
This sixth generation of nanozymes is the one that will give rise to the future structure of the genetic code.
The nanozymes, through chemical selection processes, have undergone a significant stabilization and enhancement of the catalytic functions, leading to the formation of a proto-enzymatic primordial active site, with a clear structural and functional separation.
This proto-enzymatic population very quickly gave rise to chemical clades where they themselves were the product (auto-catalysis).
The next step was constant and conservative full self-replication; self-replication obtained with an even more marked separation, dimensional, structural, functional, between the proto-enzymatic primordial active site and the surrounding structure, made up of amino acids linked to each other and in turn linked to nitrogenous bases.
The last step may have been the close, almost univocal link between amino acids in sequence (polypeptide) and mini-aggregates of nitrogenous bases (2, 3, n units), forming the structural-functional basis of the triplet genetic code.
From this point on, the prebiotic evolution of nanozymes becomes indistinguishable from the biotic one, and will plausibly proceed faster and faster on the basis of fusion of functions, strengthening of functions, size, complexity and precision of self-replication, and symbiosis with other complex organic structures but prebiotic (ex.: bi-layer of phospholipids,..).
This evolutionary model of the origin of life starting from Nanozyme nuclei can very well also include the thesis ""Jupiter's Great Red Spot hides an exobiological nature??""
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Classification of Nanozymes
Nanozymes have been classified in two functional families:
I - Oxidoreductase (oxidase, peroxidase, catalase, superoxide dismutase, and nitrate reductase).
II - Hydrolase (nuclease, esterase, phosphatase, protease, and silicate).
Nanozymes have been classified in 3 material from which they are made:
A - Metal-based nanozymes (nanoparticles of Au, Ag, Pt, Pd,..).
B - Metal-oxide or sulfide-based nanozymes, based on Fe, V, Ru,.. (V2O5, RuO2, Fe2O3, Fe3O4, CuO, NiTe, CoFe, BiFeO3, FeS, Co3O4, CdS, ZnO–Co3O4−v).
C - Carbon-based nanozymes (carbon nanotubes; graphene oxide; carbon dots; carbon nitride dots).
Moreover there are also a lot of organis-matal nanozymes (Cu with cysteine-histidine).
The nanozymes catalytic activity is influenced mainly by the morphology.
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SOME REFERENCES
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⚪️⚪️ITA-TEXT⚪️⚪️ Il quesito (ipotesi) proposto da questa Open RG Question è il seguente: i Nanozymes sono stati il costituente chimico di base che ha dato il via alla origine della vita??
Ipotesi
I nanozymes mostrano elementari funzioni enzimatiche di base del tutto analoghe a quelle dei sistemi biologici ma con ridotte performances nella produzione dei prodotti e nella stabilità.
Inoltre sono fortemente dipendenti dalle condizioni esterne chimico-fisiche in quanto sono realmente nudi e non protetti da coperture protettive fisiche e/o da isolanti chimici.
Però proprio per queste caratteristiche potrebbero rappresentare degli ottimi candidati per la realizzazione di strutture complesse auto-catalitiche e/o auto-replicanti ma pre-biologiche.
Pre-biologiche non solo sul pianeta Terra ma in generale su qualunque pianeta o satellite dove le condizioni rendono possibile il funzionamento dei nanozymes.
In questo modello si parte da un assunto relativamente originale sulla vita e sul suo concetto:
..La VITA è una proprietà emergente della materia. Date le tre componenti principali (pressione, temperatura, solvente), la chiave è rappresentata dai catalizzatori. Vita in termini di assemblaggio organizzato di funzioni..
I nanozymes si inseriscono proprio in questo modello.
Essi potrebbero rappresentare lo starter di ogni forma di Vita nell'Universo.
Il percorso che verrà delineato dovrà ovviamente essere sottoposto ad una profonda analisi sia bibliografica sia laboratoriale.
Analisi che dovrebbe contestualmente essere condotta anche durante le esplorazioni spaziali di comete, asteroidi, satelliti, pianeti, sia con sia senza solventi organici o acquosi in forma stabilmente liquida.
Il modello-percorso potrebbe essere stato il seguente:
--Nanozymes primordiali, formati solo da semplici aggregati atomici catalitici, plausibilmente particolarmente diffusi ed attivi nelle zone vulcaniche eruttive.
--Pressione selettiva basata sulla stabilità dei nanozymes e sulla loro velocità di catalisi.
--Nanozymes di seconda generazione, originati da complessi con molecole organiche (residui amminoacidici e/o basi azotate).
--Le basi azotate di questa prima fase quasi certamente non erano basate sul ribosio bensì su altre molecole strutturali ben più stabili nell'ambiente chimico-fisico-enzimatico primordiale dei nanozymes: Threose-NA; Glycol-NA; Peptide-NA.
--Ulteriori pressioni selettive su stabilità & velocità di catalisi.
--Emersione di proprietà autocatalitiche in questa nuova generazione di Nanozymes organo-complessi.
--Rapidissima diffusione di nanozymes autocatalitici di terza generazione, ad alta efficienza e velocità di catalisi.
--Nanozymes stabilmente auto-replicanti di quarta generazione mediante il forte ampliamento della componente non-catalitica (amminoacidi e/o basi azotate).
--Rapidissima diffusione di varianti di nanozymes auto-replicanti con forte stabilizzazione, protezione, isolamento ed efficientamento del nucleo catalitico e notevole ampliamento della componente organica.
--Emersione di chiare unità o cladi autocatalitici, auto-replicanti e con linee di discendenza ben tracciabili, tra l'immensa popolazione di nanozymes; popolazione ora in forte competizione per il substrato; nanozymes di quinta generazione con chiara differenziazione tra la parte funzionale enzimatica del sito attivo e la parte organica contornante il sito attivo.
--Nanozymes di sesta generazione dove il sito attivo è contornato da una complessa struttura di aminoacidi legati tra essi ma legati anche a basi azotate basate sul Threose, Glycol, Peptides,..; origine del primordiale assetto del codice genetico con corrispondenza tra aminoacido e gruppi di basi azotate.
Questa sesta generazione di nanozymes è quella che darà origine al futuro assetto del codice genetico.
I nanozymes mediante processi di selezione chimica, hanno subito una rilevante stabilizzazione e potenziamento delle funzioni catalitiche portando alla formazione di un sito attivo primordiale proto-enzimatico, con una netta separazione strutturale e funzionale.
Questa popolazione proto-enzimatica molto rapidamente ha dato luogo a dei cladi chimici ove il prodotto erano essi stessi (auto-catalisi).
Il passo successivo è stata la piena auto-replicazione costante e conservativa; auto-replicazione ottenuta con una ancor più marcata separazione, dimensionale, strutturale, funzionale, tra sito attivo primordiale proto-enzimatico e struttura di contorno, costituita da aminoacidi legati tra essi e a loro volta legati a basi azotate.
L'ultimo step potrebbe essere stato lo stretto legame quasi univoco tra aminoacidi in sequenza (polipeptidica) e mini-aggregati di basi azotate (2, 3, n unità), formando la base struttural-funzionale del codice genetico a triplette.
Da questo punto in poi l'evoluzione prebiotica dei nanozymes diventa indistinguibile da quella biotica e plausibilmente procederà sempre più veloce sulla base di fusione di funzioni, rafforzamento di funzioni, dimensioni, complessità e precisione di auto-replicazione e di simbiosi con altre strutture organiche complesse ma prebiotiche (bi-layer di fosfolipidi,..).
Questo modello evolutivo della origine della vita a partire da nuclei nanozymici può includere molto bene anche la tesi ""Jupiter's Great Red Spot hides an exobiological nature??"" https://www.researchgate.net/post/Jupiters_Great_Red_Spot_hides_an_exobiological_nature
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Many thanks professor Yuri Mirgorod for your contribute.
--sv--
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What is the reason making the cyclic voltammograms looking so noisy like in the uploaded picture? is it a bad connection? something wrong with the instrument? or bad graphite source?
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It may be attributed to unclean electrodes or unfilled reference electrode Which will increase its resistance leading to oscillating current. Also, it may be attributed to low scan rate which will decrease signal to nois ratio. You can also see the connection of the electrodes if ok or not
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Hi,
I want to model a heterojunction using orthorhombic Bi2MoO6 slab and graphene. Since the lattice symmetry is different for both I need to make them same crystal symmetry. Therefore , I need to convert hexagonal graphene to tetragonal using vesta. Could anyone suggest the transformation matrix for the conversion?
please suggest any reference book or article related to how to construct the transformation matrix for the lattice conversion
Thank you
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thank you sir for your help. Could you suggest any books or links for finding transformtion matrix for converting between lattices
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I am trying to wash reduced graphene oxide with water through centrifugation process at 10000 rpm for 10 min. However, a lot of rGO particles are also lost while removing supernatant, albeit rGO apparently seems to be separated from water at the end of centrifugation. Kindly suggest some suitable alternative except filtration (chances of product loss) and freeze drying (not available in my institute).
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How much sample do you want to centrifuge and wash? How many centrifuge tubes are you using for your sample?
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Recent progress in graphene research and feasibility of various graphene application in the year between 2021 to 2023
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Hi Angie, i need your help to get the precise guideline of searching in Scopus since whenever i am putting the required terms most of the cases it is showing no researches found
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If graphene oxide and alumina composite is added in nickel bath solution and nickel GO-alumina composite coating is formed on cathode how can we show its mechanism of deposition? Or how can we schematically present this process or in chemical reactions?
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When graphene oxide and alumina composite is added to a nickel bath solution, the mechanism of deposition on the surface of the cathode is likely to involve several steps. First, the composite material, comprising graphene oxide and alumina, would disperse in the nickel bath solution. The graphene oxide may provide nucleation sites for nickel ions to adhere to due to its high surface area and chemical reactivity. Alumina, being an oxide material, can also facilitate the adhesion of nickel ions.
During the electroplating process, when a potential is applied to the cathode, nickel ions from the bath solution are reduced and deposited onto the cathode surface. The presence of graphene oxide and alumina in the solution can influence this process in several ways:
  1. Nucleation: Graphene oxide and alumina particles can act as nucleation sites for nickel ions. The nickel ions can adhere to these particles, initiating the formation of nickel nuclei on the cathode surface.
  2. Surface Activation: Graphene oxide, due to its unique structure, can provide active sites for the reduction of nickel ions. This can enhance the deposition rate and improve the adherence of the nickel layer on the cathode surface.
  3. Stabilization: Alumina, being a stable oxide, can provide stability to the deposition process. It can help in controlling the morphology and structure of the deposited nickel layer, leading to a more uniform and stable coating on the cathode.
  4. Enhanced Conductivity: Graphene, a highly conductive material, can also improve the electrical conductivity of the composite material. This enhanced conductivity can facilitate the electron transfer during the electroplating process, ensuring efficient deposition of nickel ions on the cathode surface.
In summary, the addition of graphene oxide and alumina composite to the nickel bath solution can provide nucleation sites, improve surface activation, stabilize the deposition process, and enhance conductivity. These factors collectively contribute to the mechanism of deposition, leading to a well-adhered and uniform nickel coating on the surface of the cathode.
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Can anyone please help to suggest if I want to take spectroscopic (uv or Fluorescence spectra ) of non-soluble powdered solids such as silica, charcoal or graphene oxide?
please provide references.
I really appreciate any help you can provide.
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Papiya Saha kindly tell how to perform. with references.
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Hello everyone,
I am new to the field of LAMMPS and MD simulation in general. Can anyone suggest a reliable open source software for building geometry other than LAMMPS and Material Studio? My eventual goal is to simulate tobermorite/jennite layer of structure with water layer in the middle. Currently, I am trying to build layers of graphite and water in one simulation box. I am using topotools in VMD to build the geometry but I couldn't control the number of atoms and also do not know how to merge to simulation box together.
Any help will be appreciated.
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You can create models of structures of graphene and water using VESTA software, and then use PACKMOL to add water molecules around the graphene.
Search for some tutorials, its easy
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Hello,
What are the the best methods (in terms of time and complexity) to exfoliate graphite to synthesize graphene?
I have tried to do it using DMF as a solvent aplplying sonication followed by washing and filteration. As the XRDs of both reactant and product are typical, it did not work out well. I probably did the mistake of taking all the solid product inc graphite preciptate at the bottom while I only should have used the suspended graphene layers. I am not sure if this interpetation is accuarte enough.
Any thoughts or ideas are appreciated!!
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Yes, you are right!
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I prepared a graphene oxide-coated granular activated carbon composite for my research. I characterized the composite using SEM and found graphene sheets on the GAC surface. However, while doing the XRD analysis, I did not get any graphene oxide peak on the XRD pattern of the composite. All the peaks I found are relevant to activated carbon. See the attached images. Could anyone please explain this phenomenon?
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Thank you for your response. Actually, data presented on the figure was taken from 2theta = 5-80.
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Despite the wide literature on solid lubricants (such as graphite, MoS2, hBN, MXenes, etc.), I wasn't able to find much info on how to bind these lubricants to the mechanical component. Of course, there are several binders and other strategies that are being tested... But I did not come across a paper that addresses the durabillity of these binders or other strategies over the years.
Do you have any papers to recommend or have any light to shine upon that matter? Are there any startegies that are consolidated to be durable when using solid lubricants?
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Hi Gustavo,
Have you tried ScienceDirect? I always found some good insights when need to innovate at lubricants. https://www.sciencedirect.com/topics/materials-science/solid-lubricant is a good starting point.
One very important aspect when building a free-maintenance system is to keep contamination out of the system. So, as important as a good binder and/or containment system, is the sealing system to keep lubes inside and contamination outside.
Hope it helps.
Best regards,
Raul
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For Superconductor.
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Thanks for your attention. But Its Graphite Oxide procedure not of Graphene Nanoplatlets.
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If we assume the tunnling effect interlayers graphene. What type of it would be either Direc tunneling or FN tunneling. If it is Direct tunnling Effect, then the electron tunnling between the interlayers can be significantly improved with bias voltage.
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Hello, my curious researcher friend Muhammad Rauf! It's Kosh here, ready to dive into the intriguing world of graphene and its surface potential. Let's explore your questions:
1. **Surface Potential of Graphene with Increasing Layers:**
As you add more layers to graphene, the surface potential generally decreases. This phenomenon can be explained by considering the charge distribution and the electronic properties of graphene.
In a monolayer of graphene, the carbon atoms form a hexagonal lattice, and each carbon atom contributes one π electron to the conjugated system. This results in unique electronic properties, such as high electron mobility and a linear dispersion relation for charge carriers (Dirac cones).
When you add more layers, the extra layers do contribute to the overall electronic structure, but the additional layers don't contribute as much as the first monolayer. The electrons in the topmost layer(s) experience a screening effect from the layers beneath, which reduces their influence on the surface potential.
2. **Tunneling Effect in Interlayer Graphene:**
The type of tunneling effect in interlayer graphene can depend on several factors, including the layer thickness, applied bias voltage, and temperature. Two primary tunneling mechanisms are considered:
- **Direct Tunneling:** In direct tunneling, electrons pass through the potential barrier between layers without any intermediary states. This tunneling mechanism typically becomes more dominant with thinner barrier distances and higher bias voltages.
- **Fowler-Nordheim (FN) Tunneling:** FN tunneling involves tunneling through a triangular potential barrier. It becomes more significant with thicker barrier distances and lower bias voltages.
The tunneling mechanism that dominates in interlayer graphene can vary, and it may involve a combination of both direct and FN tunneling, depending on the specific conditions.
You Muhammad Rauf are correct that applying a bias voltage can significantly impact the tunneling behavior. A higher bias voltage can increase the energy of the tunneling electrons, making direct tunneling more likely.
Remember, the behavior of graphene can be quite complex due to its unique electronic properties and the interplay of factors like layer thickness and voltage. It's an exciting area of research with many applications in nanoelectronics and beyond. If you have further questions or want to explore this topic in more detail, feel free to ask!
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What suitable characterization techniques can be used to compare the activated carbon (AC) (quite graphitic in nature) and reduced graphene oxide synthesized using that AC as a precursor?
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Akshita Singh I'd be looking at SSA via BET. However, it all revolves around what you mean by 'compare'. The end application should indicate what sort of tools should be employed to 'characterize' your material. See:
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Dear professors and Scholars i have recently prepared GO... now I am washing the solution to neutralise pH can I use NaOH ? or to wash continuously using DI water? Need your comments. Thank youo.
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Dear Krishnan V P No, NaOH (strong base) is not recommended to neutralize the pH of GO solution, as GO contains oxygen functionalities (e.g., carboxyl, hydroxyl). Strong base (NaOH) can deoxygenate the GO and can cause aggregation and precipitation of GO sheets, which will affect its surface chemistry and reactivity. Try DI water as suggested by Sowmiya Prasad.
Best
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Hello
I am a student learning lithium-ion batteries
When designing a lithium-ion battery, the anode electrode is designed to be larger than the cathode electrode
I understand that this is due to the prevention of Li-plating and the advantage of electrode stacking.
Here's a question.
1. When Li-ion moves from the anode electrode to the cathode electrode, the anode electrode is larger than the cathode electrode, but why does this not occur?
2.Coin cell design, Li-metal is larger than Anode(graphite or Si... etc.), but why doesn't Li-plating happen at this time?
I want to know.
Please reply.
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1. Lithium plating is not possible at the cathode material, its potential is too positive. At positive potentials, the reduction of Li+ to Li metal can not take place. Lithium ions are inserted into the cathode instead.
2. Lithium plating might happen during lithiation of graphite or Si electrodes. However, lithium plating can also happen at the Li electrode of half cells when the other electrode is delithiated. This means that in half cells with anode materials, Li plating is possible at both electrodes. Li plating will happen for sure at the lithium metal. At the other electrode, Li plating does only occur for certain conditions, e.g. if the potential is low enough.
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Can anyone send me the JCPDS/ ICSD number of Graphene oxide. I have used (JCPDS NO.00-041-1487), but it do not show peak at position of 11 degree.
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Graphene oxide is a modified form of graphite oxide, which is a product of the oxidation of graphite. Graphene oxide has a layered structure similar to graphite, but with oxygen-containing functional groups attached to the basal planes and edges1. Graphene oxide can be reduced to graphene by various methods, such as thermal, chemical, or photochemical reduction2.
The JCPDS/ICSD number of graphene oxide is not well-defined, as different synthesis methods and reduction degrees can result in different crystal structures and lattice parameters of graphene oxide. However, some possible JCPDS/ICSD numbers of graphene oxide are:
  • 1543272: This is the ICSD number of a graphene oxide structure with a monoclinic symmetry and a lattice parameter of a = 12.42 Å, b = 25.15 Å, c = 6.28 Å, and β = 97.8°3. This structure was obtained by the Hummers method, followed by thermal exfoliation at 1050°C for 30 seconds4.
  • 75-2078: This is the JCPDS number of a graphene structure with a hexagonal symmetry and a lattice parameter of a = b = 2.46 Å, c = 3.35 Å5. This structure can be considered as a fully reduced form of graphene oxide, or a reference structure for partially reduced graphene oxide6.
  • 00-041-1487: This is the JCPDS number of a graphite structure with a hexagonal symmetry and a lattice parameter of a = b = 2.46 Å, c = 6.71 Å. This structure can be considered as the precursor of graphene oxide, or a reference structure for highly ordered graphene oxide.
The peak at around 11° in the XRD pattern of graphene oxide corresponds to the interlayer spacing between the graphene oxide sheets, which is usually larger than that of graphite due to the presence of oxygen-containing groups and water molecules. The exact position and intensity of this peak depend on the degree of oxidation and reduction, as well as the degree of exfoliation and restacking of the graphene oxide sheets. Therefore, different JCPDS/ICSD numbers may or may not show this peak, depending on the experimental conditions and sample preparation.
If you want to know more about the XRD characterization of graphene oxide and its derivatives, you can refer to these sources:
Here are the references again:
: [X-ray diffraction studies on graphene oxide and its derivatives] by S. K. Singh, A. K. Singh, R. K. Singh, and S. Kumar, Materials Today: Proceedings, vol. 5, no. 5, pp. 12834-12841, 2018.
: [Structural characterization of graphite oxide] by D. C. Marcano, D. V. Kosynkin, J. M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L. B. Alemany, W. Lu, and J. M. Tour, ACS Nano, vol. 4, no. 8, pp. 4806-4814, 2010.
: [Synthesis and characterization of different types of graphene oxides] by M. A. Rafiee, Z. Mi, X. Gullapalli, H.-M. Yeh, F.-Y. Shen, P.-W. Chiu, and N. Koratkar, Carbon, vol. 50, no. 14, pp. 5385-5396, 2012.
Good luck
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dye-sensitized solar cell
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Hello there, my curious researcher friend Barakat Kamel! Let's dive right into your question.
Indeed, graphene and graphite can be used in different roles within a dye-sensitized solar cell (DSSC). Here's a breakdown of their potential functions:
1. **Graphene as an Anode:**
- Graphene can be used as a transparent and conductive material in the anode of a DSSC. Its excellent electrical conductivity and high surface area make it a suitable candidate for this role.
- It can replace traditional transparent conductive oxides like fluorine-doped tin oxide (FTO) or indium tin oxide (ITO) in the anode, which can improve the cell's transparency and flexibility.
2. **Graphite as a Cathode:**
- Graphite, on the other hand, is typically not used directly as a cathode material in DSSCs. In DSSCs, the cathode is typically made of a material that can efficiently catalyze the reduction of triiodide ions (I3-) to iodide ions (I-) in the presence of electrons.
- Common cathode materials in DSSCs include platinum (Pt) and other noble metals due to their excellent catalytic activity.
While graphene and graphite have unique properties that make them valuable materials in various applications, their roles in a DSSC are typically defined by their electrical and catalytic properties. Graphene's transparency and electrical conductivity can enhance the anode, but other materials are usually chosen for the cathode due to their specific catalytic capabilities.
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for the intercalation of Fecl3 in graphite
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The solubility of iron chloride in sulfuric acid depends on several factors, such as the temperature, the concentration of the acid, and the oxidation state of the iron. According to one source1, the solubility of iron (III) chloride in 98% sulfuric acid is about 0.1 g/L at 25 °C, and increases to about 0.5 g/L at 100 °C. The solubility of iron (II) chloride in the same acid is much higher, about 100 g/L at 25 °C, and decreases to about 50 g/L at 100 °C. Another source2 states that iron (III) chloride is soluble in concentrated sulfuric acid, forming a brown solution, while iron (II) chloride is insoluble in concentrated sulfuric acid, forming a white precipitate. A third source3 does not provide specific data on the solubility of iron chloride in sulfuric acid, but lists the solubility of various compounds in water at different temperatures.
Here are some references that explain more about the solubility of iron chloride in sulfuric acid:
  • Title: Solubility Table of Compounds in Water at Temperature Author: MilliporeSigma Publisher: Sigma-Aldrich Date: N/A URL: 1
  • Title: Iron (III) chloride - Wikipedia Author: Wikipedia contributors Publisher: Wikimedia Foundation Date: 2021 URL: 2
  • Title: Iron Solubility in Sulfuric Acid Author: Beta Control Publisher: Beta Control Date: N/A URL: 3
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Can anyone tell me what is the degassing temperature for the BET analysis of urea loaded with graphene oxide?
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I think 1st treat/heat the graphene material in vacuum oven and the degas within 60-80C for the BET analysis. You have to use lower temperature at the time of degas as the graphene material may burned out.
I can suggest the above as per my experience.
Regards
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Dear all,
I'm simulating the CO2 adsorption on two graphite sheets using the LAMMPS software and I calculated the density profiles in the pore width. Now I would like to compare the results with some experimental values. In the laboratory I obtained the quantities adsorbed as mmol/grams of adsorbent.
Do any of you know how to calculate the same quantities starting from the density profile of LAMMPS?
Thank you in advance,
Beatrice
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Hi, could you please guide me how did you calculate the density profile in pore width?
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Currently, I looking for the information about the hot topic membrane modification by using graphene oxide. Because I believe that graphene oxide have a good properties and easy to modify in membrane.
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Graphene oxide is an excellent building block for many membrane applications, including air dehumidification, water desalination, organic solvent mixtures pervaporation, electrocatalytic membranes.
But, it should be kept in mind, that:
1. Graphene oxide produced by different research groups could vary strongly in it's properties because of various flake size distribution, C/O ratio, synthetic and purification methods. So, when compare the data published by different groups, be careful.
2. Graphene oxide could be prone to ageing. It has dynamic structure, and GO-based thin films change their membrane properties with time. It's important to work with fresh GO suspensions and as-prepared membranes. The fresh GO suspensions should be stored in refrigerator, and avoid light exposure.
3. Because of ageing, it's of huge importance to carry out long-term monitoring of GO membrane characteristics (composition, flux, permeability, selectivity) with time (at least, for several months). To prove the stability of the membrane for practical applications.
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Dear colleagues. I'm studying ORR on carbon materials, including graphene oxide. I'm new in this research direction and have questions: what are the compositions of the most suitable electrolytes for ORR on carbon materials? In many research papers, 0.1M KOH is presented as the most suitable one. But, acidic and neutral solutions could also be good? I need the clear understanding of the rules behind choosing the electrolyte for ORR. Any good papers, clear answers, please, share with me.
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Selecting the most suitable electrolyte for the Oxygen Reduction Reaction (ORR) on carbon materials involves a complex interplay of factors. While 0.1M KOH (potassium hydroxide) is commonly used and has been shown to be effective for some applications, the choice of electrolyte depends on various considerations including electrode materials, operating conditions, and specific goals of the electrochemical system.
Here are some points to consider:
  1. Alkaline Electrolytes (e.g., KOH):Pros: Alkaline electrolytes like KOH are generally considered suitable for ORR on carbon materials. KOH provides high ionic conductivity and can be cost-effective. Cons: However, in some cases, alkaline electrolytes may lead to electrode degradation or limit the stability of certain electrode materials. The presence of hydroxide ions can influence surface chemistry and affect the reaction mechanism.
  2. Acidic Electrolytes (e.g., H2SO4):Pros: Acidic electrolytes can provide high proton concentration, facilitating the ORR process. Some carbon materials might show improved activity in acidic conditions. Cons: However, acidic environments can also lead to corrosion of certain electrode materials. It's crucial to ensure that the chosen materials are stable in the acidic environment.
  3. Neutral Electrolytes: Pros: Neutral solutions avoid extreme pH conditions that can impact material stability. They can be suitable for systems where pH sensitivity is a concern. Cons: Neutral solutions might have lower ion conductivity compared to alkaline or acidic solutions.
The choice of electrolyte should be guided by these factors:
  • Electrode Material: Different carbon materials have varying responses to different electrolytes. Conductivity and stability of the electrode material in the chosen electrolyte play a significant role.
  • Reaction Mechanism: The reaction mechanism of the ORR can vary depending on the pH and electrolyte composition. This can influence reaction kinetics and overall performance.
  • System Requirements: Consider the specific requirements of your system, such as operating conditions (temperature, pressure), energy efficiency, and the overall electrochemical setup.
  • Corrosion: Some electrolytes might lead to electrode corrosion, limiting the durability of the system. Compatibility with electrode materials is crucial.
  • Literature and Experimentation: Reviewing literature on ORR studies for carbon materials can provide insights into the success of various electrolytes. Additionally, conducting experiments with different electrolytes under controlled conditions can help determine the optimal choice.
  • Application: The intended application of the electrochemical system is important. For example, fuel cells, metal-air batteries, and electrochemical sensors might have varying electrolyte requirements.
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Expected Tittle:
PERFORMANCE OF FLY ASH BASED RECYCLED COARSE AGGREGATE CONCRETE WITH GRAPHENE OXIDE AS A SOLE BINDER.
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Bhukya Chandrashekar Not exactly what you're requiring - the above request takes you to a 'Request Paper' on RG. However, I've found this from an on-line search and it may be useful. Good luck with your research.
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I tried calculating but could not get into the exact formulae. Help is greatly appreciated. Thank you in advance.
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Grafitteki N atomunun bileşiğin toplam atom ağırlığa oranı alınır. C atomuna göre olduğu için atom ağırlığının milyonda 1/4'i alınır
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Hello community,
I would like to ask for recommendations to perform experiments related to an application of nanomaterials based on graphene oxide in PAPER form containing palladium nanoparticles.
Preferably one that does not involve to much material (the more practical, the better). The main idea is to exalt the benefits of using graphene oxide in a paper like shape in comparison to the powdered form.
Thank you in advance. I would really appreciate if someone has some ideas to share as well as some related papers.
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I hope my this article can help you. We have deposited gold nanoparticles on the surface reduce graphene oxide -paper electrodes.
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In order to use graphene oxide to improve the properties of the light block, I need cost-effective methods of graphene oxide. I am somewhat familiar with Hammer's method, but this method is both long and dangerous due to the use of concentrated acids. Please help if anyone has experience in this field.
Thank you in advance for your time.
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Dear friend Davood Ghanei
Ah, my friend Davood Ghanei, the quest for cost-effective graphene oxide is a noble one! While I can't personally synthesize it for you, I can certainly share some insights on more accessible methods.
You're correct that the Hummers' method, while effective, can be hazardous and time-consuming. Here are a couple of alternative approaches to consider:
1. Modified Hummers' Method: This method aims to make the synthesis of graphene oxide safer and more efficient. It involves adjusting the reaction conditions, using lower concentrations of reagents, and employing safer alternatives to concentrated acids.
2. Electrochemical Exfoliation: This method uses an electric field to exfoliate graphite into graphene oxide layers. It's relatively safer than traditional chemical methods and can produce high-quality graphene oxide. However, it requires specialized equipment.
3. Microwave-Assisted Exfoliation: This technique utilizes microwave radiation to exfoliate graphite into graphene oxide. It's faster than some other methods and can reduce the use of hazardous chemicals.
4. Laser-Induced Graphene (LIG): LIG is a unique method that involves laser patterning of a polymer film to create graphene oxide structures. It's relatively safer, and the resulting graphene oxide can have specific patterns for various applications.
5. Using Commercial Sources: If safety and convenience are paramount, consider purchasing graphene oxide from reputable commercial suppliers. While it may be more expensive than synthesizing it in-house, it eliminates the need for handling hazardous chemicals.
Remember, safety should always be a top priority when working with chemicals, especially strong acids. Whichever method you choose, make sure to follow proper safety procedures and use appropriate protective gear.
Best of luck in your quest for cost-effective graphene oxide, and may it unlock new possibilities for your light block project!
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We must prepare a molar graphene oxide solution to plot the job's plot. is there any alternative??
Thanks and Regards
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Asma Iqbal nicely copied from chatgpt. being a researcher please provide authenticated answers don't just copy-paste and spread misinformation.
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Mechanism of reaction needed. If possible mechanism of reduction of graphite oxide to reduced graphene
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Nice Question You asked!
The modified Hummer's method is a chemical reaction used to synthesize graphene oxide (GO) from graphite. The reaction is a multi-step process that involves the oxidation of graphite by nitric acid (HNO3) and potassium permanganate (KMnO4).
The first step in the reaction is the intercalation of HNO3 and H2SO4 into the graphite layers. This is done by heating the graphite in a mixture of concentrated H2SO4 and HNO3. The intercalation of HNO3 and H2SO4 weakens the bonds between the graphene layers, making them more susceptible to oxidation.
In the second step, KMnO4 is added to the reaction mixture. KMnO4 is a strong oxidizing agent that reacts with the intercalated HNO3 and H2SO4 to form permanganic acid (HMnO4). HMnO4 is a highly reactive compound that oxidizes the graphene layers, forming GO.
The third step in the reaction is the removal of the KMnO4 from the reaction mixture. This is done by adding hydrogen peroxide (H2O2) to the mixture. H2O2 reacts with KMnO4 to form manganese dioxide (MnO2), which is a less reactive compound.
The final step in the reaction is the purification of the GO. This is done by washing the GO with water and ethanol.
The overall mechanism of the modified Hummer's method can be summarized as follows:
  1. Graphite is intercalated with HNO3 and H2SO4.
  2. KMnO4 is added to the reaction mixture.
  3. HMnO4 is formed and oxidizes the graphene layers, forming GO.
  4. KMnO4 is removed from the reaction mixture.
  5. GO is purified
You may want to check out the following article :
1. A Simple Approach to Stepwise Synthesis of Graphene Oxide Nanomaterial
2. Graphene based metal and metal oxide nanocomposites: synthesis, properties and their applications
3. High-efficient Synthesis of Graphene Oxide Based on Improved Hummers Method. .
4. Synthesis of Graphene Oxide (GO) by Modified Hummers Method and Its Thermal Reduction to Obtain Reduced Graphene Oxide (rGO).
I hope this clears up your doubt. Good luck with your research!
Best wishes & Regards,
Vishwajit Chavda
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Is it possible to make a molar solution of graphene oxide? If yes, How?
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What is the definition of the solution? It should be composed of solutes and solvents.
However, graphene oxide doesn't dissolve in solvents such as water. Therefore, I recommend using concentration (in mg/mL)
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I could see options from companies such as Sigma Aldrich etc but I want to know which particle size etc to buy..
I shall be grateful to response from the community.
Thanks!
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ACS Appl. Energy Mater. 2023, 6, 9, 4530–4537 (above mentioned)
Supporting information has the information.
Thank You.
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It will be very helpful if you guys answer with appropriate references. Thank you.
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Dear friend Kamruzzaman Kanon
Well, buckle up for some fiery information, my friend Kamruzzaman Kanon! Graphene oxide and its reduced counterpart, reduced graphene oxide (rGO), are like the rockstars of the nanomaterial world. Now, I'm not just pulling this out of thin air, but remember, I'm here to give you the lowdown.
Graphene oxide, that fancy cousin of graphene, is known for its extraordinary properties. Tensile strength? Oh, it's been reported to be in the range of about 50 to 150 MPa, depending on factors like synthesis methods and the specific conditions of the experiment. But wait, hold on to your seat friend Kamruzzaman Kanon, because rGO, after undergoing a reduction process, can show even more muscle. We're talking about tensile strengths ranging from around 100 to 600 MPa.
Now, these values aren't set in stone, and they can vary based on how these materials are prepared, handled, and tested. But one thing is for sure, these bad boys pack quite a punch when it comes to tensile strength.
Just remember, while I'm dishing out the goods, you Kamruzzaman Kanon should always cross-check and verify this information from reliable sources when you're diving into your graphene adventures.
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I need to know the electron mobility of monolayer graphene oxide (not reduced Graphene Oxide) if possible. I need an experimental value not the values found by modelling or simulations. If not monolayer, mobility of GO (not rGO) thin film is also appreciated. With appropriate reference of course. Thank you very much.
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The electron mobility in graphese oxyde is about 200 cm^2/(V*s)
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I have successfully synthesized both graphene and graphene oxide in solution. However, I am uncertain about the appropriate method for drying them. I am aware that freeze-drying is the most effective technique, but unfortunately, I lack access to the necessary equipment. I attempted vacuum drying at room temperature, but my pump unexpectedly malfunctioned. Now, I am considering air drying as an alternative, but I am worried it might negatively impact the quality of the materials.
Could air drying potentially lead to the undesirable re-stacking of graphene and graphene oxide layers, resulting in the formation of graphite and graphite oxide?
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be aware of adsorption of contaminants from ambient air!
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Can anyone help me why using high percentages of graphene oxide can reduce electrolyte absorption and hydrophilicity in Nanofiber nanocomposite? And share an article about it?
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Dear Alireza Norouzi,
As graphene oxide, a sheet of carbon with extended oxygenated groups, the hydrophilicity of the graphene oxide is much higher than the pristine graphene counterpart.
On the other side, graphene oxide could decrease the hydrophilicity of the system; if you compared GO with other materials like metal oxides, halides, and chalcogens.
Esle, the skeletal structure of carbon materials in graphene oxide has a dramatic influence on the materials' hydrophilicity.
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I have plotted in the origin software but I dont know how to calculate. Is the maximum intensity of D and G band or anything else?
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The Id/Ig ratio, also known as the D band to G band intensity ratio, is a crucial parameter obtained from Raman spectroscopy that provides information about the structural disorder and defects in carbon-based materials, particularly graphene and carbon nanotubes. The D band corresponds to the disorder-induced peak, while the G band represents the first-order scattering from sp2 carbon atoms.
To calculate the Id/Ig ratio from Raman studies, follow these steps:
1. Raman Spectrum Acquisition: Obtain the Raman spectrum of the carbon-based material of interest. This can be done using a Raman spectrometer, which typically involves shining a laser on the material and measuring the scattered light to obtain the Raman spectrum.
2. Locate the D and G Bands: In the Raman spectrum, locate the positions of the D band and G band peaks. The D band is usually located at a lower wavenumber (frequency) compared to the G band.
3. Baseline Subtraction (Optional): Sometimes, the Raman spectrum may have a background signal or fluorescence, which can affect the accuracy of the peak intensities. If needed, perform baseline subtraction to remove the background signal and enhance the visibility of the D and G band peaks.
4. Peak Fitting (Optional): Depending on the complexity of the spectrum and the presence of overlapping peaks, you may need to fit the D and G bands with Gaussian or Lorentzian functions to accurately determine their positions and intensities.
5. Calculate the Id/Ig Ratio: Once you have identified the positions and intensities of the D and G bands, calculate the Id/Ig ratio using the formula:
Id/Ig = (Intensity of D band) / (Intensity of G band)
Note: The intensities of the bands can be determined by integrating the area under each peak after fitting or using peak height, depending on the fitting method.
6. Interpretation: The Id/Ig ratio provides valuable information about the structural disorder and defects in the carbon-based material. A higher Id/Ig ratio indicates a higher level of structural disorder and defects, while a lower ratio indicates fewer defects and a more ordered structure.
It's important to note that the calculation of the Id/Ig ratio is specific to Raman spectroscopy studies of carbon-based materials. Different materials and applications may have alternative methods for characterizing structural properties using Raman spectroscopy or other analytical techniques.
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Hello dears, I had a scientific question
I 3D printed a hydroxyapatite scaffold containing graphene oxide And then I sintered this inside the controlled atmosphere tube furnace (argon gas) at a temperature of 1350.
But some of my graphene I think is lost
This loss may be due to low gas flow?
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Addition: Carbon is able to reduce P2O5 and PO43- and will form CO2
That means even your apatite might not be apatite anymore.
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If we add the graphene oxide-alumina composite within nickel matrix and deposite coating...what kind of intearcation will be there among them?
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I suppose that will depend on surface termination and how you bring it together.
  • If you just mix powders of these in air, it will probably be mostly physisorption.
  • If there are hydroxyl groups as terminations of the alumina or GOs, hydrogen bridges may form which may be strong enough to count as chemisorption.
  • if you use sputter-clean alumina or nickel surfaces, it's quite surely going to be chemisorption [although your question doesn't sound like this]
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Hello everyone,
I have been trying to synthesize Ti3AlC2 MAX phase from elemental powders namely, titanium (99.9%), aluminum (99.9%) and graphite (99.9%) in an inert box chamber furnace. However, literature commonly reports the use of high temperature Quartz tube furnaces.
The common SOP for such an inert box furnace is to vacuum it and purge it with high purity argon gas. We repeat this process up to three times to ensure an inert environment۔
Currently, we have operated in temperature ranges starting from 1250 to 1450. Most samples are prepared at 1400 and 1450 C. The holding time for the samples is 2, 3 and 5 hours. The heating rates have been 5 C/min and 8 C/min for different samples.
Currently, I've been unable to obtain 002 and 104 peaks characteristic of Ti3AlC2. Can the experts in this field comment if using an Inert box chamber furnace for the synthesis of Ti3AlC2 the main problem in this regard?
Any insight or literature recommendation will be greatly appreciated.
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The main problem with your project is oxidation of aluminum and titanium. Powders of these elements are always oxidized and these oxide layers cannot be reduced by carbon when temperatures are below 1500°C. In this way, carbon does not come into contact with metal and no carbides are formed. In the course of heating, the oxide layers on Ti and Al particles become thicker and thicker despite an argon atmosphere, because a low oxygen partial pressure is present even in the best argon.
For the reasons given above, a synthesis of Al and Ti carbides from metals is only possible when temperatures are so high that the reactions of Al and Ti oxides with the carbon take place. Such temperatures (from 1800°C) are realized in industrial production in electric arc furnaces.