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I have deacetylated chitosan using 50% w/w NaOH for 6 hours. But still it doesn't dissolve completely. Should I repeat the deacetylation step?
Thank you for your guidance.
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Dear all, following is a good free access review. My Regards
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Dear Researchers,
Let’s share and discuss the best books that you have enjoyed recently in the field of Materials science and engineering.
Please let us know your opinion about this topic.
Best Regards,
Hossein Homayoun
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You have to see: Materials science and Engineering an Introduction, tenth edition by William D. Callister, Jr.
I think it´s a good book.
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It is well known that the value accounting for the average of all grain orientations in a polycrystal ("Taylor-factor") must be bounded between the Sachs (=2.24, assuming grains as indepentent of their neighbors) and the Taylor (=3.06, assuming all grains have to be able to undergo all possible deformations, i.e. 5 indepentent slip systems should be available per grain) solutions.
However, I sometimes see authors calculating shear stress-shear strain curves from macroscopic stress-strain curves using a value of sqrt(3) [1,2]. Taking the inverse 1/sqrt(3) leads to a value of around 0.57 as an "average Schmid factor", which is obviously higher than the theoretical bound of 0.5 on the Schmid factor.
Am I not getting something here or what are these authors referring to?
Thank you very much in advance!
Niklas
[1] On page 4: Li, S., Wu, X., Liu, R., and Zhang, Z., "Full-Range Fatigue Life Prediction of Metallic Materials Using Tanaka-Mura-Wu Model," SAE Int. J. Mater. Manf. 15(2):133-153, 2022
[2] Implied in figures 15, 16: Vayssette, Bastien; Saintier, Nicolas; Brugger, Charles; El May, Mohamed; Pessard, Etienne (2019): Numerical modelling of surface roughness effect on the fatigue behavior of Ti-6Al-4V obtained by additive manufacturing. In: International Journal of Fatigue 123, S. 180–195.
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Hi Fillipo,
thank you very much for your answer. Can you eloborate a little more on that or maybe give a source where I can read about it? I know the formulation 1/sqrt(6) which is about 0.408 and corresponds to the Schmid factor of octahedral glide systems in an [001]-orientated fcc crystal but have never heard about the sqrt(3)…
Best regards,
Niklas
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Hello, researchers. I hope you're all well. How can we know the type of semiconductor from the band structure (N type or P type)?
Thank you in advance.
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The differentiation can be ascertained to fermi level. When we have a pure Semi- conductor at absolute zero from theoretical point of view the fermi level is at the middle in the forbidden energy band gap. On doping if the fermi level shifts towards the valence band it's a p type conductor and if fermi level shifts towards the conduction band it is an n type semiconductor.
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The construction industry is a major contributor to global carbon emissions and environmental degradation. In recent years, there has been a growing interest in adopting sustainable practices in the built environment. Based on recent research studies, what are some of the most promising sustainable practices being implemented in the construction industry?
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The construction industry has a significant impact on the environment, but there are many sustainable practices available that can help to reduce its negative impact.
  1. Using sustainable materials
  2. Designing for energy efficiency
  3. Reducing waste
  4. Water conservation
  5. Site selection:
  6. Green roofs and walls
  7. Carbon reduction:
I believe that by adopting these practices, the industry can become more sustainable and reduce its impact on the environment.
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Like to know If I take without doing sample preparation Shall I get clearly images or not? Where I can do sample preparation in Tamil Nadu for taking TEM images with EDX?
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For non-conductive polymer nanocomposites, it is necessary to perform sample preparation before imaging with TEM to prevent charging and improve image quality. One common method is to embed the sample in a conductive resin, such as epoxy or polystyrene, which helps to dissipate the charge and improve the conductivity of the sample. The sample can then be sectioned using a microtome or focused ion beam (FIB) and placed onto a TEM grid for imaging.
If you attempt to image a non-conductive polymer nanocomposite without any sample preparation, it is likely that the images will suffer from charging, poor contrast, and low resolution.
As for where to do sample preparation and TEM imaging with EDX in Tamil Nadu, there may be several options available depending on your location and specific needs. One possibility is to contact local universities or research institutions that have TEM facilities and inquire about sample preparation and imaging services. Another option is to search for private laboratories or companies that offer TEM imaging services. It is recommended to ensure that the facility has experience working with non-conductive polymer samples and can provide high-quality imaging results.
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I intend to perform mechanical tensile test for my polymer nanocomposites. Does there exists any ASTM standard to follow? Can I also know the dimensions of the specimen to be produced? Lastly, I intend to create a mould for the dog-bone shape. Can we get files online to create the dog-bone mould using 3D printer?
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Yes, there are several ASTM standards available for performing mechanical tensile tests on polymer nanocomposites. Some of the commonly used standards are:
  1. ASTM D638 - Standard Test Method for Tensile Properties of Plastics
  2. ASTM D3039 - Standard Test Method for Tensile Properties of Polymer Matrix Composite Materials
  3. ASTM D882 - Standard Test Method for Tensile Properties of Thin Plastic Sheeting
The dimensions of the specimen depend on the specific ASTM standard chosen for the test. For example, ASTM D638 specifies the dimensions for Type I, II and III specimens. Similarly, ASTM D3039 and ASTM D882 specify the dimensions for different types of specimens.
Regarding the creation of a dog-bone mold using a 3D printer, there are several online resources available that provide files for 3D printing dog-bone molds. Some popular online resources include Thingiverse, GrabCAD, and MyMiniFactory. However, it is important to ensure that the dimensions of the mold are as per the ASTM standards to obtain accurate results.
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I am preparing chitosan film by casting chitosan solution into petri dish and let it air dry. I am using NaOH to peel off the dried film but it breaks the film. I have used different molar strengths of NaOH 0.01 to 0.1 M. But film breaks down.
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But as i know so far chitosan is insoluble in water, for your consideration.
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I want to build a thin film of BCC iron
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Possible techniques reported are thermal evaporation technique, Pulsed Laser Deposition, physical vapour deposition
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AssalamoAlaikum Hello Everyone hope you are doing well.
Yesterday I received an email from my supervisor in which he mentioned that to make a new proposal on the Topic of CO2 storage/capture as impurity by using GO (graphene oxide). I haven't worked on it. Could you suggest me some articles that are related to the topic and helpful to understand the topic. Actually I have to submit it in next 5 days so please if you have some information please guide me on this topic.
I am highly thankful to all of you for your time and suggestions (in advance)
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suggest to look for a more intelligent supervisor - this is nonsense. For CO2 storage only cheap bulk material make sense.
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I am using mixing models to calculate effective parameters (such as permittivity or permeability) of mixtures, i.e. inclusions with a given volume fraction in a host medium. There are several mixing formulas that can provide values of the effective parameter of the mixture, such as Maxwell-Garnett or Bruggeman.
Bruggeman's model treats the host medium and the inclusion similarly, and it can handle any number of different inclusions. But, there is a limitation due to the mathematical formulation.
Suppose the simple case of only one inclusion in a host medium, the equation used to find the effective parameter of the mixture is a second order polynomial. If the discriminant is negative (which sometimes happens) then the solution is complex. But this may be non physical depending on the application case (conductivity calculation, permittivity is neither the inclusion nor the host have losses, etc) where we know that a real value is requested.
For a higher number of inclusions, this may happen more often.
So, what is the solution in this case ? How to use Buggeman's model to get a real value for the effective parameter in the case the equation's solutions are complex ?
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I am grateful to the participants of this discussion concerning Brugemman’s equation. This encouraged me to prepare the paper V. Mityushev, Effective properties of two-dimensional dispersed composites. Part II. Revision of self-consistent methods, Comput. Math. Appl. 121 (2022) 74-84. The paper concerns the case of real conductivity. The result for the complex constants (permittivity) is submitted for publication.
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This is a discussion that I wish to go on and remain helpful for all the Drone researchers, manufacturers, designers, operators and users and sort of a buyers guide.
"What are the right materials for a Fixed Wing Drone?"
This question pertains to any type of material that one finds good to be used for various different kinds of practical applications. This is understandable that will applications, materials used will be different. Also, Long Range/Short Range and High Altitude/Low Altitude applications are a considerable parameters.
Few materials and applications are mentioned here. However, we are not limited to that.
MATERIALS
  • Expanded Polyolefin Foam (EPO)
  • Expanded Polypropylene Foam (EPP)
  • Expanded and Extruded Polystyrene (EPS/XPS)
  • Balsa Wood (Balsa + Plywood)
  • Glass Fiber Composite
  • Carbon Fiber Composite
  • Carbon Fiber + Glass Fiber + Kevlar
APPLICATIONS
Civil/Forest
  • Mapping
  • Inspection
  • Surveillance
  • Payload Delivery
Military
  • Surveillance
  • Payload Delivery
  • Warfare
Your input in the right material for the right application will be well appreciated.
Thank You for your contribution.
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Carbon fiber is typically used, and carbon UD is used in some major primary structures. The solar drone applied in this paper used carbon fiber and UD together. In addition, certified materials (B-Basis, DB) must be used when using these drones for commercial purposes, such as sales, rather than for experimental purposes.
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Dear Researchers,
I am searching for the material properties of EPO (Expanded Polyolefin) Foam to use it in the manufacturing of Fixed Wing Unmanned Aerial Aircrafts.
Requesting for your help with links and documents.
Thank You
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Currently, the acceptance rate of MDPI Materials is about 65%. Normally, this rate is 20-30% for other journals. Is MDPI Materials publishing so many papers for money and compromising on the quality of work?
Thank you
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In my opinion, based on the quality of articles I have accessed in my area, I can say MDPI materials are of good quality.
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I have jaw milled an aluminosilicate glass and omitted ferrite impurities via HCl. After ball milling with either metal cup and balls or stabilized zirconia balls with ABS cup, there are lots of impurities that I can not omit completely. I have tried both ball milling and wet milling and neither of them worked. Is there any other way to mill the glass powder to under 1 micrometer without this much of impurities?
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Hi all,
I am in need of the physical and thermal properties of food grade silicon / BPA free silicone.
I am doing a comparative study on the design of mats used in the microwave ovens and other general thermal applications. This involves the iterations in the design and the materials grades.
I have selected few designs from the available sources. The design involves the pattern of the ribs that helps in heat dissipation.
I am struggling to get the material properties for the food grade silicone or BPA free silicone. The properties helps us to conduct the thermal analysis for the mat.
It will be highly helpful if you can help me in getting the properties of the food grade silicone or BPA free silicone.
Below links are for the design references for the product for which I am supposed to make the comparative thermal analysis..
Edits made :
Silicon is replaced with Silicone.
Tag word Silicon is removed.
Thanks,
Prabhu
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Thank you for the useful background. So it wasn't silicon, or silica but rather silicone... A little work on Google and RG will help you. In 2 minutes I have found the general descriptions: https://lifewithoutplastic.com/silicone/
and something on thermal properties (from poorly conductive to conductive). See attached. Fermi estimates can easily be found by Googling the appropriate property (e.g. 'conductivity') followed by the word 'silicone'. Good luck with your research.
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We have been synthesizing copper nanoparticles via chemical reduction method and using different capping agents to increase the stability of the copper nanoparticles as with the passage of time the color and oxidation state of copper nanoparticles vary.
We have so far tried immobilizing copper nanoparticles onto sepiolite, used capping agents like glycerol, tween80, CTAB and PVP. And different reducing agents including NaOH, glucose, ammonia, hydrazine and NaBH4 as well as ascorbic acid.
The synthesized nanoparticles attain brick red color and then turn black. We want to maintain the brick red color.
I will be grateful for your kind responses and guidance.
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Dear Noor Ul Ain thank you for posting this very interesting technical question on RG. Red nanoparticles of pure copper metal (Cu(0)) are highyl sensitive to oxygen and, as already indicated by Yuri Mirgorod, the corresponding copper oxide nanoparticles are thermodynamically more stable. However, I just came across an inmteresting articles in which a chemical reduction protocol using copper(II) sulfate pentahydrate as precursor salt and starch as capping agent is described in detail. This might be the solution of your problem as no inert gas is required in this proces. Please have a look at this paper:
A chemical reduction approach to the synthesis of copper nanoparticles
The article can bee freely downloaded as pdf file from the internet (see attachment).
I hope this answers your question. Good luck with your work and best wishes, Frank Edelmann
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Following the procedure below I obtain a solid polymer which after FTIR analyses I identified as a HDI trimer and not a polyurethane prepolymer formed by the union of PEG and HDI.
For the preparation of the pre-polymer, PEG400 diol, together with DBTDL (catalyst), were fed into a three-neck round-bottom flask reactor. Nitrogen flow was maintained for 20 min to provide an inert atmosphere. The mixture was stirred for 30 min at 60 °C. Then, HDI was added dropwise to the mixture and the reaction proceeded for another 1 h at 60 °C under N2 atmosphere, yielding an isocyanate-ended, viscous pre-polymer. The molar ratio of diol:HDI was kept constant at 2:3.
I tried drying the PEG under vaccum + molecular sieves, changing the NCO:OH proportion, the order of addition... How could I avoid this trimerization of the HDI and obtain the objective PEG-based polyurethane viscous prepolymer?.
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Dear Pedro Jesús Navarrete Segado, I think there is an important ecxess of NCO initial concentration, try reducing it or increase OH-PEG-OH initial concentration. Also make a re-check of the calculation step. My Regards
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Hello,
One of my colleagues is working with piezoelectric components and couldn't find the shock response spectrum for various piezoelectric components. Can anyone please share your idea to deal with the calculation process of shock response spectrum (srs) of piezoelectric components? However, any informative links that contain useful resources or details will be very helpful.
Thank you for your time and guidance.
Best wishes,
Faishal Rahaman
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I have a RG write-up for the impulse excitation of a piezoelectric shock sensor (PSS), which you may find of interest for your current problem, see, . I just uploaded this Method today, 3/2/2022. I hope this helps.
Regards,
Thomas Cuff
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Any provided material would be helpful.
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In my opinion you should report R square first, followed by whether your model is a significant predictor of the outcome variable using the results of ANOVA for Regression and then beta values for the predictors and significance of their contribution to the model.
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If I were to make a half dome as an umbrella to protect a city from rain and sun how would I proceed. Are there special materials or do you have an idea on how to make this? What do you say about an energy shield ?
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Dear all, I think the easiest way is an underground city. Shullters are built for similar protection purposes. My Regards
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I have prepared magnesium green compacts from powders of different particle sizes. I observed that the green strength of compacts produced from fine powder was very low. Green compact splitted in two parts in the vertical plane during removal of green compact from the powder compaction dies. I repeated the experiment so many times and observed the same behavior. What can be the possible reason? Please explain.
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Green compacts of any powder compacts have low strength because no bonding is there between particles. The green compacts possess whatever strength is because of compaction force. The compaction force removes the empty spaces and facilitates mechanical interlocking of particles. Only after sintering strength is developed. So, change the design of the die for easy removal of green compacts.
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Hello all,
I´m currently working for a medical device company. We are trying to understand the buckling effect during an insertion force test.
We use a flexible PVC extrusion with these properties:
Hardness: 95 (ASTM D-2240)
Specific gravity: 1.73 (ASTM D-792)
Tensile strength psi: 3400 (ASTM D-638)
Elongation%: 250 (ASTM D-638)
100% Modulus psi: 2860 (ASTM D-638)
This extrusion is inserted into another medical device and the force required to insert the extrusion must be below 4 lbf. However, it is noted that during insertion procedure the extrusion buckles, losing force and failing test. The extrusion is inserted using a fixture to guarantee that 4lbf are being applied, there are some cases where the readings of the force tester are below 4lbf but the extrusion get stuck and didn't pass all the way thru the medical device not reaching the desired end position. Our guess is that the column force is lost as result of buckling.
Extrusion length is about 10 inches, OD is about .077” and ID is .035”, this isn’t a solid extrusion. For this case, we would like to know much force (lbf) can be applied to the extrusion before buckling. Seems like we might use Euler formula, but it is unclear to me how to use the formula adding the factor that this isn’t a solid column, I assume wall thickness may be considered.
I appreciate any help to solve this doubt.
Thanks!
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A quick check with pens and papers-
Use Euler's Buckling formula
max load P= EI*(pi)^2/L^2. L is the insertion point (into hole, box, whatever) to holding point (where the pipe is gripped and applied force. E is young's modulus. I is area moment of inertia, I=(pi/64)* (D^4-d^4). D is outer and d is inner dia of tube
This bold portion would work just fine to use the area moment of inertia of a hollow column.
For eccentric loading, use the Secant formula instead
But wait! if PVC tube is way too flexible to be considered to be elastomeric rather than linear elastic, there can be error, because Euler's formula was derived for linear elastic deformation of columns.
If standard simulations (Solidworks, Comsol, Ansys) seem too hard for you, go to some user friendly online simulation interfaces like simscale. Just upload 3D image of files in their simulation IDE, give input parameters, and you are done within a few minutes to hours.
Go for it.
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Hi,
A part of my research project is to obtain the strain distribution of a certain geometry that has one flexure. I define flexures as localized thinness that occurs in a constant thickness geometry (CAD picture attached). For my case, I am looking at a flat beam and a hollow cylinder with one flexure that is 5 cm wide and 1 mm thick, and there is a smooth transition from 2mm thick to 1 mm thickness. I am using ANSYS mechanical (static structural simulation) to get the strain distribution. I have also attached the plots that I got for both of the cases. My question is, for a flat beam, there is a clear rise to a higher strain value where flexure is placed, however for the cylinder case, there is a dip first, and then strain rises and then flattens out and then rises again, creating this "Batman ear" looking shape. I do not know why it happens. So I was wondering if anyone here has any idea or possible explanation. The geometry is set up the same: one end is fixed, and a point load is applied to the free end. The material for both of the case is ABS plastic. Thanks, in advance.
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Follow
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As the title says, I am trying to learn more about fracture analysis and how cracks propagate through brittle materials. Does anyone have any good recommendations on books or other learning material?
Thanks in advance.
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I have several confusions about the Hall and quantum Hall effect:
1. does Hall/QHE depend on the length and width of the sample?
2. Why integer quantum Hall effect is called one electron phenomenon? there are many electrons occupying in single landau level then why a single electron?
3. Can SDH oscillation be seen in 3D materials?
4. suppose if there is one edge channel and the corresponding resistance is h/e^2 then why different values such as h/3e^2, h/4e^2, h/5e^2 are measured across contacts? how contact leads change the exact quantization value and how it can be calculated depending on a number of leads?
5. how can we differentiate that observed edge conductance does not have any bulk contribution?
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You distinguish a normal classical Hall efect from a Quantum Hall effect.
Normal size devices exhibit the first, contain considerable number of electrons.
The magetic field acting on the current pushes electrons to one side of the device
and is counteracted by the Hall voltage set up from charge accumulation. Proportionality between magnetic field and Hall voltage for steady current.
Quantum devices contain fewer electrons in narrow or small devices (Nanostructures) . The magnetic field provokes the equivalent of Landau levels that contain the states for electrons. These pass at regular intervals as the magnetic field increases. Thus there are regular jumps
in the electron conductance as magnetic induction increases.(In single electron conductance, or normal quantum hall effect
The fractional quantum Hall effect is believed to be the consequence of electron interactions and quasi particle formation. This is an extremly complicated phenomena, and not nearly as well understood as many would have you believe.
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hello! RP0! I working with materials of tire . now , I meet a question.HOW TO IMPROVE DRY GRIP OF TYRE , JUST CHANGE THE MATERIALS OF TREAD COMPOUND?
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Dear Chen,
in the past I worked a lot with amine modified SBR rubber (cheically modified) in a close cooperation with a german tyre maker. Taget was to reduce rolling resistance and wet grip. It worked pretty well. Maybe this concept also works to improve dry grip.
Regards,
Roman
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With the increasing demand, the consumption of metallic materials is increasing. But the primary sources of these materials (ores) are limited. So, there is an urgent need for an efficient recycling technique to meet the increasing demand. There are mainly two techniques, powder metallurgy and casting, used for recycling metallic materials. Which is the better technique, powder metallurgy or casting?
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Just came across this question. Slightly unrelated but aligned to re-cycling in the foundry environment.
Please see my paper on recycling waste foundry sand:
The paper also looks at alternative methods of recycling waste foundry sand.
Hope this might be of some use to your overall topic.
Best Regards
Martin
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Hi everyone, does someone know the work principles that VASP(The Vienna Ab initio simulation package) calculate elastic constant? I have checked many literature and they applied a matrix to unit cell, but I don't know if they are used by current version VASP(5.3.3). When I check OUTCAR, I can only find the elastic constants, but I cannot find where is the process, i.e, the matrix applied and the energy of strained lattice. Can someone tell me how to find those data, or introduce some literature about this?
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Hi Rajeev,
The purpose of smearing is to ease the complication in integration (technically summation) by broadening the energy levels around the Fermi level by creating a small and fictitious electronic temperature. For metals, at absolute zero, while energy levels below Fermi-level are completely filled, the energy levels above it are completely empty. Hence there is an abrupt change in occupancy at the Fermi level. However, this is not the case in semiconductors and insulators. Therefore broadening for metals is different from that of semiconductors and insulators. In VASP, the tag "ISMEAR" provides options to choose from different available smearing schemes to broadening the energy levels around the Fermi level. If you are trying to calculate elastic constants for metals, I would recommend you to use ISMEAR=1, for semiconductors and insulators use ISMEAR=-5. If you are writing scripts to run calculations for large number of systems, then as suggested in the vasp wiki consider using ISMEAR=0.
I Hope this is useful
Best,
Santosh
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I am applying top gate voltage using Al2O3 (100nm) dielectric. I would like to calculate effective elecrtic field applied using this top gate. I can apply top gate voltage of 1V (say). how much effective electric field can be obtained by 1V top gate.
Please help me
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The electric filed in the dielectric is E= V/d = 1 V /(10^-7) m = 10^7 V/m
Because you apply the voltage with a metalic electrode on top of the gate the electric field in the dielectric is less than 10^7 V/m with the Schottky barrier
1V- (50 -100 mV) for Al2O3
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Hello, everyone,
I'm a little confused about valence band structure of Aluminum nitride (AlN). It is known that the crystal-field split energy in AlN is negative, so there are a lot of papers saying that the crystal-field split-off hole band is the topmost.
On the other hand, according to the k.p method (for example, or ) valence band energies at k=0 can be expressed as shown in the picture below (where Δ1 is the crystal-field splitting).
For Δ1>0 (like in GaN or InN), E1>E2>E3 and the bands are usually reffered as HH, LH and CH, respectively, so the topmost band is the heavy-hole band.
For any values of Δ1 and Δ2, E2 is always larger than E3, so in the case of AlN E2>E1>E3 which should mean that the topmost valence band is the light-hole band. Am I missing something obvious?
Another quick question is about an appropriate interpolation scheme for hole effective masses of ternary alloys. Should we use linearly interpolated Luttinger-like parameters A1...A4 for a certain composition to calculate the effective masses (including strain effect if needed) or should we calculate effective masses for the binaries from their parameters A1...A4 first and then interpolate between the obtained effective masses?
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The valence band ordering for the AlGaN alloys is discussed in
M. Feneberg et.al.
"Anisotropic optical properties of semipolar AlGaN layers grown on m-plane sapphire", May 2015
  • Applied Physics Letters 106(18):182102 (year 2015)
  • DOI:10.1063/1.4920985 (or full text in research gate)
The properties of AlN are discussed here:
M. Feneberg et.al.
"Anisotropic absorption and emission of bulk ( 1 1 ¯ 00 ) AlN"
  • Physical Review B 87(23), 235209 (2013)
  • DOI: 10.1103/PhysRevB.87.235209 (or full text in research gate)
Ruediger
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Hi I want to know more about how are new cities implementing biophilic design to their buildings and how much this is growing. Also how important is the LEED certificate becoming for this implementation.
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Hi dear Santiago.
Real architecture is called architecture in which human thoughts and feelings are taken into account and this architecture creates a perfect fit that pays attention to structure and function at the same time. We know that our relationship with nature promotes health and well-being, and this relationship can also improve physical function. People who live in a building do not just need to work, play, eat or sleep. They want to be inspired and inspired by their surroundings, to feel comfortable and strong in it. They need a space that makes them more comfortable. The solution to architectural sustainability is to work in harmony with nature. That is, one must understand nature, explore it with sensitivity, and at the same time avoid damaging nature's systems. The architect-planner should pay attention to the concept of biophilia, which causes the continuity of performance and health and emotional states of residents and individuals and leads to positive reactions in the environment, and the general process in the architectural predominance to such things as:
1- Making natural and physical frameworks friendlier
2- Optimal organization of energy consumption
3- Ensuring the effective relationship between human progress and optimal management of natural resources in reducing the negative effects of climate change.
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Conduction electron density will be different in anatase and rutile structure of TiO2.
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Hi Sir, may i know what is m in the relation?
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Upon equilibrating an Ice Ih structure at 250K and using write_data command for obtaining the end structure post-equilibration, I found that it does not contain the required bond information that was present in the initial geometry file.
Also, if the previous bond info from the initial geometry file is copied over to this new post-equilibrated data file, the bonds look incorrect on visualization and LAMMPS gives an error stating "Inconsistent image flags" and "bond/angle/dihedral extent > half of periodic box length"
Does anyone know how to write or extract the bond info post-equilibration successfully in LAMMPS? Attached are the initial (1hx20.lmp) and equilibrated (data.equibicev2) files pertaining to the problem.
Any insight is appreciated.
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The LAMMPS trajectory does not contain the bond topology information. The psf file should be made on your initial configuration. If you are not using create and delete bond then pre and post equlibrated structure will sure find the correct topology from the psf file.
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By definition, I know Lateral Strain divided by Longitudinal Strain but how to determine this by using Universal Testing Machine or any other method?
what is the procedure to find Poisson's Ratio?
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Only with two extensometers mounted on the test piece (one longitudinal, the other transversal) one can measure the Posson's ratio. Only the people equipped to make true stress / true strain tests can do it (and they are not many). I strongly suggest to use cylindrical test pieces and to repeat the test many times, to have a sensible measurement. remember that all materials are anysotropic and this is valid also for Pisson's ratio.
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My experiment demand x-ray CMT imaging. I need to place my samples over a substrate that should be x-transparent. Can anyone please any suitable materials (rather than foam) that is x-ray transparent?
Thank you in anticipation.
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Dear Pradip Singha , any stiff material consisting of low atomic number elements are suitable.
Examples are PMMA or polycarbonate.
Patient tables for Xray CT are built as sandwich of carbon fibers tissues (plate) -foam-carbon fiber tissue.
For small weight sample a thin carbon fiber plate is sufficient.
You may have seen them already.
In the attached linke there are some picture of such plates:
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What is the mechanism and method of making the steel fibers used in reinforcing concrete and what are the residues or wastes or losses caused from the manufacturing stage ?
Are there detailed industry instructions that can be obtained ?
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Dear Ahmed Mousa,
Steel fibers are short discontinues strips of specially manufactured steel. Generally, their inclusion in the concrete improves the mechanical properties of concrete significantly. As the most common matrix, which is now mostly use in construction industry is Reinforced Cement Concrete. Main Reinforcement purpose is to resist bending due to applied load.
Ashish
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Absorption vs Wavelength Plot w.r.to Temperature.
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For this purpose, after simulation, go to the Post-processing template, then
in General result choose '' Optical '' in the first tab and for the second tab choose
'' Calculate Reflectance Transmittance and Absorbance '' then specify Ports and Modes have been used in your simulation and finally click on evaluate.
Done,
Good luck,
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Dear colleagues,
I am a researcher working with bovine hydroxyapatite. I want to reduce the percentage of carbonate on the sample. Is there any suggested techniques for this? I am measured the carbonate from EDX (SEM-EDX). Thank you
Thank you.
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Dear Maria Apriliani Gani,
These may be addition of impurities, high temperature and environmental conditions can reduce the formation of carbonates.
Bone mineral is not pure hydroxyapatite. The small, plate-shaped (20–50 nm long, 15 nm wide, and 2–5 nm thick) apatite crystals contain impurities, most notably carbonate in place of the phosphate groups. The concentration of carbonate (4–6%) makes bone mineral similar to a carbonate apatite known as dahllite. Other substitutions are potassium, magnesium, strontium, and sodium in place of the calcium ions, and chloride and fluoride in place of the hydroxyl groups.These impurities can reduce the crystallinity of the apatite , and, in doing so, may alter certain properties such as solubility. The solubility of bone mineral is critical for mineral homeostasis and bone adaptation.
Carbonate substitution in apatite each control the crystal’s perfection and crystallite domain size, affecting material properties, in different environmental conditions. High temperature substitution methods indicating a higher energy barrier for the formation of carbonate.
Ashish
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Recently I tested a novel superhydrophobic coating by means of potential curves. What is odd is that I found a significative change in Ecorr (from 800 to 500 mv in comparison with the bare metal...) but instead of a lowering of Icorr I found an increase in ICorr (10-8 bare metal to 10-7 protected). The coating is conductive (it's C based). I have no idea how to interpret the results. Any ideas?
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@Sarah in my case it was related to the nature of the coating which was conductive. I can share with you the article we published if needed
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Please suggest what are different types of polymorphic transformations and best available literature decoding the same. For example, I am not clear if:
1. Different polytypes of SiC are due to reconstructive/ displacive or any other transformation?
2. Is existence of C as diamond or graphite due to order-disorder transformation?
3. Is the energetic material like CL-20 having 4-5 polymorphs due to displacive transformation?
Please discuss with examples
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Dear,
In mineralogy, only topologically different structures of the same composition are usually considered to be polymorphs. Crystal structures formed of segments that can be stacked with different orientations are called polytypes. There is a symbolism of polytypes, based on the number of repeating segments and symmetry. Other options today do not differ in nomenclature rather (ordering-disordering -OD structures, polytypoids, etc.).
SiC is considered strongly polytypic, where Identical layers are shifted or rotated. Stacking in an identical position is not possible. It is good to draw the structure of one of the SiC polytypes in some program (Vesta, XTALDRAW etc.)
Graphite and diamond are completely different structures with different bonding characteristics. So the transition from graphite to diamond is completely reconstructive. However, graphite itself is polytypic (graphite-2H, -3R and disordered graphite) and probably also polymorphic (chaoite is high-pressure graphite). Diamond is polymorphic (diamond, lonsdaleyite).
I don't know anything about the CL-20 explosive.
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Hello everyone. Given microstructure image belongs to a 12% ledeburitic cold work tool steel (annealed and tempered). The sample was etched with picral (100 mL ethanol and 4 g picric acid). I tried to reveal retained austenite structure. Because I've limited knowledge in steel metallurgy/characterization, I need some help here. I know the white phases are carbides, which precipitate through thermomechanical forming. Any retained austenite can be observed? What would be black phases between grain boundries? Any answers will be appreciated about clarifying this microstructure.
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May be you can observe this article:
You can also make nanoindentation test. This test is performed to determine hardness of the phases. You can also determine the microstructure with EBDS. But you must prepare your sample very well. Especially polishing must be wonderful.
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I have created an Ice 1h crystalline structure and an Aluminium substrate structure and equilibrated both at 250K. Now I need to bring them together in a way that an adhesive bond is created. Reading the literature I have found that this can be achieved by an energy minimization process to bring the structure in contact and thereby inducing artificial stress at the interface that can then be relaxed and a nucleation process can be started; but I don't grasp how this is done in LAMMPS.
Any insight is appreciated.
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Ty so much for the detailed information, Misha.
I will try these steps.
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I am looking for a scientific explanation for the anomalous values of Avrami exponents. Regrading the literature, the typical values of Avrami exponent have to be between 1 and 4. Different Avrami values demonstrate the different mechanisms of crystallization (Phase Transformation), including nucleation rate, growth rate, and dimensionality of the growth. Meanwhile, we obtained some anomalous values of Avrami exponents around 5, we appreciate any contribution in finding meaningful explanations.
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Dear Dr. Sajad Sohrabi ,
I appreciate your explanations very much and congratulate you on your nice published paper. In addition to your accurate interpretations, we have provided some additional information in the following paper:
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In the case of Ti-alloys, it is confirmed that α stabilizer increases the c/a ratio. What is the mechanism of correlation of the c/a ratio with the unit cell? It is true if increases c/a ratio in HCP structure will linearly decrease unit-cell? or vice versa? What is the mechanism to connect these phenomena?
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Dear Dr.
Ahmad Zafari
Thanks sir.
So, with increasing slightly c/a ratio , is that any correlation mechanism with changing unit cell volume, i.e slightly decrease, increase?
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Generally we add spin-orbit interaction as a perturbation term in the system. which system has this spin-orbit term naturally in its hamiltonian.
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There are 2 classes of truly physical effects, which are originated from SO interaction:
Dr. Vadym Zayets classifies them according to the following scheme *:
Enhancement of external magnetic field, localized electrons and atomic gas experience this class of effects. In this type, time-reversed symmetry is broken by the external H.
  • perpendicular magnetic anisotropy.
  • magnetostriction.
  • g-factor.
  • fine structure.
Creation of spin polarization by an electrical current, conduction electrons experience this class of effects, time-reversed symmetry is broken by the electrical current J.
  • spin Hall effect.
  • inverse Spin Hall effect.
  • spin relaxation.
References
Dr. Vadym Zayets, “Spin-Orbit Interaction” https://staff.aist.go.jp/v.zayets/spin3_32_SpinOrbit.html
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In an alloy containing two different elements different in diffusion coefficient.
At high temperature, they diffuse or oscillate at different rates. Due to different oscillation rates, solute atoms possess compression force on neighboring solvent atoms.
May anyone give me a brief about this force?
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up
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I am trying to select suitable element type (Solid or Shell) for impact analysis. I have tried with both solid and shell elements. The results are same for both element types up to certain impact velocity, later there is a considerable difference in the results obtained using solid element and shell element. So I want to validate with the analytical model and select the element type which is close to the results obtained using analytical models.
Any other suggestions to select suitable element?
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I suggest you to have a look at the following papers:
- Numerical investigation on ballistic resistance of aluminium multi-layered panels impacted by improvised projectiles
Szymczyk, M., Sumelka, W. & Łodygowski, T.
Arch. Appl. Mech., 88, 51–63 (2018)
-Experimental and numerical investigation on the anti-penetration performance of metallic sandwich plates for marine applications
Na Zhao1, Renchuan Ye, Ali Tian, Jie Cui, Peng Ren, Minghui Wang
Journal of Sandwich Structures & Materials, Vol. 22 issue: 2, page(s): 494-522 (2019)
- Advances in Projectile Penetration Mechanism in Soil Media
Mohd Ahmed, Saeed AlQadhi, Javed Mallick, Mohammed Noor Desmukh and Hoang Thi Hang
Appl. Sci.,10, 6810 (2020)
-Rigid Projectile Impact on Concrete Target
Wu H., Peng Y., Kong X.
In book: Notes on Projectile Impact Analyses. Springer, Singapore. https://doi.org/10.1007/978-981-13-3253-1_1 -pp 1-56.
My best regards, Pierluigi Traverso.
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Hi everyone,
I wanna know about creating the Graphene model in CST.
In: Macros -> Materials -> Create Graphene Material for Optical Applications.
What is the exact formula that is used in this option?
Is it the Kubo formula? I compared this with the Kubo formula according to the attached files but they are not the same!
Maybe this attached formula is an approximation. So what is the exact one for the Kubo formula used in CST?
I would be grateful if you can help me with this regard.
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You can find out on YouTube
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Is it possible to compare the Theoretical maximum adsorption capacity (qm of Langmuir) of my sample to other materials when the (R2 of Langmuir is about 0.82) and the (R2 of Freundlich model about 0.98)
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How to apply Langmuir adsorption isotherm. A complete guidance ..
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I have to dilute it, is butyl acetate suitable?
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The commercial thinner is the blend of acetone (30 % by volume), ethyl acetate (25 %), butyl acetate(25%) and toluene (20%). The blend is used for thinning the auto stock paste and lequires and varnishes.
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An interstitial atom (such as H, N, O) sitting not on their regular place, but between other atoms in the metals structure.
How to detect where is their location on that structure (in crystallographic viewpoints) with instrument analysis rather than assumed.
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For BCC matrix and interstitials mechanical loss spectra can be measured to quantify amount of interstices. More info you can find in the paper:
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You need to measure the permittivity and permeability of your material and then calculate n.
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thanks a lot
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We can make materials with different refractive indexes by include to dielectric some metallic particles with different concentrations. It will be similar to metamaterials but on the ground of natural substances
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Any close value will also work.
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Dear Abhishek Mukherjee,
The optical absorption coefficient can be obtained by using the equation [2] which can be used in a non-conducting dispersive medium. Here w is photon frequency, μo is the permeability of free space, ε1 and ε2 are frequency-dependent real and imaginary parts of dielectric permittivity from the VASP output of the first-principle calculation.
Refer this article for permeability data
2. D. J. Griffiths . Introduction to Electrodynamics. 4th Edition, Pearson Education (2013).
Ashish
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I need references articles that explain the drawings for the following materials, which illustrate the diagram between DR UV-Vis spectrums of the following materials blank sample as expressed in Kubleka-Munk function versus
the measured wavelength and the materials are ZnO, CuO, Fe2O3, and Co3O4.
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I request the professionals in this to please help me in my project which i am doing in my final year. I'd be very grateful even if its just a bunch of research papers or websites that your sharing.
thank you.
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To obtain reliable and valuable answers, you have to specify, what kind of industrial sludge are you talking about. Oil sludge, sludge containing heavy metals, press mud, sugar beet mud, sludge from tannery industries? Some else?
Regards
Vit
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What according to you should be researched/accessed with respect to WC based solid lubricant tools? What is your view with respect to future research in this area? (For e.g. Tribological study etc..)
Thanks in advance..
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Thanks Soumitra Paul sir for your extensive in depth answer. I will surely go through the articles.
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A kind of surface roughness is produced by the application of laser energy density at high laser power (> 140W) which looks like an open porous structure. This kind of structure is not observed at lower laser power.
Is it produced due to oxidation of the layer? Or could it be a sign of instability at high laser power?
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  1. During intensive, powerful remelting of the surface, the melt exists longer than usual. This longer time is sufficient for crystal growth when cooling, and needle-shaped crystals grow, which are clearly visible in the picture.
  2. Pores in the surface are not open pores, but closed voids that arise when the melt crystallizes: the crystalline phase has a smaller volume than the melt and than the amorphous phase, which is formed in the case of high speed low power remelts.
  3. With powerful, rapid remelting, temperatures are so high that copper oxide can split off the oxygen and form metallic copper: 2Cu2O = 4Cu + O2. So, it may be that the needle-shaped crystals are made of metallic copper.
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The main (and generalistic) advantages and disadvantages of each type of nanosystem have been widely pointed out in literature. However, the advantages and disadvantages stated are too broad and sometimes overlap. Of course, it can depend on several factors: the targeted tissues; the loaded compounds; the type of administration; the final formulation; industrial scalability; among others. This way, this question aims at opening a debate to untangle and explore further the potentialities of each nanosystem and, more specifically, the (1) differential and (2) more specific applicabilities of each one towards the right final choice for the preconized biomedical application. Personal experiences and opinions are deeply welcomed!
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Choose polymer based systems as they are more stable than lipid based.
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I want to convert the Young's modulus and Poisson ratio of an orthotropic material given in Cartesian coordinates into cylindrical coordinates. Please suggest me the way or provide me the link or document where I can get these things. Thanks in advance
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Also note that under the same loading the deformation of material with rectilinear orthotropy differs from the deformation of materials with cylindrical orthotropy.
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At the moment, only the lazy one doesn't investigate high-entropy materials. But what is that?
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It is always good to return to the original definition and meaning of the terms.
Entropy is often correlated with the disorder but not always. Entropy is the measure of unknown information. How do we understand this? The trick is to understand what is macrostate and what microstate.
* Macrostate is observable value.
* Microstate usually not.
Unknown are microstates as we can not measure them.
Just an example with a dice, where we can observe microstates. Macrostate is the sum of all values of all thrown dice. The trick is that there are existing many microstates giving one macrostate. Not every macrostate has the same number of microstates.
Macro states with the highest number of associated microstates have logically the highest probability to be observed in the system as far as all microstates have the same probability It leads to the original Boltzmann definition of entropy.
When there are microstates with different probabilities, we just group them together and we get the well-known definition of Boltzmann entropy and similar Shannon entropy
H = - sum(p_i * ln(p_i))
They are the same except for the Boltzmann constant.
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I need to draw a comparison between the two for my study of their frictional factors. Motivation is towards its industrial applications mainly pertaining to fluid dynamics. Any leads would be really appreciated.
Thank you!
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Dear Jaydev,
Alloy 6082 is known as a structural alloy. 6082 is in the 6XXX series of aluminium alloy grades and have a higher amount of silicon. Aluminium alloy 6082 is a medium strength alloy with excellent corrosion resistance. It has the highest strength of the 6000 series alloys. In the T6 peak aged temper, alloy 6082 machines well and produces tight coils of swarf when chip breakers are used. Applications 6082 is typically used in highly stressed applications, Trusses, Bridges, Cranes, Transport applications, Ore skips Beer barrels and Milk churns. Alloy 6082 T6 is typically supplied as Plate and Sheet. 6082 has very good weldability and machinability, but strength is lowered in the weld zone. When welded to itself, alloy 4043 wire is recommended. If welding 6082 to 7005, then the wire used should be alloy 5356.Friction stir weld (FSW) of 6082 is quite popular. Maximum 1 % Mn content is there with 6082 with high hardness value 90HB.
Generally, plate is available in heat treated condition T6(T6 - Solution heat treated and artificially aged or peak aged maximum strength but losses in corrosion property compared to over aged condition of aluminum alloy) and T651(further, solution heat treated, stress relieved by stretching then artificially aged to attain corrosion).
M247, known super alloys or high performance alloys consist of many elements in a variety of combinations to achieve a desired result. The alloy MAR-M 247 is a cast polycrystalline nickel-base superalloy developed by Martin Marietta Corporation processed by hot isostatic pressing (HIP) was subjected to symmetrical cyclic loading. This can exist at the high temperature and high cycle fatigue.
Refer this site for M247
Refer this site for 6082.
file:///C:/Users/3020/Cookies/Desktop/Downloads/Aalco-Metals-Ltd_Aluminium-2. Alloy-6082-T6T651-Plate_148.pdf(strength and property detail can se taken as a reference)
Ashish
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I want to know about the type of polymers in PCBs.
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Dear Rohit Jha, the essential criterium in selecting the best polymer matrix for board circuits is ' the dimentional stability ' under different stresses, i.e., stresses such thermal, mechanical, and chemical. This criterium is in favor of an unchallenged choice of thermosetting resins. This is in fact the classical approach being followed till nowadays. In addition to that, more recent advances are requiring mainly the flexibility which is lacking in classical thermosets. Nanohybrid composites which fullfill all the classical features of thermosets, they also show other requirements dictated by the newly emerged technological applications. My Regards
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Im trying to model the failure of polycarbonate using the Johnson-cook model for ductile metals in Abaqus, I have found literature in which the parameters for the constitutive equation were given, but I havent found any resource with values for the fracture model, does anyone have any knowledge or could point me in the right direction?
Cheers!
Alex
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Dear Alexander,
Refer this paper for your query.
The strain rate sensitivity of the yield stress fell into two behaviors, either a progressive increase in terms of strain rate or an increase with a transition in the intermediate strain rate range. It can relate materials constant idea using model.
Ashish
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I am searching for various materials related to energy absorbing applications. These material should sustain high shock load like a near field blast scenario. As far I know, there are some materials like, FRPs, Metal Foams, concrete structure, Honeycomb structures of metals and nonmetals, which can absorb the sudden shock loads.
Kindly suggest some advanced energy absorbing materials which could sustain very high shock load and suppress the shock waves.
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3D printing in many settings is indicated to be a 'hobby'. However, if one envisions how 3D printing can contribute to re-shaping our day to day lives, one possibility is to make use of materials for common uses or that contribute to circular use cycles. Organic materials are available in many forms around our collective living environments. Therefore, understanding what materials are available and common products that are used could help to identify paths of research that could utilize 3D printing on larger scales and more common settings.
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The list of additive manufacturing raw materials is immense and including them in keys words didn't make sense. Here are some common plastics in a list to contribute to discussion:
  • ABS
  • ABSi
  • ABS-ESD7
  • ABS-M30
  • ABS-M30i
  • Accura 48HTR
  • Accura 60
  • Accura ABS
  • Accura Bluestone
  • Accura ClearVue
  • Accura Xtreme
  • ASA
  • Cynate Ester (CE 221)
  • Epoxy (EPX 82)
  • Nylon 12 (Unfilled)
  • Nylon 12 (Glass-Filled)
  • PC-ISO
  • Polycarbonate
  • PPSF
  • Rigid Photopolymer
  • Rigid Polyurethane (RPU 70)
  • Somos NeXt
  • Somos PerFORM
  • Somos Protogen 18420
  • Somos ProtoTherm 12120
  • Somos Taurus
  • Somos WaterClear Ultra 10122
  • Somos Watershed XC 11122
  • Ultem 1010
  • Ultem 9085
  • Urethane Methacrylate (UMA 90)
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I am looking for literature on high temperature solders, also containing Pb. Any suggestions will be highly appreciated.
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Dear Javeid,
Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Alloys that melt between 180 and 190 °C (360 and 370 °F; 450 and 460 K) are the most commonly used. 999 fine silver is 1761 degrees F and with sterling silver, it is 1640 degrees F. With solder, there are multiple flow points available because of the complexity of multi-step soldering.
There are strong research on research on high-temperature Pb-free solder alloys and the research trend for characterization of the interfacial reaction layer. To improve the product reliability of high-temperature Pb-free solder alloys, thorough research is necessary not only to enhance the alloy properties but also to characterize and understand the interfacial reaction occurring during and after the bonding process.
The development of lead-free solder alloys for high-temperature applications is required to meet increasing demands for reliable replacements for lead-containing alloys. The main candidate alloys can be covered for soldering from the Au–Sn, Au–Ge, Zn–Al, Zn–Sn, Bi–Ag and Sn–Sb alloy systems.
When solder is joined to a substrate, an interface intermetallic compound (IMC) is formed by diffusion of the constituent atoms in the solder and substrate. These IMCs grow by solid-liquid phase diffusion and solid-solid phase diffusion. Solid-liquid diffusion occurs by mass transport between the melted solder (liquid) and substrate (solid) during the bonding process, whereas solid-solid diffusion is responsible for IMC growth after the bonding process. IMC growth reportedly has an important effect on the reliability of solder joints.
Vianco defined “ultrahigh-temperature” solder as “solder used in environments having sustained temperatures as high as 300°C and momentary temperature excursions to levels as high as 350°C”. High-temperature solders are generally required to have adequate physical properties, including high ductility and thermal conductivity and low electrical resistance, and to be cheap and eco-friendly. In particular, they must have a higher solidus temperature than the secondary reflow temperature (~250°C) of the intermediate Tmsolder packaging and have a lower liquidus temperature than the glass transition temperature (~400°C) of polymer-based substrate materials.
To improve the product reliability of high-temperature Pb-free solder alloys, thorough research is necessary not only to enhance the alloy properties but also to characterize the interfacial reaction layer formed during and after the bonding process. Accordingly, the contribution of TEM analysis to the development of high-temperature Pb-free solders is expected to become more important, and it will provide insight into interfacial reactions at the solder joint.
References:
Just go through the references- one is about soldering, one is about characterizations, one is about thermal studies, one is about electronics soldering. Hope it would help you in understanding soldering.
Hope it is helpful for you.
Ashish
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If global warming cannot be resolved by controlling/minimising gas emissions, then extraordinary measures may be the only viable options, one of such ideas is placing a solar shield between the sun and earth at the L1 lagrangian point to obtain a reduction in solar insolation . It may sound crazy, more like science fiction to know that a disk of 2000km in diameter would be necessary to reduce solar radiation reaching earth by 1.7%. I wonder about the sort of stresses that would be experienced by such an enormous body. Also, what sort of materials' properties would be required to withstand the conditions at L1, for example solar radiation, other rays. While it is possible to calculate the disk's orbital velocity around the sun, its angular velocity (around its axis) is difficult to calculate. I would be grateful if those with relevant experience could share their thoughts about how such calculations could be achieved.
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The following article is relevant:
This paper presents a novel method of space-based geoengineering which uses the mass of a captured near Earth asteroid to gravitationally anchor a cloud of unprocessed dust in the vicinity of the L1 position to reduce the level of solar insolation at Earth. It has subsequently been shown that a cloud contained within the zero-velocity curve of the largest near Earth asteroid, Ganymed, can lead to an insolation reduction of 6.58% on Earth, which is significantly larger than the 1.7% required to offset a 2 °C increase in mean global temperature. The masses of the next largest near Earth asteroids are found to be too small to achieve the required level of insolation reduction, however, they are significant enough to be used as part of a portfolio of geoengineering schemes.
Cheers
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Dear all :
May anyone share with me a Graph showing the curves for Temperature vs Thermal Conductivity, and Temperature vs. Electrical Conductivity/Seebeck Coefficient (in the same Graph) for distinct type of materials: (semiconductors, semiconductor alloys, metals, semimetals, etc.) showing the points in the range up to 1000°C ?
This is for use in Thermoelectric materials.
If someone can send it to me I'll appreciate it a lot
Thanks !
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Dear Franklin,
You will get these graphs in many literature. But it is not possible to get these graphs upto 1000 degree celsius for all materials.
Anyway, I think it is better to get these results by your own Experiments because standard data always doesn't match with your working material due to impurities and difference in microstructures.
If anything you want regaring the Experimental details for these I can tell you ( but upto 600 degree Celsius)
Love and Regards
N Das
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Some good models have been proposed for compression (e.g. Mander et al (1989), Scott et al (1982)). But which model to choose for tension?
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Trying to find out how the frequency affects the dielectric constant of a material in order to find a substitute. Thnk you in advance for any help with this.
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Dear Researcher,
You can create some computational models in CST and HFSS software for this study from the point of view of dielectric constant in the kHz to MHz frequency range. I will suggest that you study the following articles and their references:
Borehole measurements of conductivity and dielectric constant in the 300 kHz to 25 MHz frequency range R. N. Grubb ; P. L. Orswell ; J. H. Taylor, Radio Science Year: 1976 | Volume: 11, Issue: 4 | Journal Article | Publisher: AGU
Cited by: Papers (2)
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Because of different deformation coefficients of materials in perovskite devices, we have some troubles to get good cross-section SEM images when trying to cut the devices. How do you usually cut the solar cell devices?
Thank you!
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One of the suitable methods is to prepare the cross section by chemical etching. In this case you will get smooth surface that you can observe by the electron microscope.
If the etch rate is different across the cross section of the layers it will automatically delineate the layers. Otherwise in order to increase the contrast you can bias it by a DC voltage.
Best wishes
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I have a XRD data with a number of overlapping peaks. Hence I am not able to go below GOF 2 and Rwp 10 .
What Goodness of Fit and Rwp could be considered to be the best for Rietveld Refinement in XPert High Score Plus for a material with overlapping peaks?
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Forget about "best" in terms of both Rwp, GOF, or DW statistics. OK, Rwp is said to be "best" if below 10; GOF - if between 1 and 2. But we need to be careful here: adding additional (or any) parameters to the refinement may easily lead to a drop of Rwp --> false positive result / overparametrization. When I do Rietveld (I use the TOPAS software), then I use as low number of parameters/corrections as possible. My approach is tested via the Reynolds Cup competition and it works well, at least with non-clay minerals. I owe a lot of my knowledge in this field to the Rietveld Mailing List, and David Bish. That said, sample displacement and LP factor are a must, so are other, KNOWN, instrumental or related parameters. Regarding the Crystallite Size and Strain (and also most of the REFINED parameters): the value calculated must be > error. If the value calculated is below the related error, then the particular parameter is out of being physically meaningful to the refinement, and in the next run it must be unmarked.
Indeed, I've seen good (reasonable) models with Rwp >10 and even GOF >2. These are "just numbers", they DO say something, but the graphical representation of the result, and its fit to the original data, are also important.
What helps me is the famous Robert A. Wilson and his "forget about 100%" and "forget about IS".... A thing is SUPPOSED TO BE / SIMILAR TO / LIKE.... (:
Cheers,
Luke Kruszewski
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I have a silicone material with the rheology data as shown in the attached image, that was performed using temperature sweep program from 45°C to 160°C.
I would like to understand why does the graph exhibits a double tan delta peak of the same material. What does a double tan delta peak mean from general materials point of view? Anybody has any hypothesis?
*repeated measurements also yield the same result.
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DearAlan,
In the rgeology peak, tan(δ) quantifies the balance between energy loss and storage. In your case, the growth of the overshoot peak is caused by reentanglement of the solution. The inset shows representative transient shear stress data at minimum G. The double peak maxima superpose indicates independent of filler particle size. It also indicates there is a high perturbation rate to the low shear stress of almost 3 Pa and subsequently high damping is seen.
Ashish
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How can I couple Electrical field and magnetic field from Piezoelectric and Magnetostrictive materials?
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Dear Dibyajyoti,
Translation and rotation of a permanent magnet, using a choice of piezoelectric (fiber composite and bulk PZT) and magnetostrictive (amorphous FeSiB ribbon and bulk Terfenol) materials research has been done earlier. Just example is Integrated micro-harvester (coupling devices of two material piezo and megnetostrictive) has been designed.
Coupling magnetostriction and piezoelectricity
Piezoelectric materials are not time dependant if “leaks” are neglected, and thus they may prove useful for our purpose. However, in order to produce high voltage, piezoelectrics require high stress over small displacements, provided through contact forces. Magnetostrictive materials can produce high stress to deform the piezoelectric over small deformations. They are compatible with small strain and can be “activated” remotely, via magnetic field interactions. In a variable magnetic field, a magnetostrictive material stretches or shrinks. When coupled to a piezoelectric, this deformation displaces electric charges in the material, thus achieving the electromechanical conversion. The various conversion stages are such as:
Mechanical energy …… to ……. strain in Magnetostrictive materials-
to strain in piezoelectric materials …… to …. Electric energy output of piezoelectric materials.
The coupling of these two materials allows energy conversion from magnetic/mechanic to electricity. The quasi-static motion of a permanent magnet near the magnetostrictive element can produce a relatively high voltage at the output of the piezoelectric element, regardless of the device’s scale. First, we investigate a device where the permanent magnet is translating. Second the permanent magnet rotates above the device, instead of translating. The magnetostrictive material’s properties and shape should not induce any preferential magnetization direction. When a permanent magnet rotates above the device, the easy axis in the metglass also spins. it was deduced that with a quasi-static rotation speed, even less than 1 rpm, it may still obtain the maximum voltage with the device coupled with a high impedance load. Coupling piezoelectric and magnetostrictive materials allows exploiting quasi-static phenomena.
Just refer this article.
Hope my interpretation article help you out.
Ashish
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Are there any standard procedures or scientific price list to evaluate the cost of the materials (for industrial mass production)? I want to compare the price of alloys based on its elemental content. I know that the metal costs fluctuate but any scientific procedure to evaluate the alloy cost?
Thanks.
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Usually, what a customer is willing to pay for an alloy is determined by its properties, not its chemistry. That is, one may assume that customers buy the cheapest alloy that meets their needs. Of course, properties are determined by the specific combination of chemisty, processing, and microstructure. For example, most Al alloys are over 90% Al; and therefore, on a commodity basis they should all cost about the same. However, the processing and heat treatments required to get the properties required for aircraft alloys has a strong influence on their final price. However, let us suppose one only wants to look at the cost of the elemental constituents for some analysis. What level of purity should one use for each element in this calculation? That is, the cost of an element in "pure form" can vary greatly with the degree of purity. An element can be very inexpensive at a commercial purity of 99.8%, but orders of magnitude more expensive at 99.9998%. The 0.2% could be elements that ruin the properties of a high tech alloy, but are perfectly acceptable in a low tech alloy. These requirements will be a significant factor in determining the price of the commodities required to make an alloy.
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Manganese was doped upto 1% in MgAl2O4 spinel. As doping concentration increase,I found a gradual red shift in the transmission spectra. what is the basic cause of red shift?
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Dear Haider,
Doping is addition of impurity to the material. Manganese can substitute the Mg atoms and so building MnAl2O4. So after doping the material will be composed of a mixer of two materials. The energy gap of the of the mixer will be smaller than the host material if the MnAl2O4 has a smaller band gap than MgAl2O4. I assume this is what happening in your experiment. In order to verify this hypothesis you need to get the energy gap of the two materials. Or you measure them separately.
There is other bend gap narrowing as a consequence of shallow doping because of the increase in the free carrier concentration either in the conduction or the valence band.
For more information about this phenomenon please see the paper in the link:
Best wishes
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Which are the most preferred ceramics for dental implants?
TIA
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The most dental ceramics preferred to restore dental implants are monolithic zirconia, lithium disilicate, zirconia layered with felspathic.
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Dear experts,
I am investigating how polyurethanes are affected by the degree of mixing. More in general, I am interested to study how the contact between the two reactants (in my case polyol and isocyanate), and as a consequence the reaction rate, can be affected by changing tre speed of the stirrer.
May you suggest me which parameter to investigate?
And, please, if you have some reference about this topic can you share it?
Thanks in advance.
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Hi,
When the surface area of reactants is increased, the frequency of collision between the reactant particles is also increased. Greater the surface area, higher will be the rate of reaction.
Best regards
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In order to do a material analysis on solar pv panels, I want the percentage of each material used in it (I'm considering the whole assembly such as batteries, junction box, combiner box etc). For example, Silica 72%, Silver 0.6%, Nickel 13%, Cadmium 22%... but I couldn't find any website/article/papers on it.
If anyone have any information on it/if anyone know where I can get it from could you please share it with me? Any pointers would do. Thank you for your time in advance!
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Hi Amruta,
If its elemental analysis you are looking for then ICP is the best method, though given that there is Si involved, it might pose some problems. Also, ICP is a destructive testing method, which I assume if going to be an issue for you.
The only other methods that come to mind are XRF and EDX. Repeated large area scans from both could provide you with a pretty good picture, but not the most accurate. Furthermore, both of them being X-ray based techniques have limited probe depth. Ultimately it would depend on the kind of accuracy you need.
I hope this helps.
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I am not running a heat transfer job in Abaqus. It is a material mechanical response job. I noticed that TEMP and DTEMP are both passed in as parameters in the UMAT regardless and I am wondering if I can specify an initial temperature in the Abaqus job, calculate DTEMP in my umat using the equations I need, and then save the temperature in TEMP without having to save it as an user-defined state variable that has to be read back in in the UMAT? Or is that only available if I am running a heat transfer job?
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In a UMAT subroutine, both TEMP and DTEMP are passed for information. TEMP is the temperature at the beginning of the increment and DTEMP is the temperature increment. These variables can be used for integration of constitutive relations but should NOT be modified (same as for STRAN and DSTRAN). The evaluation of the temperature increment is performed by ABAQUS outside the UMAT based on the thermophysical properties of the material (for instance when adiabatic self-heating is included).
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I'm writing a project in which I am trying to prove E-TPU is a better sued material for shoe soles than TPU and EVA, but the data won't cooperate.
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The data are the data and if they don’t Fit your model, then the model must be changed.
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I need to solve a polyurethane binder and the recommended solvent is NMP( N-Methyl-2-pyrrolidone ) but I have to replace it with another solvent due to material  shortage. Is there any alternative ?
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This is also my question. I am working on this topic currently, and my preliminary experiments shows that heat treatment can have a positive effect on leaching. I will publish the results of these experiments in the future.
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Hi RG community--
My question: Are the Gibbs free energy curves of pure substances always parabolic at constant temperature? E.g. Is the function G(P) at constant T always parabolic?
And if so, can someone point me towards a proof or derivation of this fact?
Thanks so much!
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Dear Mr. Power-Palm.
In response to your question on Gibbs free energy.
Where from you came to the idea that it is of parabolic shape? (*Are he Gibbs free energy curves of pure substances always parabolic? And if so, can someone point me towards a proof or derivation of this fact*? ).
The format of this RG-page unable to present plot. However, if you appeal to my personal mail, I'll send you plot that shows connection of Gibbs energy and other thermodynamic functions (H -enthalpy, U-free internal energy, etc.). My requisite you can see below.
From this plot, you can clearly see that Gibbs enery directly depends on entropy S -the higher entropy, the lesser Gibbs energy, and visa versa H=G+TS→ G=H-TS.
However, Gibbs energy has another important mathematical feature –on the solution interval (i.e. the enthalpy is given and fixed H=Const), the Gibbs energy is strictly convex function of arbitrary form (particularly, it may be parabolic one). Strict mathematical proof of this statement was first presented by Zeldovich, and you can find this poof in my textbook *A Simple Kinetic* (pages 43-45). By the way, you can see mentioned plot in the same my book – see page 31.
To access this book make the following Cloude procedure:
1. Go to GoogleChrome (or Yandex):
2. Make link https://yadi.sk/d/7w5jSXrB3GBzti and clic.
3. The title *SimpleKinetics.pdf* will appear. Clic and open file. Find pages 43-45 (and 31).
4. Reload this file from Cloud-system to your comp.
Unfortunately, this is Russian version, but the equations are the same at any language, so, it is my hope, that you will understand the proof.
Summary: Gibbs free energy is continuous (i.e. it has first derivatives at any point) convex function of arbitrary form (incl. parabolic shape).
Regards
Vasili DIMITROV, Ph.& Ch.D.
Emeritus Professor of Chemical Physics.
25 Fisherville Rd, #703, North York,
ON, M2R 3B7, Canada.
Tel. home (1)-416-546-8442, cell (1)-647-632-6355.
Skype vasilidim
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For close shaped section, polar moment of inertia can be calculated from perpendicular axis theorem (adding both the 2nd moment of area in cross sectional axis). But how to calculate polar moment of inertia (2nd moment of area in perpendicular direction of the cross section) of I beam?
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The statement "I am looking for 2nd moment of area in y direction of this shape." is not correct. Maybe you are looking at the polar moment of the section with respect to y axis:
Iyy =Izz+Ixx
(I assume, although not shown in your drawing, that (xyz) has origin at the barycenter of the section)
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It is know that austenizing steel produces hard martensite after quenching, and the properties of it can be improved by tempering to create better toughness while making the metal softer and more ductile.
Yet say this method is used for a piston (which was quenched then tempered at 600 degrees C). What happens to the hardness of the low alloy steel in standard operating temperatures up to 425 degrees C?
Are there any further phase changes? Can something like precipitation hardening occur or are these temperatures too low for an already QT steel.
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If you properly quench a hardenable steel and then temper it at 600 C, you sure can use it at 420 without any damage to microstructure and properties. The only one additional question should be asked and replied: how much time your part should serve at 420 C. If the service is long-period, it may cause some undesirable microstructural change with time.
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what is the relation of between ionic conductivity of IT SOFC electrolyte and cathode in cathode reaction mechanism?
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Asim Idrees Thanks, This is what i was trying to look for, I am new to this field.
Thanks to all
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how can we just justify the increase in activation energy by increasing the GDC/SDC content in sofc cathode.....
for reference please see this paper page 6/2165....
DOI 10.1007/s10853-015-9526-7
10.1016/S0167-2738(02)00102-9
page 32
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Thank you for highlighting the pages, Nin Nan
Here is a possible explanation to your question.
Ceria, when used as an MIEC in electrodes, under reducing conditions (anode) doped ceria is partially reduced from Ce4+ to Ce3+ . This induces n-type electronic conductivity, which can lead to partial internal electronic short circuits, and this problem increases with increasing temperatures. See Fig. (Fuel Cell Fundamentals by R O Hayre) where the electronic conductivity at the anode side will be greater than the ionic conductivity for temperatures greater than about 550C.
The disadvantages of doped ceria can be partially solved by adopting a multilayer approach where, for example, a GDC layer facing the cathode is combined with another solid electrolyte (e.g., YSZ) facing the anode. However, multilayer cells also have performance problems due to formation of reaction products with low conductivity at the interface between the electrolyte layers, as well as the mismatch in thermal expansion between the electrolyte layers, which can result in microcracks.
So these reaction products, or change in reaction mechanisms for Doped Ceria at the cathode side is what is mentioned in the papers you shared. And it seems like they have come up with an optimal doping concentration of 30% for lowest ASRs for doped ceria used at the cathode side.
Hope this answers your query
regards
Waqas
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Hi everybody;
As you know material's mechanical properties have changed after heat treatments.
So each one of you know how to find a way to reach the relation between heat treatments and for example yield strength of materials ? (Experimental tables or formula)
Thanks for any guide
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You refer this document for basic understanding of heat treatment effects on mechanical properties of steel.
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I wish to find a bending and torsion test standard for a surfboard (non-prismatic) that is roughly 2000mm long. The closest I've found for bending test is probably those ones that are designed for concrete where the specimen is really long and thick.
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Three Point bending test is recommended
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'Hello Everyone ,
Hope you are doing fine . I am a graduate student and I have not much idea of the scientific journals .
Can you suggest me some authentic journals where I could submit my work related to composite's structural (numerical investigation of buckling behavior) . The work is pure simulation based .
As I am a student I would really appreciate a journal with minimum to zero submission fee .
Best Regards
Aamir
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Hi Aamir,
In addition to Amrit's comment, I would add:
In addition to the ACI struct. J.
Regards!
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I know that youngs modulus is material property but am not clear about stiffness how vary?
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The stiffness directly proportional to Young's modulus.
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It is known that bulk materials and thin films represent two different universes in terms of diffusion controlled transformations. Are commonly used phase diagrams, mainly made using bulk materials investigations, can find application in the exploration of thin films?
Dear colleagues, what is your opinion on this topic?
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By processes implying low temperature (i.e. Pvd or electrodeposotion) you can obtain alloys not predicted by phase diagrams (that are constructed for equilibrium conditions). These alloys are not thermodynamically stable. So if you increase the temperature, they can decrease their excess of energy and you obtain a thin film exactly composed of the phases predicted by the phase diagram of the bulk material. It happens at ambiant temperature with thin film of gold deposited on copper. With ageing, the copper and gold diffuse and at the end your (cheap) watch becomes pink.
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I know you can apply displacement to a rigid body (cylindrical rod) to perform a 3 point bending test in ABAQUS. Is it possible to apply force to the rod (e.g. rod with super high young's modulus so it wont deform). I am trying to apply topology optimisation on a structure, so the displacement will change when material is removed at every iteration.
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Build the bending die (tool) model and the contact is considered. After that, you apply a concentrated force on the die or tool.
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I want to optimize a process. The process has 12 important process parameters ( 12 factors and each has three levels). I want to use RSM tool. The RSM is best approach with respect to optimization as compared to other techniques. But it is not capable to manage data with 12 factors. it is possible that some one split or divide the whole process into small sections (3 factors and three levels) and then optimize the process. Is it possible that someone divide the large process into small portions/sctions and then do optmization. If yes, have you any research paper for a reference. Can you share with me.
Need expert opinion and guidance
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Optimizing an Oil Refinery Production is one of my projects. Such a problem has many thousands of equations, many PDEs, and hundreds of constraints. Do you have any Operations Research background (OR)? An OR background would be helpful to understand the complexity. Here are two articles that may enlarge your view of the problems. and
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I have diagram of cyclic voltammogram, seeking to understand how to define the diagram voltammogram.
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I found the following video link very informative - although I assume there is bit of anomaly in the definition of anodic and cathodic current.
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Aim is to introduce different amounts of oxygen into Zr and study its deformation behaviour.
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Heating it in open air for various times will form oxygen layer of various thickness on the surface of Zr. O2 is very eager to get into the surface of Zr :). Than you can anneal the sample in furnace for penetration of O2 content. Though this is not a scientific way of doing it. You may get different results with different experiments.
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I am having 4 inorganic salts - NaOH KOH NaNO3 KNO3. I want to prepare a salt mixture using any of these 4 salts which should have melting point in the range 175-215 °C.
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I recommend you to read this paper:
Best regards